BC-8嵌段聚丙烯并非嵌段物

介绍了日本三菱油化公司（现为三菱化学公司）BC-8嵌段聚丙烯的开发经过及实际结构。近年结构分析结果发现BC-8嵌段聚丙烯并非嵌段物，而是由均聚聚丙烯、EPR（乙丙橡胶）以及聚乙烯（链上有少量丙烯单元但并非嵌段物）三者组成的高分子合金。     

“3+1”人才培养模式企业实践教学研究——应用技术大学的教学改革

针对目前"3+1"人才培养模式中企业教学内容构建还不完善、达不到教学目的等问题,根据应用技术大学的人才培养目标要求,以人才的素质培养和专业能力培养为目的,研究和探索企业实践教学对人才培养的意义。     

Isothermal crystallization behavior of polypropylene catalloys

The isothermal crystallization behavior of polypropylene (PP) catalloys and neat PP were studied with differential scanning calorimetry and polarized optical microscopy (POM). The crystallization kinetics of the samples were described with the well‐known Avrami equation. The crystallization rate depended remarkably on the content of the ethylene component in the PP catalloys. The crystallization half‐time increased obviously with the increase of the ethylene component in the PP catalloys. We also observed by POM that in isothermal crystallization, there were many more nuclei in the PP catalloys than that in neat PP and with an increase of the ethylene component, the average size of the spherulites decreased obviously. Even when ethylene content was as high as 27%, the crystallization rate still increased apparently, and this was quite different from common PP melting blends, in which the crystallization rate decreased when the ethylene content was relatively high because of the obstruction effect of dispersed droplets to the spherulite growth of the PP matrix. © 2004 Wiley Periodicals, Inc. J Appl Polym Sci 93: 877–882, 2004     

Dehydrogenation of Cyclohexene on Platinum Nanoclusters on a Thin Film of Al2O3/NiAl(100)

Using a scanning-tunneling microscope, reflection high-energy electron diffraction and photoelectron spectra with synchrotron radiation, we investigated the temperature dependence of the dehydrogenation of cyclohexene (C₆H₁₀) adsorbed on Pt nanoclusters supported on an ultra-thin film of Al₂O₃/NiAl(100). The Pt clusters, grown by vapor deposition, are structurally ordered and exhibit a mean diameter 2.2 nm and height 0.4 nm. The progress of dehydrogenation was monitored through the temporal variation of C 1s photoelectron spectra; analysis of these features revealed that the dehydrogenation of cyclohexene with increasing sample temperature occurs as a sequential process beginning around 150 K, a temperature significantly less than that for Pt single-crystal surfaces. The dehydrogenation behavior, particularly the decomposition into elemental carbon, is found to vary with Pt coverage.     

硕士学位授权点审核系统设计与实现

为了使传统的审核过程信息化、数字化,对硕士学位授权点审核系统将要实现的管理功能进行分析,并介绍了开发技术和发布平台的设计,以及在建设过程中要解决的关键性问题。该系统开发之后,已在本省上线并运行,效果良好。希望该系统的设计、实现和实际运行能够为其他兄弟省份提供借签。     

基于iebook的电子书播放外部视频功能的实现

Exe类型电子书制作软件集成文字内容和小图片非常容易,效果也很不错,但是对集成高品质的音视频、数码照片等大容量数据文件却无能为力。通过对iebook超级精灵自带模板以及Exe电子书文件的深入分析,把flash技术、流媒体对象和file协议有机结合,实现动态加载指定相对路径下的外部视频文件到电子书中,大大提高了iebook超级精灵在处理多媒体方面的实用性。     

Sequence distribution and thermal properties of poly(butylene naphthalate terephthalate)

Poly(butylene naphthalate terephthalate) (PBNT) copolyesters were synthesized from bis(4-hydroxybutyl) terephthalate (BHBT) and bis(4-hydroxybutyl) naphthalate (BHBN) as starting materials. BHBT and BHBN were either homopolymerized or copolymerized at 260∼270 °C in the presence of titanium tetrabutoxide (TBT) as a catalyst to provide PBNT with various compositions. The copolyesters were characterized using inherent viscosity, X-ray, d.s.c., t.g.a. and ¹H NMR. The composition and sequence distribution of the copolyesters was determined from ¹H NMR spectra. The copolyesters exhibited a degree of randomness of about 1, indicating that the reactivity of BHBT and BHBN was almost the same. X-ray and d.s.c. showed PBNT copolyesters to be crystalline polymers. T.g.a. kinetics showed PBNT copolyesters to exhibit higher degradation activation energy, that is, better thermal stability, than PBTs.     

球形和圆柱形变换催化剂宏观活性评价新方法

运用“ 催化反应单元” 概念提出了球形私圆柱形变换催化剂的宏观活性评价新方法, 即催化剂分层整齐排列各粒、各层间填充细小惰性颗粒的排列方式和消除了内外扩散影响的反应器结构以这种方法所做的活性评价试验结果置信度高, 其二级反应速率常数k_T有解析解, 可以此作为变换催化剂宏观活性评价标准与催化剂的填充层数无关.     

高职网络技术专业毕业生就业满意度调查分析

对高职网络技术专业125名毕业生就业满意度跟踪调查,从就业情况、首次就业成功因素、专业课程内容设置、专业教师教学水平、专业教学管理、专业技能重要性、运用专业技能熟练程度、对职业资格证书的意见等九个方面进行分析,为教学改革提供依据。研究大学生就业能力结构及其对就业结果的影响,对调整课程设置与教学内容,构建以能力为核心的课程体系具有重要意义。     

黄荆提取物对几种害虫的杀虫活性

研究了黄荆种子二氯甲烷提取物对5种害虫的杀虫活性以及对天敌异色瓢虫的安全性。结果表明：黄荆提取物对菜青虫、小菜蛾、麦长管蚜和桃蚜都有较高的杀虫活性，尤其是对菜青虫的活性最高，稀释100倍，处理4龄幼虫死亡率可达93．3％。但对大猿叶甲的杀虫活性则很低。黄荆提取物对异色瓢虫幼虫有一定的杀虫活性，但对其成虫无任何影响。本研究结果为开发利用这一新的杀虫植物资源提供了依据。