Synthesis and surface-active properties of trimeric-type anionic surfactants derived from tris(2-aminoethyl)amine

Trimeric-type anionic surfactants (3C_ntaAm, where n is a hydrocarbon chain length of 8, 10, or 12) with three hydrocarbon chains and three carboxylate headgroups were synthesized from tris(2-aminoethyl)amine, and their properties were investigated by surface tension, electrical conductivity, dynamic and static light-scattering, fluorescence of pyrene, and emulsification power techniques. The critical micelle concentrations (CMC) of 3C_ntaAm were 0.00092–0.00834 mmol dm⁻³, and the surface tensions at the CMC were 33.3–39.9 mN m⁻¹. The areas per molecule occupied by 3C₁₀taAm and 3C₁₂taAm were extremely small, showing they were highly compact at the air/water interface. In addition, adsorption or micellization behavior of 3C_ntaAm was estimated by parameters such as pC ₂₀ (the efficiency of surface adsorption), CMC/C ₂₀ (the ease of adsorption relative to the ease of micellization), and ΔG _M ^o (Gibbs energy of micellization). Dynamic and static light-scattering mesurements of 3C_ntaAm showed a hydrodynamic radius of 45–61 nm above the CMC and aggregation numbers of 10–82 at the CMC, respectively. The fluorescence intensity ratio of the first to the third band in the emission spectra of pyrene started to lower from far above the CMC for 3C₈taAm and 3C₁₀taAm, and below the CMC for 3C₁₂taAm. This suggests that loose micelles or premicellar aggregates are formed in solutions. Mixtures of aqueous solutions of 3C_ntaAm and toluene formed oil-in-water-type emulsions, and the stabilizing abilities were in the order of 3C₈taAm>3C₁₀taAm>3C₁₂taAm. The degree of emulsification of 3C₈taAm remained at 69% after 24 h of standing. Thus, 3C_ntaAm exhibited unique properties superior to monomeric or dimeric surfactants that were significantly influenced by their hydrocarbon chain lengths.     

Stereocomplex formation between enantiomeric poly(lactic acid)s. X. Binary blends from poly(D-lactide-CO-glycolide) and poly(L-lactide-CO-glycolide)

Binary blend films from lactide-rich poly(D -lactide-co-glycolide) (PDLG) and poly(L -lactide-co-glycolide) (PLLG) were obtained by casting methylene chloride solutions of the two mixed copolymers with different D- and L-lactide contents (X_DI and X_LI ), and their crystallization was studied by differential scanning calorimetry (DSC). Four combinations were selected from the binary (A-B) blends: mixing of the same polymer [X_DI (A) = X_DI (B) or X_LI (A) = X_LI(B)], blending under X_DI (B) = X_LI (A), blending of a D -lactide homopolymer [X_DI(B) = 1] with other PDLGs, and blending of a D -lactide homopolymer [X_DI(B) = 1] with other PLLGs. Racemic crystallites were exclusively formed between PDLG and PLLG when they had high lactide unit contents. The melting point and enthalpy of fusion of the racemic crystallites decreased with a decrease in X_DI of PDLG or X_LI of PLLG, suggesting that glycolide units in the polymer disturbed the growth of the racemic crystallites. A similar behavior was also observed for the homocrystallization in nonblended copolymer films. Homocrystallites composed entirely either of D -lactide unit or L-lactide unit sequences were formed when one component was crystallizable and the other component had the same sign of optical rotation or very different lactide content. An interesting finding was that even nonhomocrystallizable lactide-poor PDLG and PLLG could form racemic crystallites when both were blended. © 1994 John Wiley & Sons, Inc.     

