Determination of standard gibbs energies of formation of Cr2N and CrN

The standard Gibbs energies of formation of Cr₂N and CrN have been measured by an equilibration technique and by using thermogravimetry and differential thermal analysis (TG-DTA) at temperatures ranging from 1232 to 1523 K. The results are expressed as follows:

Synthesis and characterization of K2NiF4-type CaLnCoO4 (Ln = Sm and Gd)

K₂NiF₄-type CaLnCoO₄ (Ln = Sm and Gd) has been synthesized at 1173 or 1223 K in air using citric acid (CA) and ethylene glycol (EG). CaLnCoO₄ (Ln = Sm and Gd) has an orthorhombic structure with the space group Bmab. The average particle sizes are approximately 300 nm for CaSmCoO₄ and approximately 170 nm for CaGdCoO₄, respectively. The global instability index (GII) indicates that the crystal structure of CaGdCoO₄ is more stable than that of CaSmCoO₄. CaLnCoO₄ (Ln = Sm and Gd) is a p-type semiconductor and shows paramagnetic behavior above 5 K. The 1/χ-T curve of CaSmCoO₄ deviates from the Curie-Weiss law, whereas the 1/χ-T curve of CaGdCoO₄ follows the Curie-Weiss law in the temperature range of 5 ≤ T ≤ 300 K. From the values of the observed effective magnetic moment (μ_eff) of CaLnCoO₄ (Ln = Sm and Gd), it is considered that the spin state of the Co³⁺ ion is low.     

纳米碳洋葱的研究进展

纳米碳洋葱是一种以C60为核心的同心多层球面套叠结构的碳分子。从结构形貌、制备方法等角度讨论纳米碳洋葱和纳米石墨微粒的区别。着重对纳米碳洋葱的形成进行分析和比较,认为纳米石墨微粒可能是先形成一定数量的壳层然后分别沿壳层向外和向内推进长大,石墨化程度具有方向性;而纳米碳洋葱是先形成C60,然后以螺旋机制生长。最后从能量角度讨论纳米碳洋葱的稳定性,并对其修饰改性、化合物嵌插以及性能方面的研究进行评述。     

COMPLEXITY RELAXATION OF THE TENSOR PRODUCT MODEL TRANSFORMATION FOR HIGHER DIMENSIONAL PROBLEMS

The Tensor Product (TP) model transformation method was proposed recently as an automated gateway between a class of non‐linear models and linear matrix inequality based control design. The core of the TP model transformation is the higher order singular value decomposition of a large sized tensor, which requires high computational power that is usually outside of a regular computer capacity in cases of higher dimensionality. This disadvantage restricts the utilization of the TP model transformation to models having smaller dimensionality. The aim of this paper is to propose a computationally relaxed version of the TP model transformation. The paper also presents a 6 dimensional example to show the effectiveness of the modified transformation.     

Novel structure of GaAs-based interdigital-gated HEMT plasma devices for solid-state THz wave amplifier

Theoretical analysis of potential distribution in the interdigital-gated high electron mobility transistor (HEMT) plasma wave device was carried out. The dc I–V characteristics of capacitively coupled interdigital structure showed that uniformity of electric field under the interdigital gates was improved compared to the dc-connected interdigital gate structure. Admittance measurements of capacitively coupled interdigital gate structure in the microwave region of 10–40 GHz showed the conductance modulation by drain–source voltage. These results indicate the existence of plasma wave interactions.     

Hypomagnesemia as a predictor of mortality in hemodialysis patients and the role of proton pump inhibitors: A cross‐sectional, 1‐year,retrospective cohort study

