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排序方式: 共有6925条查询结果,搜索用时 15 毫秒
61.
Kien Tiek Wong Boris Brigljević Jeong Hyeon Lee So Yeon Yoon Seok Byum Jang Choe Earn Choong Inwook Nah Hyeongjun Kim Hyun-Seog Roh Sang Kyu Kwak Hankwon Lim Min Jang 《Small (Weinheim an der Bergstrasse, Germany)》2023,19(1):2204336
This study focuses on the applicability of single-atom Mo-doped graphitic carbon nitride (GCN) nanosheets which are specifically engineered with high surface area (exfoliated GCN), NH2 rich edges, and maximum utilization of isolated atomic Mo for propylene carbonate (PC) production through CO2 cycloaddition of propylene oxide (PO). Various operational parameters are optimized, for example, temperature (130 °C), pressure (20 bar), catalyst (Mo2GCN), and catalyst mass (0.1 g). Under optimal conditions, 2% Mo-doped GCN (Mo2GCN) has the highest catalytic performance, especially the turnover frequency (TOF) obtained, 36.4 h−1 is higher than most reported studies. DFT simulations prove the catalytic performance of Mo2GCN significantly decreases the activation energy barrier for PO ring-opening from 50–60 to 4.903 kcal mol−1. Coexistence of Lewis acid/base group improves the CO2 cycloaddition performance by the formation of coordination bond between electron-deficient Mo atom with O atom of PO, while NH2 surface group disrupts the stability of CO2 bond by donating electrons into its low-level empty orbital. Steady-state process simulation of the industrial-scale consumes 4.4 ton h−1 of CO2 with PC production of 10.2 ton h−1. Techno-economic assessment profit from Mo2GCN is estimated to be 60.39 million USD year−1 at a catalyst loss rate of 0.01 wt% h−1. 相似文献
62.
Hyunsik Choi Bolam Kim Sang Hoon Jeong Tae Yeon Kim Dong-Pyo Kim You-Kwan Oh Sei Kwang Hahn 《Small (Weinheim an der Bergstrasse, Germany)》2023,19(1):2204617
A variety of wound healing platforms have been proposed to alleviate the hypoxic condition and/or to modulate the immune responses for the treatment of chronic wounds in diabetes. However, these platforms with the passive diffusion of therapeutic agents through the blood clot result in the relatively low delivery efficiency into the deep wound site. Here, a microalgae-based biohybrid microrobot for accelerated diabetic wound healing is developed. The biohybrid microrobot autonomously moves at velocity of 33.3 µm s−1 and generates oxygen for the alleviation of hypoxic condition. In addition, the microrobot efficiently bound with inflammatory chemokines of interleukin-8 (IL-8) and monocyte chemoattractant protein-1 (MCP-1) for modulating the immune responses. The enhanced penetration of microrobot is corroborated by measuring fibrin clots in biomimetic wound using microfluidic devices and the enhanced retention of microrobot is confirmed in the real wounded mouse skin tissue. After deposition on the chronic wound in diabetic mice without wound dressing, the wounds treated with microrobots are completely healed after 9 days with the significant decrease of inflammatory cytokines below 31% of the control level and the upregulated angiogenesis above 20 times of CD31+ cells. These results confirm the feasibility of microrobots as a next-generation platform for diabetic wound healing. 相似文献
63.
Jiabin Liu Jiawei Deng Yangyang Zhu Xiaokang Geng Lifu Zhang Sang Young Jeong Dan Zhou Han Young Woo Dong Chen Feiyan Wu Lie Chen 《Advanced materials (Deerfield Beach, Fla.)》2023,35(1):2208008
With the great potential of the all-polymer solar cells for large-area wearable devices, both large-area device efficiency and mechanical flexibility are very critical but attract limited attention. In this work, from the perspective of the polymer configurations, two types of terpolymer acceptors PYTX-A and PYTX-B (X = Cl or H) are developed. The configuration difference caused by the replacement of non-conjugated units results in distinct photovoltaic performance and mechanical flexibility. Benefiting from a good match between the intrinsically slow film-forming of the active materials and the technically slow film-forming of the blade-coating process, the toluene-processed large-area (1.21 cm2) binary device achieves a record efficiency of 14.70%. More importantly, a new parameter of efficiency stretchability factor (ESF) is proposed for the first time to comprehensively evaluate the overall device performance. PM6:PYTCl-A and PM6:PYTCl-B yield significantly higher ESF than PM6:PY-IT. Further blending with non-conjugated polymer donor PM6-A, the best ESF of 3.12% is achieved for PM6-A:PYTCl-A, which is among the highest comprehensive performances. 相似文献
64.
Duplex spinel-ZrO2 ceramic composites were produced by an emulsion-hot kerosene drying technique. The sintered duplex spinel-ZrO2 ceramics which had the composition of 55 wt% Al2O3-20 wt% ZrO2-25 wt% MgO, consisted of a spinel matrix, whose grain size was in the range of 1.5 to 2.0 m, and uniformly dispersed zirconia agglomerates having grain sizes ranging from 1.0 to 2.0 m. Zirconia agglomerates began to appear at a temperature of 1500 °C and the duplex spinel-ZrO2 structure was formed with the weight ratio of Al2O3/MgO being within 1.67 to 2.20 and the amount of ZrO2 addition being within 5 to 25 wt %. The relative density, fracture toughness, flexural strength, and critical temperature difference of the spinel-ZrO2 composite were 97.8%, 1.98 MPam0.5, 390 MPa, and 275 °C, respectively. 相似文献
65.