The aqueous thermal polycondensation of asparagine and isoasparagine and the structure of polyaspartic acid

Summary Both asparagine and isoasparagine were converted into polyaspartic acids by refluxing the corresponding aqueous solutions at neutral pH in the presence of a salt. The properties of the resulting polyaspartic acids were studied. The dissociation behavior of the carboxyl groups in the polypeptides were studied by the potentiometric titration. The analysis of the titrational data was performed by a modified Speakman's method. The analysis show that both polyaspartic acids prepared from asparagine and isoasparagine have - and -aspartyl residues and the ratio of - and -aspartyl residues is 75 2585 15. A possible mechanism for the formation of - and -aspartyl residues in the polymer was discussed.     

A new method for the control of dilute suspension sedimentation by horizontal movement

This research addresses some factors that control the stability of dilute suspensions in sedimentation processes under a dynamic environment. Experimental and numerical studies were conducted about the sedimentation velocity control of dilute suspensions by horizontal movement for particle concentrations up to 8 wt.%. Nearly monodispersed particles were used as test particles. The effects of horizontal movement speed and amplitude on particle sedimentation process were investigated. Under stationary conditions, particles settle in only one vertical direction because of gravitational force. However, complicated particle motions arise under moving conditions due to circulation flow in horizontal moving conditions. The results show that horizontal movement can reduce the particle settling velocity or maintain the stability of the suspension.     

Analysis of Anal Secretions from Phlaeothripine Thrips

The anal secretions of 16 phlaeothripine thrips species (Thysanoptera: Phlaeothripidae) were studied, including a reinvestigation of three species previously reported. A total of 37 components were detected, including hydrocarbons, acetates, terpenes, carboxylic acids, a quinone, an aromatic compound, and a pyranone compound. The secretions of all species were composed of some of these components, with Xylaplothrips inquilinus possessing as many as 11 components. Of these components, (Z)-9-octadecene, (Z)-9-nonadecene, nonadecadiene, octanoic acid, decanoic acid, geranial, neral, alpha-pinene, beta-pinene, caryophyllene, 2-hydroxy-6-methylbenzaldehyde, and two unidentified monoterpenes [UK-I (M+136) and UK-II (M+168)] were detected for the first time. The chemicals were species-specific; four Liothrips species and three Holothrips species could be distinguished from each other and their congeners by the GC profiles of the ether extracts of their anal secretions. The anal secretions of gall-inducing thrips commonly contained terpenes. of which citral (a mixture of geranial and neral) and beta-acaridial repelled ants or had antifungal activity. The findings suggest that these terpenes play a defensive role and prevent galls from fungal infestation. 3-Butanoyl-4-hydroxy-6-methyl-2H-pyran-2-one, found from three Holothrips spp., caused paralysis in ants. Chemical analysis of anal secretion components is a useful method for the classification of tubuliferan species that are difficult to distinguish on the basis of morphological characters.     

Evaluation of a useful method to identify snow‐covered areas under vegetation – comparisons among a newly proposed snow index,normalized difference snow index,and visible reflectance

Objective methods of monitoring snow‐covered areas by optical remote sensing were evaluated using synchronous observations conducted with the passage of the Landsat‐7 satellite over the plains of Niigata prefecture, one of the snowiest regions in Japan. The observations were conducted in the springs of 2002 and 2003. Snow‐covered areas were identified using three methods: (1) visible (red) reflectance, (2) Normalized Difference Snow Index (NDSI) which uses visible and shortwave‐infrared reflectances, and (3) a newly proposed snow index called S3 which uses visible, near‐infrared and shortwave‐infrared reflectances. The Snow‐Cover Ratio (SCR) was defined as the ratio of the number of pixels in snow‐covered areas to the total number of pixels in an image. The threshold value for the three indices used to identify snow‐covered areas was defined as 50% of SCR, which converged to nearly the same value regardless of the images analysed. Under clear conditions, visible (red) reflectance can identify snow‐covered areas accurately if no vegetation is present. NDSI can distinguish snow‐covered areas from mixels (mixed pixels) of snow and vegetation by referring to the Normalized Difference Vegetation Index (NDVI). S3 can distinguish snow‐covered areas from mixels of snow and vegetation without any reference data. S3 is, therefore, more useful than NDSI because it automatically distinguishes snow‐covered areas from mixels of snow and vegetation.     

