液体与糊剂的高精度微定量

微定量是几十年来天天都在使用的、勉强实现相应量输出的一种技术。最出名的一些方法之一是有喷射器与弹筒的定量装置，后者装有油、油脂、颜料等等介质，以此借助于压缩空气脉冲排出需要量。所以，可惜精确量只在粗略范围内是有可能的。为了排出但愿再现量，就必须通过若干试验凭经验进行必要调整。     

Influence of Shaping Condition on Etherification Performance of Hβ Zeolite

Etherification reaction of FCC light gasoline over Hβ zeolite was investigated to decrease the light olefins in motor gasoline while enhancing octane. Etherification activity of several molecular sieve catalysts for FCC light gasoline was studied in a fixed-bed reactor. The influence of pore-enlarging agent (PEG) with different molecular weight, binder (γ-Al₂O₃), and peptizing agent (HNO₃) in the shaping process on etherification activity of Hβ zeolite was studied. The impregnating ways of precursor of oxides and the order of extruding and impregnating were also investigated. The results show that the activity of extruded Hβ zeolite before impregnating precursor of oxides is higher than the reverse order. The best shaping condition obtained was PEG-4000 10%, γ-Al₂O₃ 20%, and HNO₃ 10%. At the optimal reaction condition, the conversion of tert-olefins reached the peak. 62.93%, the yield of TAME, is also high and the technology can be applied to industry as well.     

The use of transparent conducting indium-zinc oxide film as a current spreading layer for vertical-structured high-power GaN-based light-emitting diodes

In this study, the performance of vertical-structured high-power GaN-based light-emitting diodes (VM-LEDs) with a transparent and low-resistant indium-zinc oxide (IZO) film as a current spreading layer (CSL) was investigated. Nickel electroplating and patterned laser liftoff techniques were employed for the transfer of sapphire substrate to nickel substrate. The novel IZO CSL atop n-side-up VM-LEDs offering benefits of superior current spreading ability, larger extraction efficiency, and lower forward voltage drop was demonstrated. As compared to the regular LED without IZO CSL, the use of an IZO CSL with an optimum thickness of around 300 nm leads to an increase in light output power by 97.1 (67.8)% and a decrease in forward voltage drop by 4.9 (15.5)% under an injection current of 350 (800) mA.     

Water bamboo husk reinforced poly(lactic acid) green composites

The water bamboo husk is one of major agricultural wastes in Taiwan. In this study, the powder obtained from the water bamboo husk was added to poly(lactic acid) (PLA) to form novel reinforced biodegradable composites. Morphologies, mechanical properties, and heat resistance of these water bamboo powder reinforced composites were investigated. The results indicate that the char yields were increased as plant powder was incorporated to PLA. In addition, the mechanical properties were also enhanced due to the addition of powders. The increments of storage moduli of PLA were about 50–200%. Moreover, the increments of loss moduli of PLA were about 70–200%. On the other hand, the T_g of PLA was slightly decreased by the addition of powder, and this may improve the brittle characteristics of PLA. Furthermore, this type of reinforced PLA would be more environmental friendly than the artificial additive‐reinforced one. POLYM. ENG. SCI., 2008. © 2008 Society of Plastics Engineers     

Investigation on interior moisture distribution inducing dielectric anisotropy of coals

Dielectric anisotropy phenomenon of coal was detectable by many dielectric measurements. The paper presented that it was attributed to coal interior moisture distribution. A new model describing interior moisture distribution was developed basing on microstructure observation of coal. In the model, coal interior moisture distribution was analyzed and simulated numerically, the relationship between interior moisture distribution and coal dielectric property was constructed, the character of the permittivity varying with moisture content had also been studied and coal dielectric anisotropy was deduced. Corresponding experiment results were well satisfied with the model analysis, demonstrating that the interior moisture content could cause coal dielectric anisotropy.     

