Hydrothermal Reaction Mechanism and Pathway for the Formation of K2Ti6O13 Nanowires

Calculations and detailed first principle and thermodynamic analyses have been performed to understand the formation mechanism of K₂Ti₆O₁₃ nanowires (NWs) by a hydrothermal reaction between bulk Na₂Ti₃O₇ crystals and a KOH solution. It is found that direct ion exchange between K⁺ and Na⁺ plus H⁺ interactions with [TiO₆] octahedra in Na₂Ti₃O₇ promote the formation of an intermediate H₂K₂Ti₆O₁₄ phase. The large lattice mismatch between this intermediate phase and the bulk Na₂Ti₃O₇ structure, and the large energy reduction associated with the formation of this intermediate phase, drive the splitting of the bulk crystal into H₂K₂Ti₆O₁₄ NWs. However, these NWs are not stable because of large [TiO₆] octahedra distortion and are subject to a dehydration process, which results in uniform K₂Ti₆O₁₃ NWs with narrowly distributed diameters of around 10 nm.     

A Study on NMR and GC/MS Spectra of the Isomers of Linear Hexyl Naphthalene

The GC/MS and NMR analysis of the reaction products of naphthalene with 1-bromohexane were reported. The products obtained were suggested to have six isomers of linear hexylnaphthalene and the structure of each isomer was determined by GC/MS and NMR spectra. For the first time, the unique chemical shift data were obtained. The content of each isomer calculated by ¹H NMR and ¹³C NMR spectra was consistent with that by GC/MS spectra, which confirmed the accuracy of NMR data.     

工程造价管理经验在房地产中的应用

随着近几年我国房地产事业蓬勃发展，因此研究和探讨工程概预算的技术数据是项目管理工作中的重要信息，也是房地产加强工程造价有效控制的重要途径，本文结合工作实际，就如何积累工程造价经验数据，谈一点个人的体会。     

Fault-aware Communication Mapping for NoCs with Guaranteed Latency

As feature sizes shrink, transient failures of on-chip network links become a critical problem. At the same time, many applications require guarantees on both message arrival probability and response time. We address the problem of transient link failures by means of temporally and spatially redundant transmission of messages, such that designer-imposed message arrival probabilities are guaranteed. Response time minimisation is achieved by a heuristic that statically assigns multiple copies of each message to network links, intelligently combining temporal and spatial redundancy. Concerns regarding energy consumption are addressed in two ways. First, we reduce the total amount of transmitted messages, and, second, we minimise the application response time such that the resulted time slack can be exploited for energy savings through voltage reduction. The advantages of the proposed approach are guaranteed message arrival probability and guaranteed worst case application response time.     

EPP在便携式数据采集系统中的应用

分析了并口处于EPP(增强型并行端口)模式时和单片机进行数据交换的原理.介绍了有关EPP的基本特性、信号定义、操作模式及其程序设计方法,设计了基于EPP协议的便携式数据采集系统,给出了技术解决方案,讨论了系统的硬件接口电路和软件编程.方案具有可靠性高、速度快、软硬件设计简捷等优点.     

（E）-2-壬烯酸合成方法的改进

(E)-2-壬烯酸是有机合成的一种重要中间体,我们利用Knoevenagel反应机理,改进了(E)-2-壬烯酸的合成工艺,在不使用脱水剂条件下,使用少量吡啶作催化剂,获得了83%的反应收率。     

近年新疆能源工业回顾与展望

新疆是我国的能源资源富集区，“九大煤田”、“十八条大河”、“三大油田”、“九大风区”资源储量丰富，品质优良，是新疆的优势资源之一，不但为新疆的开发建设提供了雄厚的物质基础，同时也将是我国重要的能源开发接替地。     

矿石中金的快速测定

研究了活性炭纤维滤布富集分离的条件和解脱方法,并利用微波溶样、液珠萃取比色法测定矿石中的金。该方法的测定范围为(0.5~xx)×10-6,相对标准偏差RSD为3.2%,可用于矿石中金的野外快速测定。     

华北油田鄚东地区深井钻井液技术

鄚东地区钻井过程中经常发生垮塌、卡钻、井漏等复杂事故。该地区深井钻井采用了抑制性及封堵性较强的铵基沥青树脂高密度钻井液体系,并根据地层特点,对不同井段制定了相应的钻井液维护处理措施。结果表明,该钻井液体系抑制性好,抗温、抗污染能力强,性能稳定,成功地控制了复杂事故的发生,满足了该地区深层钻井的要求。     

聚合物复合材料填充剂的改性

在前人研究的基础之上，归纳总结了聚合物复合材料填充剂的种类，综述了对其进行表面改性的目的、条件、方法、工艺以及对改性结果的表征等。文章还分析了影响填充聚合物复合材料性能的因素，指出了今后发展的方向。