A qualitative investigation on the importance of boundary layer in pervaporation separation of an aqueous organic reaction

The importance of boundary layer was investigated for the hydrolysis of ethyl acetate using a dense standard poly(vinyl alcohol) (PVA) membrane. A resistance in a series model approach was used to study the effect of a boundary layer for the permeation of aqueous organic mixtures involved in the study. The initial feed mixture consisted of 10% water (H₂O), 40% ethyl acetate (EA), 50% acetic acid (AA), and 0% ethanol (E) (all weight percentage basis). The experiments were conducted at 65°C. The amount of all species in the feed reservoir was found to decrease with time. Selectivity calculations based on a resistance in the series model approach indicates that the boundary layer contributes to selective permeation of aqueous organic compounds. © 1998 John Wiley & Sons, Inc. J Appl Polym Sci 70: 2361–2369, 1998     

Synthesis and evaluation of some novel additives as antioxidants and corrosion inhibitors for petroleum fractions

Benzoxazinone 2 was prepared and reacted with formamide,acetamide,some primary aromatic amines and heterocyclic amines giving the corresponding quinazolone derivatives 3-15 respectively.The reaction of benzoxazinone 2 with hydrazine hydrate and phenyl hydrazine was also studied.Representative compounds of the synthesized products were evaluated as antioxidants and corrosion inhibitors for gasoline engine lubricating oil.The highest antioxidant activities were obtained with compounds 10-15.The optimum concentration recommended for these new additives was found to be 0.lg for 1L ofoil for compounds 13-15.In addition,some of the highly effective antioxidant additives,namely 10-15,were thermally analyzed by using thermogravimetric analysis （TGA） and differential thermal gravimetric analysis （DTGA） techniques and the results indicated that compounds are thermally stable and could be used under thermal conditions.Moreover,a comparison of the oxidation stability between the tested oil containing the prepared products and lubricating oil containing commercial additives was also studied.     

One‐Pot Thioetherification of Aryl Halides Using Thiourea and Alkyl Bromides Catalyzed by Copper(I) Iodide Free from Foul‐Smelling Thiols in Wet Polyethylene Glycol (PEG 200)

In this article, we have developed a new protocol for the thioarylation of structurally diverse alkyl bromides such as benzyl, cinnamyl, n‐octyl, cyclohexyl, cyclopentyl, and tert‐butyl bromides with aryl iodides, bromides and an activated chloride using thiourea catalyzed by copper(I) iodide in wet polyethylene glycol (PEG 200) as an eco‐friendly medium in the presence of potassium carbonate at 80 and 100 °C under an inert atmosphere. The process is free from foul‐smelling thiols which makes this method more practical for the thioetherification of aryl halides. Another important feature of this method is the variety of alkyl bromides which are commercially available for the in situ generation of thiolate ions with respect to the existing protocols in which the less commercially available thiols are directly used for the preparation of arylthio ethers.     

Monitoring of Overhead Transmission Lines: A Review from the Perspective of Contactless Technologies

This paper describes a comprehensive review of non-contact technologies for overhead power transmission lines. Due to ever increasing emphasis on reducing accidents and speeding up diagnosis for automatically controlled grids, real time remote sensing and actuation is the new horizon for smart grid implementation. The technology overview with emphasis on the practical implementation of advanced non-contact technologies is discussed in this paper while considering optimization of the high voltage transmission lines parameters. In case of fault, the voltage and the current exceed limits of operation and hence real time reporting for control and diagnosis is a critical requirement. This paper aims to form a strong foundation for control and diagnosis of future power distribution systems so that a practitioner or researcher can make choices for a workable solution in smart grid implementation based on non-contact sensing.     