Studies of substrate specificities of lipases from different sources

Although lipases are widely applied in a wide variety of reactions, available information on the factors that are responsible for the substrate specificities of lipases from different sources is scarce. In this paper, nine lipase‐producing microorganism strains were isolated from oil‐containing samples. The properties of these enzymes, including pH optima, temperature optima, thermal stability, and pH stability, vary significantly with the different sources from which these lipases were isolated. The substrate specificities of the nine lipases, including fatty acid and positional specificities, were also studied. The fatty acid specificities of the nine lipases were observably different toward 15 substrates with different carbon chain lengths, different saturation degrees and different side chains. The lipases from S₃ Penicillium citrinum (PCL), MJ₁ Aspergillus niger (ANL), MJ₂ Aspergillus oryzae (AOL), YM Bacillus coughing (BCL), S₉ Geotrichum candidum (GCL), and S₁₁ Candida lypolytica (CLL) showed the strongest specificities to short‐chain esters, and the other lipases showed strong selectivity for medium‐ or long‐chain and branched esters. The positional specificities were examined by analyzing the hydrolytic products of triolein catalyzed by the nine lipases, using TLC. The lipases can be mainly classified into two groups by their specificities for the ester bond at position 2 of triglycerides; one group can selectively hydrolyze the ester bond at position 2 of the triglycerides, the other group cannot. All these nine lipases were divided into four groups by hierarchical clustering analysis on the basis of the results of fatty acid and positional specificities.     

Optimal biocompatible solvent design for a two-stage extractive fermentation process with cell recycling

In this study, crisp and fuzzy multiple-goal optimization approaches are respectively introduced to design an optimal biocompatible solvent to a two-stage extractive fermentation with cell recycling for ethanol production. When designing a biocompatible solvent for the extractive fermentation process, many issues, such as extractive efficiency, conversion, amount of solvent utilized and so on, have to be considered. An interactive multiple-goal design procedure is introduced to determine a trade-off result in order to satisfy such contradicted goals. Both approaches could be iterated to solve the interactive multiple-goal design problem in order to yield a trade-off result. However, the crisp optimization design is a tedious task that requires the designer to provide various pairs of the upper bounds for the design problem to obtain the corresponding solution. The fuzzy optimization approach is able to be trade-off several goals simultaneously and to yield the overall satisfactory grade for the product/process design problem.     

Electronic properties of dehydrogenated nanodiamonds: A first-principles study

First-principles calculations using quantum-mechanical density functional theory (DFT) are carried out to study the geometric structure and electronic properties of dehydrogenated nanodiamonds with diameters varying from 0.8 nm to 1.6 nm. The results show that the electronic properties of dehydrogenated nanodiamond are quite different from those of bulk diamond or hydrogenated nanodiamond. Surface atoms play an important role in the electronic structure, especially the states near the Fermi level, for dehydrogenated nanodiamond. In addition, it has been revealed that the size-dependent feature in the electronic properties for dehydrogenated diamonds is also contributed by the surface effect, in addition to the quantum confinement effect.     

Syntheses and Structural Characterization of Triorganotin Derivatives of Bis(carboxymethyl)trithiocarbonate: X-ray Crystal Structures of 2D Network Polymers

Six triorganotin(IV) complexes of the type {(R₃Sn)₂[C₃S₃(COO)₂]}_n (R = C₆H₅ 1; n-Bu 2; PhCH₂ 4; p-F-PhCH₂ 5; o-F-PhCH₂ 6) and {(R₃Sn)₂[C₃S₃(COO)₂]}_n·[EtOH] (R = Me 3) have been synthesized by the reaction of bis(carboxymethyl)trithiocarbonate with triorganotin(IV) chloride in the presence of sodium ethoxide. All complexes were characterized by elemental analysis IR, ¹H, ¹³C and ¹¹⁹Sn NMR spectroscopy. Except for 4–6, all complexes were also characterized by X-ray crystallography. The X-ray date revealed that complexes 1–3 show two-dimensional network polymeric structure in which the geometries of tin atoms are trigonal bipyramid with the axial positions occupied by carboxylic oxygen atoms.     

c-BN color change with bonded water added into the h-BN–Mg system

Cubic boron nitride (c-BN) crystals were synthesized in conditions of high temperature and high pressure (HTHP) when different kinds of bonded water were respectively added into the system of h-BN–Mg. All bonded water used in this work could reduce the temperature of growing c-BN compared to that in the system of h-BN–Mg. The c-BN color could change from black to yellow when certain amounts of bonded water, such as NiSO₄·6H₂O and CuSO₄·5H₂O, Mg(OH)_2, were added. However, c-BN color remained black no matter how much bonded water, such as NiCl₂·6H₂O, CuCl₂·2H₂O, and SnCl₂·2H₂O, was added. The bonded water can be classified into Chlorine-containing bonded water (Cl-BW) and Chlorine-free bonded water (ClF-BW) according to their different characters and effects on the synthesized c-BN color.