Application of "subjective gustometry and olfactometry" for determination of reaction kinetics during sensorical changes in technological processes (author''s transl)

Under special conditions the "subjective gustometry and olfactometry" (SGO) allows to combine the concentration with the intensity of flavour components by theoretical means. In this way it can be used for quantitative determination of flavour concentrations as well as for kinetic measurements of sensorical changes. Thus the equations of chemical reaction kinetics (reactionorder, speed and temperature dependancy) can be used for calculation of sensorical changes as theoretically demonstrated for the formation and decomposition of different flavour components. The requirements for indicators, aroma indices, technological processes and storage conditions for a special quality criterium can also be calculated. By using the formation of cooked flavour in apple juice as a practical example the correctness of the theoretical calculations is demonstrated.     

The incremental response of soils. An investigation using a discrete-element model

The incremental stress-strain relation of dense packings of polygons is investigated by using moleculardynamics simulations. The comparison of the simulation results to the continuous theories is performed using explicit expressions for the averaged stress and strain over a representative volume element. The discussion of the incremental response raises two important questions of soil deformation: Is the incrementally nonlinear theory appropriate to describe the soil mechanical response? Does a purely elastic regime exist in the deformation of granular materials? In both cases the answer will be “no”. The question of stability is also discussed in terms of the Hill condition of stability for non-associated materials. It is contended that the incremental response of soils should be revisited from micromechanical considerations. A micromechanical approach assisted by discrete element simulations is briefly outlined.     

An evaluation of methods for prioritizing software requirements

This article describes an evaluation of six different methods for prioritizing software requirements. Based on the quality requirements for a telephony system, the authors individually used all six methods on separate occasions to prioritize the requirements. The methods were then characterized according to a number of criteria from a user's perspective. We found the analytic hierarchy process to be the most promising method, although it may be problematic to scale-up. In an industrial follow-up study we used the analytic hierarchy process to further investigate its applicability. We found that the process is demanding but worth the effort because of its ability to provide reliable results, promote knowledge transfer and create consensus among project members.     

Improved practical support for large-scale requirements prioritising

An efficient, accurate and practical process for prioritising requirements is of great importance in commercial software developments. This article improves an existing cost-value approach in which stakeholders compare all unique pairs of candidate requirements according to their value and their cost of implementation. Techniques for reducing the required number of comparisons are suggested, thus making the process more efficient. An initial approach for managing requirements interdependencies is proposed. A support tool for the improved process has been developed to make the process more practical in commercial developments. The improved process and its support tool have been applied and evaluated in an industrial project at Ericsson Radio Systems AB. The results indicate a pressing need for mature processes for prioritising requirements, and the work presented here is an important step in that direction.     

TEM Investigations of Fine Niobium Precipitates in HSLA Steel

Commercially produced 0.03 % C, 0.08 % Nb, 0.01 % Ti high strength low alloyed (HSLA) steel in the form of 20 mm thick plates was investigated. The steel was thermomechanically processed and the mechanical properties of the steel were evaluated by tensile testing. Using analytical and high resolution transmission electron microscopy the distribution, morphology, composition, crystal structure and particle size of niobium and titanium carbonitrides were observed and identified in these steels. The distribution of the precipitates was found to be nearly random, with occasional occurrence of precipitation free zones. Complex agglomerates with a cubic TiN seed crystal overgrown by a cubic NbC particle were the most commonly observed precipitates. Further TEM analysis in the accelerated cooled and tempered specimens in 1/4 plate thickness did not reveal any evidence that additional precipitation in the ferrite occurred. Precipitation in ferrite was only detected after subsequent cold deformation and tempering of the same samples. By a combination of EFTEM, STEM, HRTEM in addition to EDX spectroscopy, a large population of strain induced NbC precipitates with fcc crystal structure ranging in size down to 2 nm were identified in the ferrite matrix.     

Deformation Behaviour of Iron‐Rich Iron‐Aluminium Alloys with Ternary Transition Metal Additions

The hardness and yield stress at room temperature and the brittle‐to‐ductile transition temperature of Fe‐Al alloys with 16 at.% Al, which is in the range of the so‐called K‐state with possible short‐range ordering reactions, and ternary additions of 0.5 and 4 at.% of the transition metals Cr, Mo, Mn, V, Ti and Ni were studied with respect to possible hardening effects of the ternary additions. The addition of Cr, Mo and Mn to the Fe‐Al alloys produce solid‐solution hardening which corresponds to the hardening effect of Al. Only Ti, V and Ni produce extra hardening effects which cannot be related to solid‐solution hardening. This extra hardening is attributed to possible fine NiAl precipitates in the Fe‐Al‐Ni case and to possible enhanced short‐range ordering and/or fine carbide precipitates in the cases of Fe‐Al‐V and Fe‐Al‐Ti.     

Multipurpose modular experimental station for the DiProI beamline of Fermi@Elettra free electron laser

We present a compact modular apparatus with a flexible design that will be operated at the DiProI beamline of the Fermi@Elettra free electron laser (FEL) for performing static and time-resolved coherent diffraction imaging experiments, taking advantage of the full coherence and variable polarization of the short seeded FEL pulses. The apparatus has been assembled and the potential of the experimental setup is demonstrated by commissioning tests with coherent synchrotron radiation. This multipurpose experimental station will be open to general users after installation at the Fermi@Elettra free electron laser in 2011.     

Microscopy under pressure--an optical chamber system for fluorescence microscopic analysis of living cells under high hydrostatic pressure

High hydrostatic pressure (HHP) becomes more and more interesting for life science research, since it can be employed to inactivate various cells. To directly monitor "cells under pressure," the development of an optical high-pressure chamber is required. Therefore, an optical pressure chamber that can be used for up to 300 MPa was constructed. This chamber has already been described as a tool for in situ observation of dynamic changes of microscopic structures in bright field as well as phase contrast. In combination with an inverted microscope, we obtained brilliant microscopic color pictures with an optical resolution more than 0.56 microm. Here, we demonstrate the capabilities of the HHP cell, in combination with epifluorescence microscopy. Using a nonadherent human B-cell line (Raji, ATCC CCL 86), stained with the fluorescent dyes propidium iodide, Hoechst 33342, or dihexyloxacarbocyanine iodide, we were able to show that the system is suitable to perform fluorescence microscopic analyses, with pressures up to 300 MPa, with viable mammalian cells.