Synthesis of tertiary amines and their inhibitive performance on carbon steel corrosion

Some tertiary amines in the series of 1,3-di-amino-propan-2-ol, referred as 1,3-di-morpholin-4-yl-propan-2-ol (DMP) and 1,3-bis-diethylamino-propan-2-ol (DEAP), had been synthesized by alkylation reaction. These compounds were checked by MS, IR, ¹H NMR and ¹³C NMR. The electrochemical performance of these products was investigated through potentiodynamic polarization measurement and electrochemical impedance spectroscopy (EIS) under thin electrolyte layer with thickness of 100 μm, and their inhibition efficiencies were measured using gravimetric method. These compounds, retarding the anodic dissolution of iron by the protective layer bonding on the metal surface, were anodic inhibitors under thin electrolyte layer. Polarization data indicated that the inhibitive performance of DMP for carbon steel was improved with the increasing of concentration, whereas DEAP showed a maximum inhibiting power at 2.5 × 10⁻² M. The values of the charge transfer resistance, obtained from impedance plots of carbon steel, showed that DEAP was a promising inhibitor. The gravimetric results showed that the inhibition efficiency of DEAP at 2.5 × 10⁻² M was 95%. The adsorption on the carbon steel surface followed Langmuir isotherm model. The Fourier transform spectroscopy (FTIR) was used to analyze the surface adsorbed film.     

冷连轧过程控制数据管理系统的研究

数据管理系统逐渐成为冷连轧过程控制中的重要组成部分。介绍了一种基于组态软件的数据管理系统,重点介绍了过程数据的采集和存储,及其在冷连轧过程控制中的应用等。     

表面脱β层梯度结构硬质合金研究进展

随着涂层技术在硬质合金领域的日益广泛应用,制备可防止涂层裂纹向基体扩展的具有表面脱立方相碳化物(即β相)的梯度结构的硬质合金基体成为需要。文中概述了此类结构合金的形成机理、影响因素以及发展现状和方向等。     

呋喃树脂自硬砂在纺织机械铸铁件上的应用

介绍呋喃树脂自硬砂在纺织机械类铸铁件生产中的实际应用，详细阐述了原材料选取，呋喃树脂自硬砂制备工艺、造型与制芯等工序的操作要点及应用实例，分析了呋喃树脂自硬砂代替普通粘土干型砂工艺的利益所在。     

用宏微观耦合模型模拟铝合金凝固过程

用一种宏微观耦合模型对Al-2．5Si在金属型中的凝固情况进行了模拟。该模型结合改进的元胞自动机模型与有限差分法，考虑了温度场、浓度场和微观生长过程。该改进的元胞自动机模型与经典元胞自动机相比较，不仅考虑了温度场扩散，而且考虑了溶质在液相中的扩散、界面曲率和溶质富集对枝晶尖端过冷度的影响。在宏微观耦合模型中采用大小两套网格分别进行宏观温度场和微观组织演变的计算。在3种不同的浇注温度下得到了3种典型的柱状晶向等轴晶转变的图形。考虑边界条件后的模拟结果发现等轴晶的形核情况与理论分析有所差别。     

基于Solid Edge参数化设计的两种方法

通过使用VB语言对Solid Edge软件进行二次开发，利用完全程序化建模方法实现对斜齿轮的参数化设计，利用变量化设计建模的方法实现对螺栓的参数化设计。     

Residual stress analysis of 7075 aluminum alloy after vacuum electron beam welding

The residual stresses distribution of 7075 aluminum alloy in vacuum electron beam welding joint was numerically simulated using nonlinear finite element method. The result shows that the longitudinal residual stress is tension stress along weld center and the stress peak value appears in the middle of the welded seam; the transversal residual stress is compression stress ; the residual stress in thickness direction is very small.     

20Cr钢球化退火工艺

本文系统地研究了２０Ｃｒ钢冷挤压毛坯的球化退火过程，选定了亚共析钢节能，省时与球化效果好的热处理工艺，并已用于工业生产，取得了显著的经济效益。     

不同石墨形态铸铁热疲劳性能试验研究

针对某些承受热循环工况的铸件，采用实验室手段，研究了不同石墨形态铸铁──灰铁、蠕铁、球铁在＞５０～４０℃循环温度下的热疲劳性能。结果表明，在本试验条件下，以球铁的热疲劳抗力最好，灰铁次之，蠕铁最差，研究结果可供实际生产中，选材时的参政。     

退火温度对Nd2(FeGaCo)14B/α-Fe纳米复合材料磁性能的影响

用熔体快淬和晶化处理的方法制备了Nd2(FeGaCo)14B／α—Fe纳米复合材料，研究了晶化热处理温度和时间对材料磁性能的影响。结果表明Nd8Fe84.5Ga1Co2B4.5纳米复合材料的磁性能随热处理条件而变化，低温长时间和高温短时间热处理所得样品的最佳磁性能相当。