Growth of intermetallic phases in Al/Cu composites at various annealing temperatures during the ARB process

The purpose of this study is to discuss the effect of annealing temperatures on growth of intermetallic phases in Al/Cu composites during the accumulative roll bonding (ARB) process. Pure Al (AA1100) and pure Cu (C11000) were stacked into layered structures at 8 cycles as annealed at 300 °C and 400 °C using the ARB technique. Microstructural results indicate that the necking of layered structures occur after 300 °C annealing. Intermetallic phases grow and form a smashed morphology of Al and Cu when annealed at 400 °C. From the XRD and EDS analysis results, the intermetallic phases of Al₂Cu (θ) and Al₄Cu₉ (γ₂) formed over 6 cycles and the AlCu (η₂) precipitated at 8 cycles after 300 °C annealing. Three phases (Al₂Cu (θ), Al₄Cu₉ (γ₂), and AlCu (η₂)) were formed over 2 cycles after 400 °C annealing.     

Phase transformations of 24Cr-14Ni-0.7Si stainless steel under different aging conditions

This study discusses the development of a phase transformation in 24Cr-14Ni-0.7Si stainless steel after aging under various aging temperatures, times, and N₂/Air ratios. The observation of OM indicated that the initial state of δ-ferrite in the test material appeared as complete dendrite structures at short aging times and then exhibited lacy and dispersed structures when the aging time increased. This led to a gradual austenitization transformation as the nitrogen/air ratio increased, accelerating the δ/σ phase transformation and retarding the δ/γ phase transformation at the same time. The δ/σ phase transformation was dominant when the aging temperature was 800 °C. A line scanning analysis of the EPMA showed that the X-ray spectrum of Cr at the δ/γ interphase boundary was raised. In addition, Si showed lower X-ray spectrum energy after the δ/γ phase transformation. Clearly, Si had a stabilizing effect on the δ-ferrite and σ-phase. Furthermore, it had the fastest precipitation ratio for the δ/σ phase transformation at 800°C among all aging temperatures.     

Process quality improvement of a qualitative response with dynamic characteristic

To achieve quality improvement in manufacturing environments, the design of experiment (DOE) and Taguchi methods are two efficiency approaches to address such problems. Applying those methods to resolve quality improvement frequently focuses on the measurable quality response (or quantitative response). However, the complexity of products or processes is gradually increased and due to the limitation of measuring equipment, the quality response could not be directly measured. Visual inspection or measurement is then used to judge the quality for nonmeasurable response (or qualitative response). Basically, for assessing the quality of a qualitative response, it is initially divided into several classes or ordered categories. As for customers’ requirements gradually changing and applications’ flexibility gradually increasing, a dynamic structure for this process will be another important consideration for manufacturers. That is, it causes the work of quality improvement to be dynamically analyzed. Dr. Taguchi had proposed a dynamic method to analyze such issues. However, only several studies focused on quality improvement of a qualitative response during the static characteristic. Parameter optimization approaches were seldom proposed to address quality improvement of a qualitative response with the dynamic characteristic. Therefore, in this study, we proposed an integrated parameter-optimization approach to resolve quality improvement of a qualitative response with dynamic characteristics. An illustrative example, quality improvement of lead twist during the stamping process for lead frame manufacturing at Science-based park in Taiwan, is employed to demonstrate the effectiveness of the proposed approach.     

Interpenetrating polymer networks of polyurethane and polystyrene ionomers

Interpenetrating polymer networks (IPNs) and linear blends of polyurethane (PUN) and poly(styrene–acrylic acid) (PSAA), which contain mutually opposite charge groups, i.e., tertiary amine and carboxyl groups, respectively, were synthesized through simultaneous bulk polymerization. Physical and mechanical properties of these IPNs and linear blends are discussed in the present paper. The tensile strength of both PUN/PSAA IPNs and linear blends has shown to increase with an increase of acrylic acid (AA) content in PSAA in any PUN/PSAA composition. A maximum value emerged in both polymer systems with 30 mol % AA in PSAA and the PUN/PSAA ratio of 25/75. A minimum swelling ratio as well as a maximum density was also observed in the IPNs and linear blends, respectively, related to this PUN/PSAA ratio. From dynamic mechanical analysis, two distinct relaxation transitions for the IPN or linear blend without AA in the system have merged into a single broad transition as the AA was introduced into PSAA. Two-Phase morphology was observed from scanning electron microscopy studies for the polymer systems in the absence of charge groups; however, one-phase morphology was observed when the charge groups were introduced.     

