压痕残余应力对氮化硅基复合材料阻力曲线行为的影响

通过压痕小裂纹直接量测法获得了ＴｉＣ，ＴｉＮ／Ｓｉ３Ｎ４复合材料的阻力曲线，采用更具合理性的指数经验公式拟合处理实验数据，初步探讨了Ｋ∞，Ｋ＾＊Ｒ，ΔＣ，等参数的物理意义。对压痕残余应力消除前 实验结果进行比较，发现压痕残余应力的消除，提高了材料的极限断裂韧性值Ｋ＾＊Ｒ，却大大减少了裂纹稳态生长的容限，使得材料的脆性行为更为突出。     

尿基复合肥生产技术的改进

通过分析尿基复合肥生产过程中出现的问题，并相应提出技术改进措施，优化操作，对复合肥产量的提高和产品质量的控制都取得了明显的效果。     

两亲性无规共聚物MAA-SMA-PEGMA的表面活性研究

利用功能性单体甲基丙烯酸(MAA)、甲基丙烯酸十八烷基酯(SMA)和聚乙二醇甲基丙烯酸酯(PEG-MA)通过自由基共聚,合成了两亲性共聚物Poly(MAA-SMA-PEGMA)。研究了其结构、临界胶束浓度(CMC)和表面张力,探讨了由共聚物与低分子表面活性剂组成的复配体系。结果表明高低分子表面活性剂复配体系在质量比为5∶5后,体系的表面张力和临界胶束浓度都有所降低,接近于低分子表面活性剂。     

Preparation and properties of PET/PA6 copolymer/montmorillonite hybrid nanocomposite

From in situ polycondensation, a poly(ethylene terephthalate)/Polyamide 6 copolymer/montmorillonite nanocomposite was prepared, after the treatment of montmorillonite (MMT) with a water soluble polymer. The resulting nanocomposites were characterized by X‐ray diffraction (XRD), differential scanning calorimeter (DSC), nuclear magnetic resonance (NMR), dynamic mechanical analysis (DMA), and transmission electron microscopy (TEM). The results of DSC, ¹H NMR, and DMA proved that the nanocomposite synthesized was PET/PA6 copolymer/MMT nanocomposite, not the PET/PA6 blend/MMT nanocomposite. The results of XRD and TEM proved that the dispersion of MMT was improved observably after the introduction of PA6 molecular chain into PET. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 101: 2512–2517, 2006     

碳纤维水泥石电阻测试方法研究

准确测量碳纤维水泥石的电阻率是碳纤维水泥石的压敏和温敏性能得以应用的关键问题之一。已有研究表明，电阻率测量结果准确性受电极的制作形式及电阻的测试方法影响较大。本文在试验的基础上，分析了几种适用于碳纤维水泥石的电极布置形式的特点及两极法和四极法对电阻测试结果的影响。研究表明，碳纤维水泥石电阻宜采用插入式四极法测量。     

Novel method for preparation of quaternary ammonium ionomer from epoxidized styrene–butadiene–styrene triblock copolymer and its use as compatibilizer for blending of styrene–butadiene–styrene and chlorosulfonated polyethylene

A novel method for the preparation of a quaternary ammonium ionomer of styrene–butadiene–styrene triblock copolymer (SBS) was developed by a ring‐opening reaction of epoxidized SBS with triethylamine hydrochloride in the presence of a phase transfer catalyst. The optimum conditions were studied. The ionomer was characterized by quantitative analysis, IR spectroscopy, and ¹H‐NMR spectroscopy. Its water absorbency, oil absorbency, dilute solution viscosity, and use as a compatibilizer for the blending of SBS and chlorosulfonated polyethylene (CSPE) were investigated. The results showed that, under optimum conditions, the epoxy groups can be completely converted to the quaternary ammonium groups. The IR spectrum did not exhibit the absorption peak for quaternary ammonium groups, whereas the ¹H‐NMR spectrum and titration method demonstrated it. With increasing ionic group content, the water absorbency of the ionomer increased whereas its oil absorbency decreased. These indicated the amphiphilic character of the SBS ionomer. The dilute solution viscosity of the ionomer in toluene/methanol (9/1) solvent increased with increasing quaternary ammonium group content. The ionomer was used as a compatibilizer for the blends of SBS and CSPE. The addition of a small amount of the ionomer to the blend enhanced the mechanical properties of the blends: 2 wt % ionomer based on the blend increased the tensile strength and ultimate elongation of the blend nearly 2 times. The blends of equal parts SBS and CSPE behaved as oil‐resistant thermoplastic elastomers. © 2005 Wiley Periodicals, Inc. J Appl Polym Sci 99: 1975–1980, 2006     

高层级轮胎各层帘布裁断角度的计算方法

提出一种新的确定高层级轮胎内外各层帘布裁断角度的方法。根据各层帘布在成品胎内部的材料分布图和在成型机头上的材料分布图，计算该层所在的机头宽度，比较计算的机头宽度和实际的机头宽度，通过调整帘布裁断角度使两者近似相等。以此确定各层帘布的裁断角度，达到内外层帘线均匀伸张的目的。     

7.50-16 12PR轻型载重轮胎的优化设计

介绍轻型载重轮胎的优化设计。采取的主要措施是：减小轮胎外缘尺寸，外直径由８０８ｍｍ减至７９８ｍｍ，断面宽由１９８ｍｍ减至１９５ｍｍ；胎面花纹以纵向花纹为主，肩部为纵横结合花纹并加深肩部通挖花纹沟的深度，改善肩部生热；胎体帘布采用加粗减层的方法，用６层１８７０ｄｔｅｘ／２尼龙帘布代替８层１４００ｄｔｅｘ／２帘布。优化轮胎重量减轻４ｋｇ，轮胎性能符合国家标准。     

微机用于抛物线齿同步带传动强度理论的研究

采用啮合原理与弹性力学复交函数相结合的方法，借助计算机对抛物线齿同步带传动强度理论进行了系统研究，并将整个计算过程编制成ＲＨＤＧＲＡＰＨ软件。利用该软件进行了带齿和轮齿及刀具齿形设计、啮合原理分析、应力和变形计算、刀具可加工最小齿数的确定及加工误差分布计算。     

Crystallization Behaviors of amino-terminated polyurethane (ATPU)-grafted polypropylene

Summary A melt-grafting approach was employed to prepare a novel functional polypropylene(FPP)—amino-terminated polyurethane grafted polypropylene (PP-g-ATPU). The crystallization behaviors of PP and PP/FPP blends were characterized using differential scanning calorimetry (DSC), wide angle X-ray scattering (WAXS) and polarized optical microscopy (POM). The effects of FPP composition on crystallization behavior, crystal transformation, and morphology of PP/FPP crystalline were investigated. The results showed that at a low dosage (<2.0 wt%) ATPU acted as a heterogeneous nucleation agent during the crystallization of PP/FPP blends. However, when the content of ATPU reached 2.0 wt% or higher, ATPU deteriorated the crystallization of PP or PP/FPP blends. The crystallite size decreased and the number of crystallites increased as the ATPU content increased. The Avrami analysis was adopted to describe the isothermal crystallization process. The difference in the exponent n between PP and PP/FPP suggested that the isothermal crystallization kinetics of PP/FPP blends followed a three-dimensional growth via heterogeneous nucleation. In terms of the half-time of the crystallization, t_1/2, the crystallization rate of functional PP blends was faster than that of PP homopolymer at a given crystallization temperature.