Controllable defects implantation in MoS<Subscript>2</Subscript> grown by chemical vapor deposition for photoluminescence enhancement

Photoluminescence (PL) of transition metal dichalcogenides (TMDs) can be engineered by controlling the density of defects, which provide active sites for electron-hole recombination, either radiatively or non-radiatively. However, the implantation of defects by external stimulation, such as uniaxial tension and irradiation, tends to introduce local damages or structural non-homogeneity, which greatly degrades their luminescence properties and impede their applicability in constructing optoelectronic devices. In this paper, we present a strategy to introduce a controllable level of defects into the MoS₂ monolayers by adding a hydrogen flow during the chemical vapor deposition, without sacrificing their luminescence characteristics. The density of the defect is controlled directly by the concentration of hydrogen. For an appropriate hydrogen flux, the monolayer MoS₂ sheets have three times stronger PL emission at the excitonic transitions, compared with those samples with nearly perfect crystalline structure. The defect-bounded exciton transitions at lower energies arising in the defective samples and are maximized when the total PL is the strongest. However, the B exciton, exhibits a monotonic decline as the defect density increases. The Raman spectra of the defective MoS₂ reveal a redshift (blueshift) of the in-plane (out-of-plane) vibration modes as the hydrogen flux increases. All the evidence indicates that the generated defects are in the form of sulfur vacancies. This study renders the high-throughput synthesis of defective MoS₂ possible for catalysis or light emitting applications.

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MCF52223的多用户在线编程应用设计

引言 目前,大多数嵌入式系统编程是针对单用户程序,即芯片中只有一个程序。有些情况下,用户希望在芯片中驻留多个用户程序,并能方便更新和选择运行,这就提出了多用户在线编程的需求。随着制造工艺的进步,芯片由8位发展到16位、32位,集成的Flash和RAM也越来越大。     

串并联板材安装机器人结构设计与实现

针对干挂工艺下大尺寸、大质量板材的安装存在自动化程度低、事故发生率高等问题,研制开发了新型的串并联板材安装机器人样机系统.在分析板材安装工艺流程的基础上,确定了机器人总体设计方案,并对机械系统进行了详细的结构设计.根据板材安装的环境特点,提出了基于倾角和激光测距传感信息反馈以及结构光条视觉定位的机器人位姿检测方法.建立...     

微分中值定理的推广及应用

微分中值定理的应用广泛，本文将较系统的归纳总结并加以推广。详细地阐述了微分中值定理的应用并加以分类，从理论和实际的结合上阐明微分中值定理的重要性。     

加快信息技术在继续教育中的应用

现代化的信息技术已被广泛用于教育领域，为此要对现代信息技术的应用现状、发展趋势及对实施继续教育的作用进行了研究。要加强继续教育院校网络系统建设，采用现代远程教育手段，使传统教学模式向多媒体化、网络化、智能化转化。     

Preparation and Characterization of Ni60-Cr<Subscript>3</Subscript>C<Subscript>2</Subscript>-WC/TiC Plasma Welding Surfacing Layer

Using plasma build-up welding technology, Ni60, WC, Cr₃C₂, and TiC composite powders were clad on the surface of the substrate in a certain proportion according to the metallurgical bonding method to increase the bond strength between the coating and the substrate. Scanning electron microscopy and energy dispersive spectroscopy were used to observe the microstructure of the surfacing layer and the chemical composition of the sample. The hardness and wear resistance of the surfacing layer were tested and analyzed by the HV-1000 hardness tester and the impact wear device. The results showed that in the microstructure, fishbone, spider-web, and floral-like structures appeared in the surfacing layer. When the micro-hardness was tested, the depth of the indentation reflected the hardness of the surfacing layer. When analyzing wear resistance, the amount of wear increases with time.     

新型III-V族变形微盘硅基混合激光器

文章中,我们设计了一种连接一个Si的输出波导的新型III-V族变形微盘硅基混合激光器,并通过BCB键合技术以及标准光刻将其制备。相比于传统圆形微盘激光器,该激光器实现了激光从硅波导的定向发射以及单纵模输出。实验上,在连续电流操作下,我们获得了0.31 mW的输出功率以及27 dB的边模抑制比。     

延迟焦化装置放空冷却系统存在问题及对策

某1 Mt/a延迟焦化装置放空冷却系统采用闭式塔内冷却技术,运行过程中出现外甩污油量大、不凝气外排造成全厂火炬系统负荷较大、放空塔顶含硫污水含油率过高造成酸性水汽提装置换热器结垢等问题,同时对延迟焦化装置提出回炼全厂污油的要求.为解决以上问题,装置停工检修过程中对放空冷却系统进行改造,主要内容为:增加放空塔底加热器;增加污油至焦炭塔顶大油气管线做急冷油管线;增加破乳剂注入及不凝气回收系统.改造后可实现该装置自产污油及全厂污油做焦炭塔顶急冷油、放空塔顶酸性水满足酸性水汽提装置进料要求及年回收约2 000 t不凝气等,实现了环保及经济效益的综合效果.     

用于钯催化载体的P改性高孔隙率γ-Al2O3/α-Al2O3泡沫(英文)

提出了一种新方法来制备用于钯催化剂的P-γ-Al₂O₃涂层改性的α-Al₂O₃泡沫。采用聚氨酯模板法,通过优化工艺参数,使陶瓷泡沫的显气孔率达到90.28%,体积密度达到0.45 g·cm^-3,且该泡沫具有可使用强度。将掺有P元素的γ-Al₂O₃涂层涂覆在α-Al₂O₃泡沫上,然后通过超声波辅助浸渍法来装载活性催化相(Pd)。结果表明,含P涂层增加了惰性泡沫的比表面积和弱酸性位点,同时减少了强酸性位点的占比。与无涂层的泡沫相比,改性的泡沫更容易装载活性相,且装载的金属Pd不容易被氧化,CO的催化转化温度(T₅₀,T₉₀)降低了50℃左右。该研究证明了低成本改性α-Al₂O₃陶瓷泡沫在钯催化剂生产中具有极大的应用潜力。     

钛合金板抗12.7mm穿甲燃烧弹厚度效应试验研究

采用12.7 mm穿甲燃烧弹对不同厚度的Ti-6Al-4V钛合金板进行厚度效应试验,研究钛合金板厚度对其防护能力的影响。采用等重钢总穿深及防护系数的方法考核其抗弹性能。结果表明,钛合金板抗小口径枪弹(12.7 mm穿燃弹)板厚在10~30 mm间厚度效应呈现正效应。