Solvent- and glow-discharge-induced surface wetting and morphological changes of poly(ethylene terephthalate) (PET)

The effects of argon glow discharge and selected organic solvents on the surface wettability of poly(ethylene terephthalate) (PET) and on the wettability decay of glow discharged PET films were studied. Glow discharge in argon (30 W/1 min) drastically reduced the initial water contact angle (CA) measurement of PET from 67.0 to 26.2°. The glow-discharge-induced wetting, however, decayed during the first 7 days and stabilized at 33.1°. Treatments in dimethyl sulfoxide, dimethyl formamide, pyrdine, and water at 80°C caused some improvement in surface wettability as shown by decreases of water CAs in the range of 53–56°. When the solvent and glow discharge treatments were applied consecutively on PET, additive effects on improving surface wettability were observed. The stabilized water CAs of the solvent-and-glow-discharged films ranged from 25.0 to 32.1° depending upon the solvent type. The solvent treatments prior to glow discharge either reduced the extent of CA decay or the time taken to reach stabilization on PET films. Scanning electron microscopic evaluation showed no difference between the solventtreated and the untreated PET surfaces, but a finely etched surface was observed on the glow discharged PET at a 40,000 magnification and above. The distinctly different surface of the DMSO-and-glow-discharged PET indicated that morphological changes on PET surface were induced by the solvent.     

Noncatalytic polymerization of ethylene glycol and epoxy molecules for rigid polyurethane foam applications

The study investigated an approach to incorporate modified epoxidized soy‐based vegetable oil polyol as a replacement for petroleum‐based polyether polyol and to substantially reduce the isocyanate loading in the rigid foam formulation. Noncatalytic polymerization of epoxidized bodied soybean oil and ethylene glycol (EG) was carried out in a closed batch reaction. Cleavage of the oxirane rings and hydroxyl group attachment at optimum conditions provided the desired polyol products. The polyols were characterized based on its hydroxyl numbers, acidity, viscosity, iodine number, and Gardner color index for quality purposes. Reactions of oxirane ring and EG were verified by spectroscopic FTIR. Crosslinking performance was evaluated by extractability analysis on the polyurethane (PU) elastomer wafers. Rigid foaming performed at 50 and 75% petroleum‐based polyether polyol replacements have shown excellent thermoinsulating and mechanical properties compared with epoxidized soybean oil (ESBO) alone or petroleum‐based polyether polyol alone. A reduction of up to 8% of the polymeric diphenylmethane diisocyanate was achieved using the synthesized ESBO‐EG‐based polyols. A higher average functionality polyol is key component to the reduction of isocyanate in PU synthesis. © 2009 Wiley Periodicals, Inc. J Appl Polym Sci, 2009     

Synthesis of ultrafine poly(styrene‐maleic anhydride) and polystyrene fibers by electrospinning

Fiber formation from atactic polystyrene (aPS) and alternating poly(styrene‐maleic anhydride) (PSMA) synthesized by free radical polymerization (AIBN, 90°C, 4 h) were investigated by electrospinning from various solutions. aPS was soluble in dimethylformamide (DMF), tetrahydrofuran (THF), toluene, styrene, and benzene, whereas PSMA was soluble in acetone, DMF, THF, dimethylsulfoxide (DMSO), ethyl acetate, and methanol. aPS fibers could be electrospun from 15 to 20% DMF and 20% THF solutions, but not from styrene nor toluene. PSMA, on the other hand, could be efficiently electrospun into fibers from DMF and DMSO at 20 and 25%, respectively. Few PSMA fibers were, however, produced from acetone, THF, or ethyl acetate solutions. Results showed that solvent properties and polymer–solvent miscibility strongly influenced the fiber formation from electrospinning. The addition of solvents, such as THF, generally improved the fiber uniformity and reduced fiber sizes for both polymers. The nonsolvents, however, had opposing effects on the two polymers, i.e., significantly reducing PSMA fiber diameters to 200 to 300 nm, creating larger and irregularly shaped aPS fibers. The ability to incorporate the styrene monomer and divinylbenzene crosslinker in aPS fibers as well as to hydrolyze PSMA fibers with diluted NaOH solutions demonstrated potential for post‐electrospinning reactions and modification of these ultrafine fibers for reactive support materials. © 2009 Wiley Periodicals, Inc. J Appl Polym Sci, 2009     

