乌南次凹南屯组高精度层序划分及地质意义

依据岩芯、录井和测井等方面资料,对海拉尔盆地乌尔逊凹陷乌南次凹南屯组内的高精度层序地层格架及其控制下的沉积体系展布特征进行了研究。结果表明,研究区南屯组主要发育有5类层序界面,共划分出3个三级层序和9个四级层序。纵观各层序的残留地层厚度变化,可发现在南屯组沉积时期沉降中心逐渐西移,地层展布特征自下至上由“中厚-东、西薄”逐渐过渡为“西厚-东薄”的变化规律。乌南次凹南屯组沉积时期主要发育有辫状河三角洲、扇三角洲、湖底扇及湖泊4种沉积体系,沉积体系平面展布具有“东西分带”的特点,其中扇三角洲沉积体系主要发育在西部乌西陡坡带,辫状河三角洲沉积体系主要发育在东部乌东缓坡带,不同时期各沉积体系的平面展布特征具有明显的继承性。     

工业流化床反应器的模拟

以两相模型为基础，结合工业生产数据，对串联一并联氧化过程进行模拟，与文献数据比较表明该模型模拟结果能反映实际生产状况，可供流化床反应器设计与开发参考．     

Effect of the processing molding temperature on the crystalline structure and properties of acrylonitrile‐butadiene rubber/trinylon thermoplastic vulcanizates

The effect of the processing molding temperature on the properties and crystalline structure of acrylonitile‐butadiene rubber (NBR)/nylon 6,66,1010 (trinylon) thermoplastic vulcanizates (TPV) was studied. With decreasing molding temperature, the stress at 100% and elongation at break of TPV changed slightly, and the solvent resistance of TPV improved. The best conditions for processing molding were 170°C and 12 min. The crystalline structure of the nylon continuous phase in TPV was investigated by X‐ray diffraction, polarized optical microscopy, and differential scanning calorimetry. The results show that the crystalline structure of the nylon phase in TPV was more perfect/orderly and formed α‐crystalline structure at a processing molding temperature of 170°C. Therefore, the oil resistance of NBR/trinylon TPV clearly improved. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 102: 1374–1379, 2006     

正六边形超高层建筑横风向气弹效应研究

为研究正六边形超高层建筑横风向风致响应和气动阻尼比,开展了一系列多自由度气弹模型风洞试验。测量模型顶部风致位移和加速度响应,基于随机减量法识别了横风向气动阻尼比。结果表明,在顶角迎风时,正六边形超高层建筑易于出现大幅涡振现象,在立面迎风时没有出现涡振现象。顶角迎风时,横风向气动阻尼比随折算风速增大呈现出“先增大到最大正值、再迅速转为最小负值,再平稳回升到零值附近”完整过程。而立面迎风时,横风向气动阻尼比与折算风速近似呈线性关系。最后,建立横风向气动阻尼比的经验评估公式。相关研究可为正六边形超高层建筑的抗风设计和规范完善提供参考。     

双峰PE100级管材料的表征与测试技术

介绍了PE100级管材料的结构特点及其性能的表征方法。该方法与传统的聚烯烃分析测试方法相结合,成为表征PE100等双峰聚乙烯管材料的有效手段。     

Doping the transition metal atom Fe,Co, Ni into C48B12 fullerene for enhancing H2 capture: A theoretical study

The feasibility of transition metal coated fullerene cages M₁₂C₄₈B₁₂(M = Fe, Co, and Ni) for hydrogen storage is investigated by the pseudopotential density functional theory. Fe₁₂C₄₈B₁₂(Co₁₂C₄₈B₁₂ and Ni₁₂C₄₈B₁₂) adsorbs 60(48 and 48) H₂ with moderate average adsorption energy of 0.50(0.45 and 0.32) eV/H₂. The gravimetric hydrogen density of Fe₁₂C₄₈B₁₂(Co₁₂C₄₈B₁₂ and Ni₁₂C₄₈B₁₂) can reach 8.7(6.8 and 6.8) wt%. The Dewar–Kubas interaction dominates the adsorption of H₂ on the outer surface of Fe₁₂C₄₈B₁₂(Co₁₂C₄₈B₁₂ and Ni₁₂C₄₈B₁₂). Therefore, the stable M₁₂C₄₈B₁₂(M = Fe, Co, and Ni) cages can be applied as candidates for hydrogen storage under near-ambient conditions.     

受约束悬臂输流管道颤振的自适应控制

使用压电片作为控制执行元件，对具有弹性支承和非线性运动约束的悬臂输流管道的颤振进行了主动控制。考虑由于压电片伸缩而产生的附加控制力矩，推导出受控输流管系统的非线性运动方程，然后基于Lyapunov稳定性理论设计了模型参考自适应控制系统，并利用数值仿真的方法对该控制方案的有效性进行了验证。通过比较输流管道受控前后的运动响应发现，该控制器对管道非线性系统的周期和混沌等运动都可实施有效的控制。     

Chemical Composition and Antioxidant Activities of Three Polysaccharide Fractions from Pine Cones

The traditional method of gas chromatography-mass spectrometry for monosaccharide component analysis with pretreatment of acetylation is described with slight modifications and verified in detail in this paper. It was then successfully applied to the quantitative analysis of component monosaccharides in polysaccharides extracted from the pine cones. The results demonstrated that the three pine cone polysaccharides all consisted of ribose, rhamnose, arabinose, xylose, mannose, glucose and galactose in different molar ratios. According to the recovery experiment, the described method was proved accurate and practical for the analysis of pine cone polysaccharides, meeting the need in the field of chemical analysis of Pinus plants. Furthermore; the chemical characteristics, such as neutral sugar, uronic acids, amino acids, molecular weights, and antioxidant activities of the polysaccharides were investigated by chemical and instrumental methods. The results showed that the chemical compositions of the polysaccharides differed from each other, especially in the content of neutral sugar and uronic acid. In the antioxidant assays, the polysaccharide fractions exhibited effective scavenging activities on ABTS radical and hydroxyl radical, with their antioxidant capabilities decreasing in the order of PKP > PAP > PSP. Therefore, although the polysaccharide fractions had little effect on superoxide radical scavenging, they still have potential to be developed as natural antioxidant agents in functional foods or medicine.     

Side-Tee混合器内微观混合行为研究

选用碘化物-碘酸盐体系,利用化学探针法对Side-Tee混合器在较高雷诺数下微观混合效率进行了研究。考察了不同影响参数(如雷诺数、体积流率比、反应物浓度、粘度、管径)对Side-Tee混合器微观混合性能的影响,并用离集指数来表征其微观混合特性。结果表明,雷诺数大于12 000后碘化物-碘酸盐反应体系对混合器内微观混合状况不敏感。基于团聚模型,估算出Side-Tee混合器在实验条件下的微观混合时间为3×10-5~3×10-4s。表明这一型式的反应器对于快速反应尤其是纳米材料制备过程具有替代传统搅拌槽反应器的优势。