H. Sang N. Xu S. Y. Zhang J. H. Du Q. Li Y. W. Du 《Journal of Materials Science》1996,31(20):5385-5389
A number of structural analysis methods were employed to investigate the microstructures of ion-beam co-sputtering of Co
x
Ag1–x
(0x100 at%) granular films. Forx=22 at%, the sample which has the optimal giant magnetoresistance at room temperature, there exists either crystallized or highly disordered regions shown by high-resolution electron microscopy. At the boundary between cobalt granules and the silver matrix, lattice mismatch was formed, leading to roughness of the interfaces. X-ray diffraction and transmission electron microscopy revealed that the samples had f c c structure at lowx, with (111) texture, and the h c p structure gradually appeared as x>75 at %. Relative lattice expansion was observed asx increased. 相似文献
66.
Sul Gee Park Ho Cheol Jeong Jeong Won Kim Dong-Hwan Hwang Sang Jeong Lee 《International Journal of Control, Automation and Systems》2011,9(2):276-284
This paper proposes a magnetic compass fault detection method for GPS/INS/Magnetic compass integrated navigation systems.
The fault is assumed to be caused by the hard iron and soft iron effect and modeled as an abrupt change in the magnetic compass
output. In order to detect the fault, a test statistic related with only azimuth error measurement is determined. When a fault
is detected, the GPS/INS/Magnetic compass integrated navigation system is changed into a GPS/INS integrated navigation system
mode. In order to show the validity of the proposed method, computer simulation and van testing are carried out. The simulation
and van test results show that the proposed navigation system gives more accurate outputs than the GPS/INS/Magnetic compass
without the proposed method. 相似文献
67.
Dong-Pyoung Sheen Tae-geun Son Dae-Kwang Myung Cheolho Ryu Sang Hun Lee Kunwoo Lee Tae Jung Yeo 《Computer aided design》2010,42(8):720-730
A simplified geometric model with lower dimensionality, such as a mid-surface model, is often preferred over a detailed solid model for the analysis process, if the analysis results are not seriously impacted. In order to derive a mid-surface model from a thin-walled solid model, in this paper, we propose a novel approach called the solid deflation method. In this method, a solid model is assumed to be created by using air to inflate a shell that comprises the surface of the solid model. First, the model is simplified by the removal of any detailed features whose absence would not alter its overall shape. Next, the solid model itself can be converted into a degenerate solid model with zero thickness. Finally, a surface model is generated by splitting large faces paired in the thinned solid model, selecting one face per pair for creating a sheet model, and sewing the selected faces. Using this method, a more practical and usable mid-surface model can be very efficiently generated from a solid model because it can circumvent not only the tedious trimming and extension processes of the medial axis transformation method but also the time-consuming patch joining process of the mid-surface abstraction approach. 相似文献
68.
In recent years, Radio Frequency Identification (RFID) industries have taken a great interest in utilizing the benefits of RFID for supply chain management, inventory control and various other applications. This paper proposed an adaptive load balancing technique for RFID middleware systems to meet the demands of scalability and heterogeneity. First, we explored five basic load balancing policies, namely, information policy, job selection policy, transfer policy, initiation policy and location policy. Eighteen load balancing schemes were then proposed for RFID middleware systems that were combinations of various types of the five basic load balancing policies. Our empirical study suggested that these load balancing strategies performed differently under different workload statuses. Finally, an adaptive load balancing strategy was proposed. The load balancing schemes and the proposed adaptive load balancing strategy have been implemented in the RFID Middleware Load Management System (RM‐LMS). Copyright © 2010 John Wiley & Sons, Ltd. 相似文献
69.
Yong‐Kyu Jang Seong Jun Lee Jae Young Lee Yi Li Jae Hoon Hwang Sang Woo Kim Chang Woo Shim Ju Yeon Seo Nam Jin Kim Yi Joon Ahn Nam Hee Kim Seon Hong Ahn Seong Ryong Lee Dae Hee Park Chi Woo Kim 《Journal of the Society for Information Display》2011,19(3):253-257
Abstract— A novel pixel design for vertical‐alignment LCDs with superior transmittance has been developed. The new liquid‐crystal mode, refered to as the hole‐induced vertical‐alignment mode (Hi‐VA), uses a via hole of an organic layer on a TFT substrate to achieve multi‐domain alignment. Compared to the conventional design, the Hi‐VA mode has a transmittance of up to 135% with a contrast ratio of 2000:1. Moreover, the new structure is free from ITO patterning or protrusion on the color‐filter side, which makes the fabrication process simple and low cost. 相似文献
70.
The human shoulder complex is perhaps the most complicated joint in the human body being comprised of a set of three bones, muscles, tendons, and ligaments. Despite this anatomical complexity, computer graphics models for motion capture most often represent this joint as a simple ball and socket. In this paper, we present a method to determine a shoulder skeletal model that, when combined with standard skinning algorithms, generates a more visually pleasing animation that is a closer approximation to the actual skin deformations of the human body. We use a data‐driven approach and collect ground truth skin deformation data with an optical motion capture system with a large number of markers (200 markers on the shoulder complex alone). We cluster these markers during movement sequences and discover that adding one extra joint around the shoulder improves the resulting animation qualitatively and quantitatively yielding a marker set of approximately 70 markers for the complete skeleton. We demonstrate the effectiveness of our skeletal model by comparing it with ground truth data as well as with recorded video. We show its practicality by integrating it with the conventional rendering/animation pipeline. 相似文献