Introduction This study aimed to evaluate the association between proton pump inhibitor (PPI) use and serum magnesium levels, and the role of hypomagnesemia and PPI use as a risk factor for mortality in hemodialysis patients. Methods An observational study, including a cross‐sectional and 1‐year retrospective cohort study. The study comprised 399 hemodialysis patients at a single center, and was conducted from January to September 2014. Multiple linear regression analysis was used to investigate the independent relationship between serum magnesium levels and baseline demographic and clinical variables, including PPI and histamine‐2 receptor antagonist use. Cox regression model was used to identify lower serum magnesium level and PPI as a predictor of 1‐year mortality. Findings Serum magnesium levels were lower with PPI use than non‐PPI use (2.39 ± 0.36 vs. 2.56 ± 0.39 mg/dL, P < 0.001). Multiple linear regression analysis showed that PPI use, low serum albumin levels, and low serum potassium and high‐sensitivity C‐reactive protein (hs‐CRP) levels were significantly associated with low serum magnesium levels. A total of 29 deaths occurred during the follow‐up period. According to Cox regression analysis stratified by hs‐CRP, only high serum hs‐CRP levels (>4.04 mg/L) in association with low serum magnesium levels was an independent risk factor for 1‐year mortality (hazard ratio: 2.92; 95% CI: 1.53–6.40, P < 0.001). Discussion Serum magnesium levels are lower in PPI use. In the inflammatory state, a low serum magnesium level is a significant predictor of mortality in hemodialysis patients.     

Lit-Sphere extension for artistic rendering

The Lit-Sphere model proposed by Sloan et al. (Proceedings of Graphics Interface 2001, pp. 143–150, 2001) is a method for emulating expressive artistic shading styles for 3D scenes. Assuming that artistic shading styles are described by view space normals, this model produces a variety of stylized shading scenes beyond traditional 3D lighting control. However, it is limited to the static lighting case: the shading effect is only dependent on the camera view. In addition, it cannot support small-scale brush stroke styles. In this paper, we propose a scheme to extend the Lit-Sphere model based on light space normals rather than view space normals. Owing to the light space representation, our shading model addresses the issues of the original Lit-Sphere approach, and allows artists to use a light source to obtain dynamic diffuse and specular shading. Then the shading appearance can be refined using stylization effects including highlight shape control, sub-lighting effects, and brush stroke styles. Our algorithms are easy to implement on GPU, so that our system allows interactive shading design.     

INTERACTIVE FUZZY PROGRAMMING BASED ON FRACTILE CRITERION OPTIMIZATION MODEL FOR TWO-LEVEL STOCHASTIC LINEAR PROGRAMMING PROBLEMS

In this article, we focus on two-level linear programming problems involving random variable coefficients in objective functions and constraints. Following the concept of chance constrained programming, the two-level stochastic linear programming problems are transformed into deterministic ones based on the fractile criterion optimization model. After introducing fuzzy goals for objective functions, interactive fuzzy programming to derive a satisfactory solution for decision makers is presented as a fusion of a stochastic approach and a fuzzy one. An illustrative numerical example is provided to demonstrate the feasibility of the proposed method.     

Random fuzzy multi-objective linear programming: Optimization of possibilistic value at risk (pVaR)

This paper considers multiobjective linear programming problems (MOLPP) where random fuzzy variables are contained in objective functions and constraints. A new decision making model optimizing possibilistic value at risk (pVaR) is proposed by incorporating the concept of value at risk (VaR) into possibility theory. It is shown that the original MOLPPs involving random fuzzy variables are transformed into deterministic problems. An interactive algorithm is presented to derive a satisficing solution for a decision maker (DM) from among a set of Pareto optimal solutions. Each Pareto optimal solution that is a candidate of the satisficing solution is exactly obtained by using convex programming techniques. A simple numerical example is provided to show the applicability of the proposed methodology to real-world problems with multiple objectives in uncertain environments.     

Residual mode filters and H ∞ control for a class of infinite-dimensional discrete-time systems

An H _∞, control problem with measurement feedback.for infinite-dimensional discrete-time (IDDT) systems whose homogeneous parts are described by Riesz-spectra operators is considered. The aim is to construct a finite-dimensional stabilizing controller for the IDDT system that makes the H _∞ norm of the closed-loop transfer function less than a given positive number δ. For that purpose, we first formulate the IDDT system as an IDDT system in l² and derive a finite-dimensional reduced-order system for the IDDT system in l². A stabilizing controller that makes the H _∞ norm of the closed-loop transfer function less than another positive number is then constructed for the reduced-order model. The finite-dimensional controller together with a residual mode Jilter plays a role of a finite-dimensional stabilizing controller that makes the H _∞ norm of the closed-loop transfer function less than δ for the original IDDT system, if the order of the residual mode filter is chosen suficiently large.