Anomalous hall conductivity in the vortex state of the organic superconductor κ-(BEDT-TTF)2Cu(NCS)2

Hall effect measurements in the vortex state of the quasi two-dimensional (Q2D) organic superconductor -(BEDT-TTF)₂Cu(NCS)₂ are reported. The sign of the Hall conductivity changes with field and temperature in the vortex state. The Hall conductivity is described as the sum of the two terms resulting from the quasiparticle ( H) and the vortex motion ( 1/H). The sign of the latter term depends on the current direction in Q2D plane. The behavior can be explained by the anisotropic motion of the charged vortex in the anisotropic Q2D plane.The authors would like to thank Professor K. Takanaka and Professor H. Ebisawa for stimulating discussions. This work was carried out at HFLSM, IMR, Tohoku University and partially supported by Grant-in-Aid for Scientific Research from the Ministry of Education, Science and Culture of Japan.     

Analysis of the sound of the Japanese voice using real-time spectral analysis

Voice signal processing requires real-time processing. For this reason, a new method which updates the spectrum by using input data is proposed. In this method, analysis in the time-frequency domain is executed as well as wavelet transform. Vowels /i/ and /e/ consist of fundamental, harmonic, and high frequency waves. These high frequency waves determine the sounds of /i/ and /e/. These high frequency waves may also exist in /a/ and /o/. In this article, we analyze these high frequency waves by using a new analyzing method, and we show the constitution of high frequency waves. Since the waveform of a consonant does not repeat, the analysis cannot be performed like the analysis of the high frequency wave of a vowel. In a consonant, we show the fluctuation of the spectrum with time.     

Improving the estimation of leaf area index by using remotely sensed NDVI with BRDF signatures

A new vegetation index, the Normalized Hotspot-signature Vegetation Index (NHVI), is proposed for a better quantitative estimation of leaf area index (LAI) than with the remotely sensed normalized difference vegetation index (NDVI), especially in the boreal forest. To obtain this new index, the Hotspot-Dark-spot index (HDS) (Lacaze et al., 2002) was introduced. HDS is calculated by the difference between the strongest vector (hotspot) and the weakest vector (dark-spot) of bi-directional reflectance, a given tract of vegetation returns in the reflecting solar position, and the geometric structure of the vegetation canopy, which are poorly represented by NDVI alone. The validity of NHVI was statistically tested using two field data sets of multi-angular observations and LAI from the boreal forests of Canada; one set was our own observations, and the other was from the Boreal Ecosystem-Atmosphere Study (BOREAS). The range of linear correspondence of NHVI with LAI is much wider than that of NDVI alone, indicating significant representation of leaf biomass in the canopy geometry captured by HDS. With the technical innovation of multi-angular remote-sensing and kernel-driven models in the future, this index has the potential to provide a more accurate evaluation of regional and global LAIs.     

Electrical characterization of high-k gate dielectrics fabricated using plasma oxidation and post-deposition annealing of a Hf/SiO2/Si structure

High permittivity (high-k) gate dielectrics were fabricated using the plasma oxidation of Hf metal/SiO₂/Si followed by the post-deposition annealing (PDA), which induced a solid-phase reaction between HfO_x and SiO₂. The oxidation time and PDA temperature affected the equivalent oxide thickness (EOT) and the leakage current density of the high-k dielectric films. The interfacial structure of the high-k dielectric film/Si was transformed from HfO_x/SiO₂/Si to HfSi_xO_y/Si after the PDA, which led to a reduction in EOT to 1.15 nm due to a decrease in the thickness of SiO₂. These high-k dielectric film structures were investigated by X-ray photoelectron spectroscopy. The leakage current density of high-k dielectric film was approximately four orders of magnitude lower than that of SiO₂.