俄罗斯圣彼得堡防潮工程建设的若干历史经验

本文系统介绍了俄罗斯圣彼得堡防潮工程规划的发展过程、工程的布置、组成以及工程的设计和当前施工的进展情况.圣彼得堡防潮工程是圣彼得堡城市建设的重要保障,在各个历史时期均得到了俄罗斯各级政府的高度重视.工程的规划、设计和施工建设过程反映了俄罗斯人对防潮管理、人水和谐相处和工程建设中对环境保护认识的发展过程.对圣彼得堡防潮工程建设经验的分析、总结,将对我国水利工作者和位于河口地区的城市防潮和防洪建设与管理起到积极的借鉴作用.     

Effects of arylthio-and arylseleno(methoxy)methanes on acid corrosion of CT 3 steel

The effects of various arylthio-and arylseleno(methoxy)methanes on corrosion of CT3 steel in sulfuric and hydrochloric acid solutions were studied by gravimetric and voltammetric methods. Some compounds of theses classes were found to be effective inhibitors of the acid corrosion of CT3 steel. The presence of the-X-CH₂-O-CH₃ groups (X = S or Se) in aromatic amines and their derivatives enhanced their inhibitive properties. However, because these groups are highly hydrophobic, the molecules of inhibitors should contain other fragments that ensure sufficient solubility. Original Russian Text ? I.N. Chernyad’ev, A.B. Shein, A.N. Nedugov, 2007, published in Zashchita Metallov, 2007, Vol. 43, No. 3, pp. 285–289.     

基于波动方程的聚焦点控制照明叠前深度偏移

 基于波动方程的聚焦点控制照明叠前深度偏移技术借助于差分计算，把速度、密度等介质参数的影响体现在差分计算的矩阵方程中，能够自动适应速度场的任意变化，快速傅里叶变换的使用也加速了波场延拓的计算速度。因此此法兼具有限差分偏移方法和傅里叶偏移方法的优点，既可适应速度场的剧烈变化，又可保证对陡倾地层的成像效果，是目前针对复杂构造最有效的成像方法之一。对于单个聚焦点及其周围的成像步骤为：①采用矩形网格情况下绕射走时的有限差分计算方法生成合成算子；②应用合成算子来合成面炮震源和面波记录；③对合成的面炮震源和面波记录做傅里叶有限差分法波动方程叠前深度偏移，得到该聚焦点及其附近区域的成像结果。按照上述成像步骤，将震源波场和炮集记录依据相应的外推公式进行延拓，最终应用成像条件求取成像值。在地质目标处选取多个聚焦点，可以得到面向目标的控制照明偏移成像，在多个层位上选取多个聚焦点进行控制照明叠前深度偏移，可以得到整块区域的成像。通过对Marmousi模型的试算，取得了较好的效果。     

川东二叠系生物礁油气藏的地震勘探技术

 生物礁油气藏是一种特殊的岩性油气藏，由于其地质特点的多样性和复杂性，使得生物礁的地震勘探难度很大。本文针对川东地区二叠系生物礁的地质特点和资料情况，以生物礁气藏为研究对象，从已知井井震响应特征分析出发，通过地震反射结构分析、神经网络波形分类处理、地震属性分析、三维可视化解释、多参数地震反演等多项地震特殊处理和解释方法，建立了生物礁和生物礁储层的判别模式，形成了有针对性的地震勘探配套技术。其中以伽马、补偿中子及声波为目标曲线的多参数地震反演技术对于预测和评价生物礁特别有效。     

初至波走时层析成像中的正则化方法

 波场的等效性、观测数据的有限性和观测误差等因素导致地球物理反演本身具有严重的多解性，降低这种多解性的一种重要途径就是对反演过程进行约束。传统的初至波走时层析成像方法，通常是在外部对模型空间施加显式的约束和平滑处理，这样就会破坏模型参数与传播算子之间的相关性，难以达到有效利用先验信息的目的, 甚至会影响反演的稳定性。针对这一问题，本文将先验信息分为三类，在此基础上阐述了通过正则化手段将各种先验信息纳入到反演方程当中，替代传统的外部约束模式。理论试验结果表明，正则化方法比外部约束方法有效地提高了反演的精度和分辨率；将该正则化方法应用于实际二维资料处理，也得到了比较好的反演结果。     

