Solution Phase Preparative Routes to Nitride Morphologies of Interest in Catalysis

This review assesses the track record and prospects of non-oxide sol–gel and solvothermal routes to nitride materials for use in catalysis. There is a strongly developing body of synthesis methods that yield highly porous materials, some with engineered pore structures, nanocrystalline materials with high surface areas and anisotropic nanocrystals that have their surface area tuned to a particular crystal face. Most of the existing catalytic work on such solution-derived nitrides has focussed on utilising base properties due to surface bound amide and imide groups in silicon (imido)nitride compositions, but there are opportunities to extend these methods to other interesting nitride compositions.     

Emulated single-mode fiber-optic link by use of a linearly chirpedfiber Bragg grating

A compact and low-cost device that emulates a standard and dispersion-shifted 100-km single-mode fiber-optic link at 1550 nm is proposed. The device, composed of a chirped fiber grating and a monitor coupler, is analyzed by simulation and experimentally proved. A chirped fiber grating synthesis procedure and an explanation for both cases are also introduced     

Application of the Monopulse Technique to a Planar Array of Nonlinearly Loaded Straight-Wire Coupled Antennas

The radiation and reception characteristics of a planar array of straight-wire coupled antennas are analyzed by a numerical method in the time domain. The numerical method allows us to calculate some significant magnitudes in an array of coupled wire antennas, such as the frequency dependence of the self- and mutual impedances between antennas. The antennas are fed by a time-varying Gaussian pulse, and they are loaded with various nonlinear elements to exert some control over the radiation field. The results are used to show how the monopulse technique with the slope pattern promises a much higher accuracy of angle measurement for a target.     

Effect of process parameters on the quality of aluminium alloy Al5Si deposits in wire and arc additive manufacturing using a cold metal transfer process

A 3D print device using a cold metal transfer arc welding station to melt a metallic filler wire is developed to build aluminium part by optimising the process parameters. First tests achieved using standard pre-recorded process parameters allow to study the effect of the travel speed and the average welding power on the geometrical characteristics of mono-layer deposits and on walls built by layers superposition. Finally, a parametric study of the effect of each process parameter controlling the shape of the arc current or voltage and the filler wire feeding is carried out in order to try to improve the geometrical regularity of the deposits, and to better understand the effect of each parameter on the melting of the filler wire, its transfer on the support plate, and the geometry of the formed bead.     

Carbopol as a model fluid for studying mixing of pulp fibre suspensions

The selection of operating conditions for a geometrically scaled 1:18 laboratory pulp stock chest in which aqueous carbopol solutions were chosen as the model fluid is detailed. These transparent solutions permit the use of optically based techniques to measure velocity profiles throughout the vessel and thus enable validation of computational models. To ensure that the carbopol solutions mix similarly to pulp fibre suspensions at the new scale it is necessary to select a mixing criterion for conservation. The dimensionless cavern size was chosen as the conserved quantity, although the implications of scaling based on other criteria were also examined. The fibre suspensions and carbopol solutions were modelled as Herschel–Bulkley fluids, based on laboratory measurements.     

Recovery of alicyclobacillus from inhibitory fruit juice concentrates

Growth of Alicyclobacillus in low-pH fruit juices may result in off-odors and off-flavors due to the production of compounds such as guaiacol (2-methoxy phenol). An important step in preventing Alicyclobacillus contamination of fruit juices is the screening of incoming ingredients. Many fruit juice concentrates contain compounds that inhibit Alicyclobacillus growth, but beverages produced from the concentrates may not contain sufficient amounts of the active component to prevent spoilage. Therefore, accurate screening of juice concentrates is essential to prevent false-negative test results and product spoilage. The objective of this study was to evaluate isolation methods for detection of Alicyclobacillus in inhibitory juice concentrates. Recovery of Alicyclobacillus spores from inoculated and naturally contaminated concentrates was compared by using pour plate, spread plate, and filtration methods. Pour plates consistently recovered the lowest number of spores from inoculated concentrates. Spread plating was the most effective method used to recover spores from inoculated apple and pomegranate juice concentrates, while filtration resulted in the highest recovery from cranberry concentrate. When tested on naturally contaminated concentrates, the pour plate method failed to detect Alicyclobacillus in many samples. Filtration was much more effective. The filtration method increased the likelihood of detecting Alicyclobacillus contamination of fruit juice concentrates containing inhibitory compounds.     