Developing two multi-objective evolutionary algorithms for the multi-objective flexible job shop scheduling problem

The aim of this paper is to study multi-objective flexible job shop scheduling problem (MOFJSP). Flexible job shop scheduling problem is a modified version of job shop scheduling problem (JSP) in which an operation is allowed to be processed by any machine from a given set of capable machines. The objectives that are considered in this study are makespan, critical machine work load, and total work load of machines. In the literature of the MOFJSP, since this problem is known as an NP-hard problem, most of the studies have developed metaheuristic algorithms to solve it. Most of them have integrated their objective functions and used an integrated single-objective metaheuristic algorithm though. In this study, two new version of multi-objective evolutionary algorithms including non-dominated sorting genetic algorithm and non-dominated ranking genetic algorithm are adapted for MOFJSP. These algorithms use new multi-objective Pareto-based modules instead of multi-criteria concepts to guide their process. Another contribution of this paper is introducing of famous metrics of the multi-objective evaluation to literature of the MOFJSP. A new measure is also proposed. Finally, through using numerous test problems, calculating a number of measures, performing different statistical tests, and plotting different types of figures, it is shown that proposed algorithms are at least as good as literature’s algorithm.     

Effect of uncertainty parameters on graphene sheets Young’s modulus prediction

Software based on molecular structural mechanics approach (MSMA) and using finite element method (FEM) has been developed to predict the Young’s modulus of graphene sheets. Obtained results have been compared to results available in the literature and good agreement has been shown when the same values of uncertainty parameters are used. A sensibility of the models to their uncertainty parameters has been investigated using a stochastic finite element method (SFEM). The different values of the used uncertainty parameters, such as molecular mechanics force field constants k _r and k _θ , thickness (t) of a graphene sheet and length (L _B ) of a carboncarbon bonds, have been collected from the literature. Strong sensibilities of 91% to the thickness and of 21% to the stretching force (k _r ) have been shown. The results justify the great difference between Young’s modulus predicted values of the graphene sheets and their large disagreement with experimental results.     

Heart rate variability in low birth weight growth restricted children during sleep and wake stages

Intrauterine growth restricted (IUGR) individuals have greater predisposition to develop a metabolic syndrome in later life manifesting itself as obesity, hypertension, type 2 diabetes or cardiovascular disease. Poor fetal growth may alter the regularity mechanism of cardiac autonomic system that is involved in the development of these diseases. The malfunctioning of the cardiac autonomic system assessed by decrease in heart rate variability (HRV) is associated with negative cardiovascular outcomes. This study is aimed at investigating the risk of development of coronary heart disease in IUGR children in later life. For that purpose HRV analysis of normal and growth restricted children was performed during sleep and wake stages. The study group consisted of 9–10 years old, 32 normal, 20 low birth weight IUGR children. The standard time domain HRV metrics (mean RR, SDNN, RMSSD, NN50 and pNN50) and Poincaré indices (SD₁ and SD₂) were used to analyse and compare the RR-interval time series of these groups. The IUGR children showed lower HRV as compared with normal children during both sleep and wake stages. The significantly decreased HRV during sleep provide an evidence of autonomic derangement that may be associated with higher risk of lethal arrhythmias in the IUGR children in later life.     

Influence of electrical discharge machining parameters on cutting parameters of carbon fiber-reinforced plastic

Today the use of high-strength carbon fiber-reinforced plastics (CFRP) composite as a material for many engineering applications is showing an increasing demand in the industry. These composites are replacing the traditional use of steel because they offer many advantages such as very light weight, high strength, and high stiffness associated with good corrosion-resistant properties. Unfortunately, there is little technological knowledge on the electrical discharge machining (EDM) process of high-strength composite materials, especially about the CFRP. In this work, a study has made into the possibility of using EDM process as a means of machining CFRP composite. Various cutting conditions such as peak current, pulse-on time, pulse-off time and open-circuit voltage were selected to perform electrical discharge machining. The effect of electrode rotation was also studied. Optimum cutting conditions and machine settings for EDM were chosen for machining CFRP composites.     

THEORETICAL ANALYSIS OF HIGH AND LOW TEMPERATURE SHIFT CONVERTERS

Theoretical analysis is performed to study catalytic reaction of CO in bolh high and low temperature shift converters. The study includes comparison between model predictions and data collected from local industries in Kuwait. Theoretical models are developed to simulate temperature and conversion profiles of CO in both the high and low shift converters. Good fits are obtained between the theoretical predictions of exit CO conversion and axial temperature profiles and the collected data. Calculations show existence of an optimum feed temperature for the high temperature shift converter. Such an optimum does not exist for the low temperature shift system because of physical limitations on operating conditions. @KEYWORDS: Carbon monoxide, Shift converters.