薄带铸轧工艺参数的分析和动态模拟

在建立洁净器区薄带坯凝固传热数学模型的基础上,通过计算机分析并动态模拟了铸轧过程中几个重要的工艺参数之间的关系及相互影响,分别模拟和分析了实现稳定铸轧所需的工艺参数范围,包括铸轧速度、浇注温度、熔池深度、铸轧压力、铸轧辊温度、冷却水流量及冷却水温度等重要参数,从理论上解决了铸轧奥氏体不锈钢薄带坯表面质量的关键技术问题,该方法对实际生产具有极其重要的应用价值.     

Effect of electrolysis superheat degree on anticorrosion performance of 5 Cu/（10NiO-NiFe2O4） cermet inert anode

5Cu/(10NiO-NiFe2O4) cermet inert anodes were prepared by cold-pressing and sintering process, and the effect of superheat degree of melting K3AlF6-Na3AlF6-AlF3 on their anticorrosion performance was studied under electrolysis conditions. The results show that, the fluctuation of cell becomes small with increasing of superheat degree, which is helpful to inhibit the formation of cathodic encrustation; the concentration of impurities from inert anode in bath goes up to certain degree, but it is far smaller than those in traditional high-temperature bath. Increasing the superheat degree of melting K3AlF6-Na3AlF6-AlF3 has unconspicuous effect on the contents of impurities in cathodic aluminum. The total mass fractions of Fe, Ni and Cu in aluminum are 15.38% and 15.09% respectively under superheat degree of 95 and 195 ℃. From micro-topography of anode used view, increasing the superheat degree can aggravate corrosion of metal Cu in inert anode, and has negative influence on electrical conductivity of electrode to some extent.     

The intervalley X6→Γ6, L6 scattering time in GaAs measured by ultrafast pump-probe infrared absorption spectroscopy

A direct measurement of the dynamics of electrons in the X₆ valley for a GaAs crystal by time-resolved absorption spectroscopy is reported for the first time. IR picosecond probe pulses were used to monitor the growth and decay of the population in the X₆ valley subsequent to excitation by a 527 nm pump pulse. The intervalley X₆→Γ₆, L₆ scattering time t_x of 0.70 ± 0.50 ps is determined and the crossection for the X₆→X₇ transition is estimated to be 1.8 × 10⁻¹⁶ cm².     

Alkylated ureas: mineralization and evaluation as N sources

An incubation experiment was conducted for 11 weeks to study the mineralization of ten alkylated ureas and urea in soil. Six of the alkylated ureas viz. methylurea(MU), 1,3-dimethylurea(1,3DMU), 1,1-dimethylurea(1,1DMU), ethylurea(EU), 1,3-diethylurea(1,3DEU) and butylurea(BU) and urea mineralized during the experiment. Urea mineralized immediately, while alkylated ureas mineralized after an incubation period ranging from less than a week to four weeks (delay period of mineralization). The delay period increased in the following sequence MU < 1,3DMU < EU < BU < 1,1DMU < 1,3DEU, but after the delay period was over the compounds mineralized almost as rapidly as urea. The delay period varied according to the number of carbon atoms in the alkyl group and their position with respect to each other on the molecule. It appeared to be specific for each compound and was apparently not influenced by the presence of urea or other alkylated ureas. This character can be used to develop mixture of various alkylated ureas to obtain N mineralization at the desired time. Rapid evolution of CO₂ and N₂O was observed during the mineralization of urea as well as alkylated ureas. Increase in soil pH was also observed during this period. The simultaneous ocurrence of these events suggested the formation of urea as an intermediate during the mieralization of alkylated ureas. None of the alkylated ureas showed adverse affect on emergence of wheat seedlings and except DEU and BU at high concentration no other alkylated urea showed any adverse effect on initial growth of wheat seedlings.