Solution‐Processible Multi‐component Cyclometalated Iridium Phosphors for High‐Efficiency Orange‐Emitting OLEDs and Their Potential Use as White Light Sources

The synthesis and photophysical studies of several multifunctional phosphorescent iridium(III) cyclometalated complexes consisting of the hole‐transporting carbazole and fluorene‐based 2‐phenylpyridine moieties are reported. All of them are isolated as thermally and morphological stable amorphous solids. Extension of the π‐conjugation through incorporation of electron‐pushing carbazole units to the fluorene fragment leads to bathochromic shifts in the emission profile, increases the highest occupied molecular orbital levels and improves the charge balance in the resulting complexes because of the propensity of the carbazole unit to facilitate hole transport. These iridium‐based triplet emitters give a strong orange phosphorescence light at room temperature with relatively short lifetimes in the solution phase. The photo‐ and electroluminescence properties of these phosphorescent carbazolylfluorene‐functionalized metalated complexes have been studied in terms of the coordinating position of carbazole to the fluorene unit. Organic light‐emitting diodes (OLEDs) using these complexes as the solution‐processed emissive layers have been fabricated which show very high efficiencies even without the need for the typical hole‐transporting layer. These orange‐emitting devices can produce a maximum current efficiency of ～ 30 cd A^–1 corresponding to an external quantum efficiency of ～ 10 % ph/el (photons per electron) and a power efficiency of ～ 14 lm W^–1. The homoleptic iridium phosphors generally outperform the heteroleptic counterparts in device performance. The potential of exploiting these orange phosphor dyes in the realization of white OLEDs is also discussed.     

Wavelet transform coding for MCP error images using quadtree decomposition and ECVQ

This paper proposes a new wavelet transform video coder which employs motion compensation, wavelet decomposition, and entropy-constrained vector quantization (ECVQ), in sequence. Each of layered subimages obtained from wavelet decomposition is segmented into basic blocks, and then the blocks are selectively encoded by ECVQ according to the energy of the samples. We introduce an efficient method to encode the map representing which blocks are encoded, based on inter-band prediction followed by a quadtree encoding. The proposed coder uses a simple forward analyzer in order to optimize the encoding parameters and introduces a preprocessing of signals which normalizes the input vectors of ECVQ in order to reduce the image-dependency of ECVQ codebooks. Simulation results show that our video coder provides good PSNR (peak-to-peak signal-to-noise ratio) performance and efficient rate control.     

Explicit rate allocation algorithm of generalised max-min fairnessfor ATM ABR services

A distributed explicit rate allocation algorithm based on the generalised max-min (GMM) fairness principle is proposed for the available bit rate (ABR) ATM services. Compared with a similar algorithm for GMM, it employs fewer fields in an RM cell and imposes lower requirements on the computational capability of the switches     

Comparison of radiation‐induced hydrocarbons for the identification of irradiated perilla and sesame seeds of different origins

BACKGROUND: Perilla and sesame seeds, a rich source of energy, are commonly utilized in different forms in many countries. During the post‐harvest period, they are contaminated with insects as well as microbes that may have importance for keeping quality and quarantine, and thus they can be treated with ionizing radiation for insect disinfestation and microbial decontamination. Reliable and routine methods to identify whether or not a food has been irradiated are needed to help consumers' understanding of irradiated food and promote international trade. In the present study, fat‐derived hydrocarbons from irradiated perilla seeds and sesame seeds of Korean and Chinese origin were analyzed in order to identify irradiation treatment by comparing their properties during the post‐irradiation period. RESULTS: Gas chromatographic–mass spectrometric analysis showed that several saturated hydrocarbons, such as tetradecane, pentadecane, hexadecane and heptadecane, were found in the non‐irradiated control samples, while four radiation‐induced unsaturated hydrocarbons (R² = 0.647–0.997), such as 1,7,10‐hexadecatriene (C_16:3), 1,7‐hexadecadiene (C_16:2), 6,9‐heptadecadiene (C_17:2) and 8‐heptadecene (C_17:1), were detected in all irradiated samples at 0.5 kGy or higher, with variations according to sample and origin. Concentrations of all hydrocarbons were reduced during storage and could not be detected in 0.5 kGy irradiated Chinese sample of either seed after 8 months. CONCLUSION: Radiation‐induced hydrocarbons (C_{16:3, 16:2, 17:2, 17:1}) could be used as markers to identify irradiated perilla and sesame seeds of both Korean and Chinese origin at 1 kGy or higher for 8 months' storage at room temperature. Copyright © 2009 Society of Chemical Industry     