Solid-state transformations during diffusion bonding of copper to iron

Solid-state bonding between dissimilar metals, produced at elevated temperatures with the application of a bonding pressure, causes structural changes in the microstructure of the zones nearest to the bond interface. These metallurgical transformations, produced by interdiffusion in the vicinity of the bond, decide the final properties of the joint. In the present paper, such diffusional transformations have been investigated for diffusion-bonded joints of Armco iron and copper with different oxygen contents (ETPC and OFLPC). The formation of iron oxide (wustite) has been observed in the ETPC-Armco iron joints. This oxide did not appear in OFLPC-Armco iron diffusion-bonded joints. This suggests that iron oxide forms by reaction of iron with oxygen dissolved in the ETPC base metal. The formation of copper particles in the iron base matrix, near the bond interface, has been observed. This may be due to two different processes: the solid-state precipitation of copper into iron and the eutectoid reaction (γ →ε +α) at bonding temperatures above 900° C.     

The structure of toluene-doped counterflow gaseous diffusion flames

The structure of gaseous counterflow diffusion flames perturbed with the addition of hundreds of ppm of prevaporized toluene is studied in two distinct flame environments: a blue methane flame stabilized on the fuel side of the gas stagnation plane and an incipiently sooting ethylene flame stabilized on the oxidizer side. The goal is to provide a well-defined testbed in terms of temperature–time history, major species and part of the radical pool, for the examination of reference fuels that are critical components of practical fuel blends. Gas samples are extracted from the flame with fused silica microprobes for subsequent GC/MS analysis and thermocouples and thin filament pyrometry are used to characterize the temperature field. Profiles of critical toluene pyrolysis products and stable soot precursors are compared with computational models using two semi-detailed chemical mechanisms. Results show that in the methane flame some oxygen containing radicals like O and OH are contributing early on to the toluene destruction path. In the incipiently sooting ethylene flame, the primary attack is from H alone. This finding confirms the different challenges that such flames pose to the validation of a chemical kinetic mechanism. The onset of toluene decay in these flames begins at relatively modest temperatures, on the order of 800 K. This reactivity is captured reasonably well by both chemical mechanisms in the methane flame, in the absence of reactants larger than C2, but not so in the ethylene flame, in the presence of a richer, more complex mixture. The aromatic ring opening mechanisms are not adequately modeled in either case. This discrepancy has implications for the modeling of practically relevant fuel blends with both aliphatic and aromatic compounds. The dominant species larger than toluene in the doped methane flame is ethylbenzene, which at least one of the mechanisms reproduces quite well. The largest measured species in the incipiently sooting flame is indene, whose concentration increase due to toluene addition is properly captured by one of the models. The experimental dataset reported here may help identifying future improvements to chemical kinetic mechanisms and complement other reactor datasets lacking the coupling of kinetics and transport of flame environments.     

Asking questions on handwritten document collections

International Journal on Document Analysis and Recognition (IJDAR) - This work addresses the problem of Question Answering (QA) on handwritten document collections. Unlike typical QA and Visual...     

Robotic Locomotion and Piezo1 Activity Controlled with Novel Liquid Marble-based Soft Actuators

A novel soft actuator is designed, fabricated, and optimized for applied use in soft robotics and biomedical applications. The soft actuator is powered by the expansion and contraction of a graphene-containing and encased liquid marble using the photothermal effect. Unfortunately, conventional liquid marbles are found to be too fragile and prone to cracking and failure for such applications. After experimentation, it is possible to remedy this problem by synthesizing liquid marbles encased with polymeric shells–polymerized in situ–for added mechanical strength and robustness. These marbles are shown to have intrinsic photothermal activity. They are then situated in bimorph-type soft actuators where one side of the actuator has a dramatically different Young's modulus than the other, leading to directional actuation which is successfully demonstrated in multistep walking soft robots. The soft actuators are shown to successfully activate the mechanosensitive Piezo protein in a transfected human cell line with high effectiveness and no toxicity. Overall, the liquid marble-powered soft actuators described here represent a new soft actuation methodology and a novel tool for mechanobiological studies, such as stem cell fate and organoid differentiation.