Quantitative characterisation of chemical inhomogeneities in Al-Ag using high-resolution Z-contrast STEM

The incoherent imaging model is applied to interpret high-resolution Z-contrast micrographs. A simple method for a column-by-column resolved characterisation of Ag-rich precipitates in Al-Ag is developed. No information on the detailed imaging process is required. Evaluating the high-angle scattering intensities of Al and Ag by image analysis, the number of Ag atoms contained in individual atomic columns can be determined accurately and moreover, the thickness of the thin foil can be calculated. Multislice simulations confirm the broad validity of the incoherent imaging model for Z-contrast STEM and are used to check the method presented. Finally, the image analysis is applied to experimental Z-contrast images of Guinier-Preston zones in Al-3 at% Ag. The Ag content of the individual atomic columns can be determined with an accuracy better than +/-10%.     

Bioavailability of fine dispersed platinum as emitted from automotive catalytic converters: a model study.

Automobile exhaust catalytic converters emit fine dispersed elemental platinum, Pt (0), in the nanometer range coated on larger aluminium oxide carrier particles. A pre-requisite for a potential systemic toxic effect of the emitted platinum is its bioavailability which was investigated using laboratory animals. To this end, a model substance was synthesised which consisted of aluminium oxide particles < or = 5 microns onto which platinum particles > or = 4 nm were deposited by a calcination process. These particles closely resemble those emitted from automobile exhaust converters. This model substance was applied to female Lewis rats in two doses by intratracheal instillation; the animals were killed after 1, 7, 28 and 90 days. In addition, the model substance was also applied during a 90-day inhalation study. After microwave digestion of the tissues, the platinum was determined in all organs and body fluids by inductively coupled plasma/mass spectrometry (ICP/MS). Platinum was found in the blood, urine and faeces and all important organs (liver, spleen, kidneys, adrenals, stomach, femur). Based on the platinum content determined in the body fluids and all organs (except the lung and the faeces) it was calculated that up to 16% of the platinum was retained in the lung 1 day after intratracheal instillation and up to 30% of the fine dispersed platinum deposited on an average during 90 days inhalation in the lung was bioavailable. Using size exclusion chromatography (SEC) in combination with ICP/MS, it was shown that > or = 90% of the bioavailable platinum was bound to high molecular weight compounds (approximately 80-800 kDa), most likely proteins.     

Capacitively coupled transmission line pulsing cc-TLP––a traceable and reproducible stress method in the CDM-domain

This paper describes a new test method called capacitively coupled transmission line pulsing cc-TLP. It is applied to different test circuits which were mounted on specially designed package emulators with a defined background capacitance. The test results are compared with the ESD thresholds obtained by CDM tests. The cc-TLP results correlate well with the CDM data.     

Mathematics 1868�C2008: a bibliometric analysis

This paper presents a bibliometric analysis of the literature published in the field of mathematics from 1868 to date. The data originate from the Zentralblatt MATH database. The increase rate of publications per year reflects the growth of the mathematics community and both can well be represented by exponential or linear functions, the latter especially after the Second World War. The distribution of publications follows Bradford??s law but in contrast to many other disciplines there is no strong domination of a small number of journals. The productivity of authors follows two inverse power laws of the Lotka form with different parameters, one in the range of low productivity and the other in the range of high productivity. The average productivity has changed only slightly since the year 1870. As far as multiple authorship is concerned the distribution of the number of authors per publication can be described quite well by a Gamma Distribution. The average number of authors per publication has been increasing steadily; while it was close to 1 up to the first quarter of the last century it has now reached a value of 2 in the last few years. This means that the percentage of single-authored papers has fallen from over 95% in the years before 1930 to about 30% today.     

Automatisierte Mikrobild-Analyse zur Klassifizierung von Eisenerz für die Roheisenherstellung

The mineralogical composition and structural properties of iron ores control their behaviour in industrial reduction plants. Micro-images of polished sections are processed by the software VisuMet to determine the proportions of limonite, hematite and magnetite. From the mineralogical composition and the structural properties of iron ores VisuMet assesses their reduction properties at standard reduction conditions.