铁氮共掺杂纳米TiO2的水热法制备及其在可见光下抗菌性能的研究

以硫酸氧钛为前驱体，硝酸铁和盐酸胍作为掺杂的铁源和氮源，采用水热法制备了铁氮共掺杂纳米TiO2粉体。利用XRD、BET对样品进行表征，研究了掺杂后TiO2粉体的晶型、粒径、比表面积等性能。结果表明，所制备的共掺杂TiO2粉体呈黄色，均为锐钛矿相TiO2，经谢尔公式计算其粒径约为10nm，比表面积分布为（135～150）m^2／g。采用紫外．可见光漫反射光谱对样品进行表征，结果表明经过铁氮共掺杂改性后的TiO2具有很强的紫外线的吸收能力，并实现了良好的可见光响应。采用菌落计数法进行了样品抗菌性能的研究，在可见光照射下样品对大肠杆菌表现出良好的杀灭性能。     

Surface Chemical Modification of Poly(Methylphenylphosphazene)

Summary The surface reactivity of poly(methylphenylphosphazene), PMPP, and its derivatives containing silane, PMPP-SiH, and alcohol, PMPP-OH, substituents was investigated. These polymers were fabricated into films by casting from THF solutions and reactions were carried out at the interface between solid film samples and solutions. The surface of PMPP was successfully modified by deprotonation under dilute conditions followed by reactions with RMe₂SiCl [where R = CH=CH₂, and H]. While surfaces of PMPP-OH were not readily modified, those containing Si-H groups reacted with oxygen when heated and with carbon tetrachloride. The polymer surfaces were examined by contact angle measurements, attenuated total reflectance infrared spectroscopy (ATR-IR), and scanning electron microscopy (SEM). We dedicate the paper to Christopher W. Allen in recognition of his outstanding contributions to inorganic ring and polymer chemistry.     

Cu/SBA-15 as adsorbent for propane/propylene separation

Samples of mesoporous silica SBA-15 were prepared under hydrothermal conditions where Cu cations were incorporated to the structure by impregnation in order to compare the adsorption behavior in the presence and absence of this element. The adsorption/desorption equilibrium isotherms of propylene, propane, and N₂ were measured to evaluate their usefulness in the propane/propylene separation. All the adsorption isotherms of SBA-15 measured in the absence of Cu cations were described by the Freundlich equation, while the adsorption isotherms of propane on Cu/SBA-15 were better represented by the Henry equation and those of propylene were satisfactorily described by the Langmuir model in the range P < 100 Torr. The adsorption uptake of propylene increased and that of propane decreased in Cu/SBA-15 as compared to the amounts observed in the SBA-15 sample. The presence of Cu atoms in the adsorbent lattice increased the selectivity towards propylene. Under some working conditions the adsorbed amount of propylene in Cu/SBA-15 sample was totally reversible and the propane uptake, negligible.     

水基传送带润滑剂综述

说明了水基传送带润滑剂的作用机理、性能要求,详细介绍了现有的水基传送带润滑剂的特点,并简单介绍了水基传送带润滑剂的发展前景和趋势。     

中国石化集团原油资源优化配置及建议

介绍了石化集团原油资源现状，分析了原油资源配置过程中存在的主要问题，提出了资源优化配置的原则与基本思路，及实施原油资源优化配置的配套措施和建议。     

IFR-2000阻燃聚丙烯热性能研究

研究了用无卤膨胀型阻燃剂IFR-2000作阻燃剂的阻燃聚丙烯的热性能和阻燃性能。     

Synthesis of nano Sb-encapsulated pyrolytic polyacrylonitrile composite for anode material in lithium secondary batteries

A novel process was proposed to synthesize nano Sb-encapsulated pyrolytic polyacrylonitrile composite for anode material in lithium secondary batteries. The preparation started with the dissolution of SbCl₃ and polyacrylonitrile (PAN) in dimethylformamide (DMF) solution, followed by the addition of KBH₄ to reduce Sb³⁺ in the solution. The Sb composite was obtained by pyrolysis of the Sb/PAN mixture that precipitated out when the DMF solution was added by plentiful water. The TEM analysis showed that about 100-200 nm Sb particles were embedded by the pyrolyzed PAN, which provided a conductive matrix to relieve the morphological change of Sb during electrochemical cycling. As-prepared composite presented good cycleability for lithium storage. The proposed process paves an effective way to prepare high performance alloy based composite anode materials for high performance lithium-ion batteries.     

Studies on crystallization behaviors and crystal morphology of polyamide 66/clay nanocomposites

X‐ray diffraction methods, DSC thermal analysis, and polarized light microscopy (PLM) were used to investigate the structural changes of nylon 66/clay nanocomposites. PA 66/clay nanocomposites were prepared by the method of melt intercalation. The results indicate that the addition of the intercalated organo‐montmorillonite (OMMT) can induce generation of the β‐form crystal of PA 66 and substantially affect the arrangement of molecules in the α‐form crystal, although the crystallinity scarcely changes. Also, the DSC results indicate that the addition of OMMT in the PA 66 matrix leads to increases of crystallization temperatures and the full width at half maximum (FWHM) of the exothermic peaks. Moreover, the viscosity factor is the main influence on FWHM of the exothermic peaks of PA 66/clay nanocomposites. The results of nonisothermal crystallization kinetics show that OMMT has the effect of heterogeneous nucleation and leads to the decrease of the size of the spherocrystal. The heterogeneous nucleation effects of OMMTs influence the mechanism of crystallization and the growth mode of PA 66 crystals. PLM photographs verify that the size of spherocrystal is decreased and visually confirm the theory of crystallization kinetics. © 2004 Wiley Periodicals, Inc. J Appl Polym Sci 95: 756–763, 2005     

聚氨酯防水涂料及其市场发展概况

聚氨酯防水涂料是当今最有效的柔性防水材料之一，介绍了聚氨酯防水涂料的发展状况，并对其市场前景进行了展望。     

Preparation of Protein-Stabilized β-Carotene Nanodispersions by Emulsification–Evaporation Method

This work was initiated to prepare protein-stabilized β-carotene nanodispersions using emulsification–evaporation. A pre-mix of the aqueous phase composed of a protein and hexane containing β-carotene was subjected to high-pressure homogenization using a microfluidizer. Hexane in the resulting emulsion was evaporated under reduced pressures, causing crystallization and precipitation of β-carotene inside the droplets and formation of β-carotene nanoparticles. Sodium caseinate (SC) was the most effective emulsifier among selected proteins in preparing the nanodispersion, with a monomodal β-carotene particle-size distribution and a 17-nm mean particle size. The results were confirmed by transmission-electron microscopy analysis. SC-stabilized nanodispersion also had considerably high ζ-potential (−27 mV at pH 7), suggesting that the nanodispersion was stable against particle aggregation. Increasing the SC concentration decreased the mean particle size and improved the polydispersity of the nanodispersions. Nanodispersions prepared with higher β-carotene concentrations and higher organic-phase ratios resulted in larger β-carotene particles. Although increased microfluidization pressure did not decrease particle size, it did improve the polydispersity of the nanodispersions. Repeating the microfluidization process at 140 MPa caused the nanodispersions to become polydisperse, indicating the loss of emulsifying capacity of SC due to protein denaturation.