Determination of mass transfer resistance during absorption of carbon dioxide by mixed absorbents in PVDF and PP membrane contactor

In this study, the absorption of carbon dioxide by the absorbent which was composed of 2-amino-2-methyl-l-propanol (AMP) + piperazine (PZ) or methyldiethanolamine (MDEA) + piperazine (PZ) in polyvinylidinefluoride (PVDF) and polypropylene (PP) membrane contactors werewas examined. Three resistances were considered in each hollow fiber, i.e., liquid-film diffusion, membrane diffusion, and gas-film diffusion. The mass transfer resistance of membrane k_m was influenced by the wetting ratio using an absorbent with higher reaction rate. The wetting ratio was affected by contact angle between the membrane and absorbent and the viscosity of absorbent. The calculated absorption rates considering wetting ratio of membrane and using the modified correlation equation of gas-phase mass transfer coefficient were reasonably agreeable to those of measured ones (standard deviation, 4%). The fractional resistance of each transport step during the experiments was then determined. The rate-controlling step was dominated by the resistance of gas-film diffusion with mixed absorbents. The absorption rates of CO₂ increase with the increasing of gas flow rates in the most experimental cases. The resistance of liquid-film diffusion was only important using an absorbent with lower reaction rate. The rate-controlling step was the membrane diffusion only at higher gas flow rate with the absorbent composed of AMP and PZ in PVDF hollow fiber membrane contactor.     

Laser-Induced Silver Nanoparticles on Titanium Oxide for Photocatalytic Degradation of Methylene Blue

Silver nanoparticles doped on titanium oxide (TiO₂) were produced by laser-liquid interaction of silver nitrate (AgNO₃) in isopropanol. Characteristics of Ag/TiO₂ (Ag doped TiO₂) nanoparticles produced by the methods presented in this article were investigated by XRD, TEM, SEM, EDX, and UV-Vis. From the UV-Vis measurements, the absorption of visible light of the Ag/TiO₂ photocatalysts was improved (additional absorption at longer wavelength in visible light region) obviously. The photocatalytic efficiency of Ag/TiO₂ was tested by the degradation of methylene blue (MB) in aqueous solution. A maximum of 82.3% MB degradation is achieved by 2.0 wt% Ag/TiO₂ photocatalyst under 2 h illumination with a halogen lamp.     

Colour appearance shifts in two different‐sized viewing conditions

This study assessed the effect of size on colour appearance, using a colour matching paradigm where two sizes were presented in a setting similar to a normal colour selection interface. Twelve colours sampling the entire range of the colour spectrum were chosen as target stimuli. The target stimuli consisted of either a large (30° by 50°) or a small (0.5° by 0.5°) test field displayed on a cathode ray tube (CRT). In the experiment, a set of small colour samples consisting of the target and its neighboring colours was presented on the screen. Fifty‐seven participants were asked to pick a colour from the sample set that appeared to exactly match the target. Results in CIECAM02 showed a consistent increase in the apparent brightness (Q) but some decrease in saturation (s) for the larger field. Hue shifts were observed to form a systematic pattern. We noticed a discernable trend showing that, for targets of bluish or purplish colour hues, the accuracy of colour matching is lower and colour difference is greater in the condition of the large viewing field. © 2010 Wiley Periodicals, Inc. Col Res Appl, 2010