Response Surface Designs for Experiments with Mixtures

In estimating a response surface where the k variables represent proportions in a mixture, the experimenter is often interested in a reasonably well-defined region of interest which may, for example, center about current operating levels. Previously developed designs are difficult to use except in exploring the entire factor space, and even then there are several disadvantages to these designs. A general method of constructing designs from familiar response surface designs in k ? 1 independent variables and the appropriate analysis for a general polynomial is given. Special attention is given to the first and second order polynomials.     

Feasible compositions for random copolymerizations

Using the attainable region approach, feasible compositions and conversions for random copolymers are determined, along with altermatives for the related reactor configurations. This analysis attempts to find all of the possible compositions that can be produced by any system of reactros and mixing. The average copolymer compositions are bounded by the feed composition and the instantaneous copolymer composition produced at the initial conditions. Since the instantaneous copolymer composition can be found through the Mayo‐Lewis equation, that case and the feed composition mark the limiting feasible compositions. The results can also be used to determine the range of feed compositions for which a specific copolymer product composition is possible. If the addition of monomer at any point in the reactor system is possible, e.g., by side‐feeding, the analysis indicates that any desired copolymer composition can be obtained.     

Hydrodeoxygenation of HMF over Pt/C in a continuous flow reactor

The three‐phase hydrodeoxygenation reaction of 5‐hydroxymethylfurfural (HMF) with H₂ was studied over a 10 wt % Pt/C catalyst using both batch and flow reactors, with ethanol, 1‐propanol, and toluene solvents. The reaction is shown to be sequential, with HMF reacting first to furfuryl ethers and other partially hydrogenated products. These intermediate products then form dimethyl furan (DMF), which in turn reacts further to undesired products. Furfuryl ethers were found to react to DMF much faster than HMF, explaining the higher reactivity of HMF when alcohol solvents were used. With the optimal residence time, it was possible to achieve yields approaching 70% in the flow reactor with the Pt/C catalyst. Much higher selectivities and yields were obtained in the flow reactor than in the batch reactor because side products are formed sequentially, rather than in parallel, demonstrating the importance of choosing the correct type of reactor in catalyst screening. © 2014 American Institute of Chemical Engineers AIChE J, 61: 590–597, 2015     

Examination of radio‐opacity enhancing additives in shape memory polyurethane foams

Three microparticle additives, tungsten (W), zirconium oxide (ZrO₂) , and barium sulfate (BaSO₄) were selected to enhance the radio‐opacity in shape memory polymer (SMP) foam biomaterials. The addition of filler causes no significant alterations of glass transition temperatures, density of the materials increases, pore diameter decreases, and total volume recovery decreases from approximately 70 times in unfilled foams to 20 times (4% W and 10% ZrO₂). The addition of W increases time to recovery; ZrO₂ causes little variation in time to shape recovery; BaSO₄ increases the time to recovery. On a 2.00 mean X‐ray density (mean X.D.) scale, a GDC coil standard has a mean X.D. of 0.62 ; 4% W enhances the mean X.D. to 1.89, 10% ZrO₂ to 1.39 and 4% BaSO₄ to 0.74. Radio‐opacity enhancing additives could be used to produce SMP foams with controlled shape memory kinetics, low density , and enhanced X ‐ray opacity for medical materials. © 2015 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2015 , 132, 42054.     

Bridging the Gap between Quantitative and Qualitative Accelerated Life Tests

Test planners have long sought the ability to incorporate the results of highly accelerated life testing (HALT) into an early estimate of system reliability. While case studies attest to the effectiveness of HALT in producing reliable products, the capability to translate the test's limited failure data into a meaningful measure of reliability improvement remains elusive. Further, a review of quality and reliability literature indicates that confusion exists over what defines a HALT and how HALT differs from quantitative accelerated life testing methods. Despite many authors making a clear distinction between qualitative and quantitative accelerated life tests, an explanation as to why this delineation exists cannot be found. In this paper, we consider an exemplary HALT composed of a single stressor to show that the HALT philosophy precludes the estimation of a system's hazard rate function parameters because of the test's fix implementation strategy. Four common accelerated failure data analysis methods are highlighted to show their limitations with respect to estimating reliability from HALT data. Finally, a modified accelerated reliability growth test is proposed as a way forward for future research in HALT scenarios to characterize the risk of attaining a reliability requirement and improve parameter estimation. Copyright © 2014 John Wiley & Sons, Ltd.     

Matching housing supply and demand: an empirical study of Hong Kong's market

This paper has the objective of improving on the issue of forecasting new housing construction, and highlights differences between space demand and investment demand in housing markets. Further, it indicates how these differences will affect construction decisions. The first step is to identify the factors associated with estimating residential property prices in Hong Kong, based on a demand-supply adjustment process. Specifically, this study examines the role of population growth, transaction volume, inflation and interest rate in determining house prices. Second, based on these estimations, a methodology is developed to estimate the investment demand schedule and new construction of residential property.     

Theory and Practice in Metropolitan Strategy: Situating Recent Australian Planning

Over the last several years, metropolitan strategies have been produced for the five mainland state capital cities of Sydney, Melbourne, Brisbane, Adelaide and Perth. The distinctive characteristics of Australian urban planning mean that they can be shown to reflect an Australian paradigm of planning. However, this paradigm is rewritten in different ways in each strategy reflecting the particular institutional circumstances and political culture of each state. In doing so there is some strong reaffirmation of this paradigm, but also indications of a more relational and transactive manner of planning adding further process to product. Here there is some resonance with recent developments in planning theory and to some extent in practice—largely in Europe.

     

Urban Development the Pattern and the Background; Concluding Discussion

When We Build Again. A Bournville Village Trust Research Publication. George Allen &; Unwin, Ltd., London, 1941. Pp. xii (16), 138.

Report Relative to Postwar Reconstruction in the City, Prepared by Improvements and Town Planning Committee, published by The Corporation of London, 1944, pp. 66 plus maps and photographs.

The Economic Status of the New York Metropolitan Region in 1944, by The Regional Plan Association, Inc., New York, 1944, xx, 91 pp.     

Government Subsidy for Housing in Great Britain

The Economic Reports of The President, January 1948, January 1947 and July 1947. With an Introduction by the Council of Economic Advisors. Reynal &; Hitchcock, New York. 307 plus xiv pages. $2.50.

The Master Highway Plan for the Boston Metropolitan Area. By The Joint Board for the Metropolitan Master Highway Plan, Charles A. Maguire &; Associates, De Leuw, Cather &; Co., and J. E. Greiner Co., Consultants, Boston. Feb. 1948. 121 pages and key maps.

A Critical Review of Research in Land Economics. By Leonard A. Salter, Jr. The University of Minnesota Press. 1948. 258 pages. $4.00.

Land Economics. By Roland R. Renne Harper and Brothers. 1947. 736 pages. $5.00.

The Redevelopment of Central Areas. The Ministry of Town and Country Planning. H. M. Stationery Office, London, 1947. 99 pages, illustrated in color. Obtainable in the U.S.A. through the British Information Services, Rockefeller Center, New York. $3.65.

Pierre Sur Pierre, Construction du Nouvel Urbanisme. By Gaston Bardet. Plans, photographs, diagrams. Editions L. C. B. Section Batiment, Paris, 1946-47. 290 pages.

Planificacion y Sociografia. By Dr. Miguel Figueroa Roman, Instituto de Sociografia, Colegio Libre de Estudios Su-periores, Tucuman, Argentina, 1946. 201 pages.