Recycling wasted scallop shell as an adsorbent for the removal of phosphate

Lots of scallop shells were discharged from local restaurants and marine product manufacturers around the city of Gangneung and most of them are dumped into landfill. The scallop shell was recycled as an adsorbent for the removal of phosphate. The shell size greatly affected phosphate removal. One gram of shell having diameter of around 45 μm removed 100 mg/L of phosphate in 3 h while that of 3 mm hardly removed in 80 h. Phosphate removal was not much affected by the pH in the range of 2.0–7.5 but it was scarcely removed beyond pH 8.0. Higher temperature was preferred for phosphate removal but the removal efficiency was almost constant over 35 °C. The maximum phosphate removal capacity was obtained through Langmuir isotherm plotting and it was as high as 23.0 mg-phosphate/g-shell. On the purpose of enhancing the adsorption capacity of scallop shell, it was treated with chemical reagents such as HCl, NaOH, NH₄HCO₃ and EDTA. HCl-treatment increased the adsorption capacity of the shell having diameter of 45 μm by 39.8% than raw scallop shell, but the treatment showed negligible effect on the shell of 1000 μm in diameter. Packed-bed containing HCl-treated scallop shell with 500 μm in diameter removed 20 mg/L of phosphate stably for 15 days and the removal efficiency was over 85% throughout operation.     

Navigating a robotic swarm in an uncharted 2D landscape

Navigation is a major issue in robotics due to the necessity for the robots’ course of movement. Navigation consists of two essential components known as localization and planning. Localization in robotics refers to one’s location with reference to a well known position inside the map. Planning is considered as the computation of a path through a map which represents the environment. This given path would be chosen based on the potential of the problem so that the expected destination would be achieved. As such, a reliable map is essential for navigation without which robots would not be able to accomplish the goals. In navigational approaches, reliability of the map would be challenged due to the dynamic and unpredictable nature of real-world applications. It is, consequently, crucial to implement solutions for searching such environments—those affected by dynamic and noisy constraints. In the present study, two enhanced versions of particle swarm optimization (PSO) called area extension PSO (AEPSO) and cooperative AEPSO (CAEPSO) are employed. During the study, AEPSO and CAEPSO are employed as decision-makers and movement controllers of simulated robots (hereafter referred to as agents). The agents’ task is to seek for survivors in realistic simulations based on real-world hostile situations. This study examines the feasibility of AEPSO and CAEPSO on uncertain and time-dependent simulated environments. The simulations follow two phases of training and testing model. Agents use past knowledge gathered during the training phase in their testing phase. The study addresses the impacts of past knowledge, homogeneity and heterogeneity in robotic swarm search. The results demonstrate the feasibility of CAEPSO as robot controller and decision-maker.     

Extrusion coating performances of iPP/LDPE blends

The performance of iPP/LDPE blends in an extrusion coating process was investigated in the terms of coating width and draw‐down ability. It is well known that iPP alone is not proper because of lower draw‐down ability with severe draw resonance in elongational flow. To obtain higher draw‐down ability, iPP was blended with LDPE. Additionally, iPPs having different molecular weight distribution (MWD) were used in this study to find out the effect of MWD of iPP on neck‐in and draw‐down ability. It was observed that iPP/LDPE blend with narrower MWD exhibits narrower coating width and higher draw‐down ability. Neck‐in and draw‐down ability were correlated with shear and elongational properties obtained by several rheological measurements. From this study, the major rheological parameters affecting extrusion performance in iPP/LDPE blends could be assessed. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2009