NiCuZn铁氧体的组成对PZT/NiCuZn材料性能的影响

首先用sol-gel法制得了Pb0.95Sr0.05(Zr0.52Ti0.48)O3纳米粉料(简称PZT),然后采用固相反应法制备了ζ(PZT:NiCuZn)为1:9和3:7的两种复合材料。研究Ni0.26-xCu0.19+xZn0.55Fe2O4铁氧体的组成对低温烧结复合材料的显微结构、电磁性能的影响。结果表明:当x=0.02的化学组成为主配方时,复合材料可实现900℃低温烧结,且ζ(PZT:NiCuZn)为1:9的复合材料的μi高达92,Q值为39,ε′为19;而ζ(PZT:NiCuZn)为3:7的复合材料的μi为26,Q值为19,ε′为32。     

尖晶石结构磁介电材料的研究进展

随着通信技术的发展,对无限通信设备的集成度有了更高的要求,天线小型化成为目前重要的研究方向。等磁介电材料是一种既具有磁导率又具有介电常数,且磁导率和介电常数几乎相等的材料,使用等磁介电材料作为天线的基板,能有效的减小天线的尺寸,提高带宽,增加辐射效率。铁氧体是由Fe2O3和一种或多种金属氧化物复合而成,具有较高的磁导率和介电常数,由于其同时具有磁特性和介电特性,是一种潜在的等磁介电材料。综述了近几年尖晶石结构磁介电材料的国内外研究进展,着重讨论了掺杂改性对烧结温度、磁导率、介电常数、直流电阻等电磁特性的影响。最后指出目前研究中存在的问题,并展望了该材料在未来发展的方向。     

Correlation between crystal structure and modified microwave dielectric characteristics of Cu2+ substituted Li3Mg2NbO6 ceramics

Structural characteristics exert significant influences on microwave dielectric properties, and ion substitution is widely adopted to modify material performances by adjusting the crystal structure. In this work, low loss Li₃Mg_2-xCu_xNbO₆ (x?=?0–0.04) ceramics were prepared by Cu²⁺ substitution. The impacts of Cu²⁺ substitution for Mg²⁺ sites on the microwave dielectric characteristics and crystal structure were discussed in detail. Rietveld refinement results implied that a single Li₃Mg₂NbO₆ phase was formed. Additionally, a dense and homogeneous microstructure with grain sizes of 7–9?μm could be achieved, and moderate Cu²⁺ substitution could significantly promote the grain growth. The correlation between microwave dielectric characteristics and crystal structure was discussed by calculating some structural parameters. The ε_r was determined by the polarizability. The Q?×?f was influenced by the packing fraction. The τ_f value was dependent on the NbO₆ octahedron distortion, and the τ_f value could be adjusted to near zero for x?=?0.02. Typically, the Li₃Mg_2-xCu_xNbO₆ (x?=?0.02) composition exhibited remarkable microwave dielectric performances: ε_r?=?15.75, Q?×?f?=?92,134?GHz (9.86?GHz) and τ_f?=??2?ppm/°C, making it a promising candidate for temperature-stable millimeter-wave applications.     

硅基超材料太赫兹波电光调制器

该文基于超材料结构设计制造并表征了一款工作在0.34 THz频率下的太赫兹电光调制器。该调制器通过超材料结构加载电压,从而在超材料结构开口处获得强电场用以输运恒定激光照射下硅基产生的光生载流子。通过电压调制信号调制太赫兹波,实现了调制深度从9%增加到50%,其调制速度达到30 kHz。     

澳大利亚英语的特点

通过对澳大利亚方言的俚语、词汇、语法与伦敦英语进行比较，发现其构成的特点，并对澳大利亚英语进行大致的了解，从而进一步认识澳大利亚的语言文化。     

Effects of Bi2O3-Nb2O5 additives on microstructure and magnetic properties of low-temperature-fired NiCuZn ferrite ceramics

NiCuZn ferrite with superior magnetic performance is vital ceramic material in multilayer chip inductors (MLCI) applications. In this study, low-temperature-sintered Ni_0.22Cu_0.2Zn_0.58Fe₂O₄ ferrite ceramic doped with 1.0?wt% Bi₂O₃-x?wt% Nb₂O₅ (where x?=?0.0, 0.1, 0.2, 0.3, 0.4 and 0.5) was synthesized via solid-state reaction method. Effects of Bi₂O₃-Nb₂O₅ additives on microstructures and magnetic properties of NiCuZn ferrite ceramics sintered at 900?°C were systematically investigated. Results indicate that an appropriate amount of Bi₂O₃-Nb₂O₅ composite additives can significantly promote grain growth and densification of NiCuZn ferrite ceramics when sintered at low temperatures. Specifically, samples doped with 1.0?wt% Bi₂O₃ and 0.4?wt% Nb₂O₅ additives exhibited excellent initial permeability (~ 410 @ 1?MHz), high cutoff frequency (~ 10?MHz), high saturation magnetization (~ 54.92?emu/g), and low coercive force (~ 20.32?Oe). These observations indicate that NiCuZn ferrite ceramics doped with appropriate amounts of Bi₂O₃-Nb₂O₅ additives are great candidate materials for MLCI applications.     

Synthesis and photocatalytic H2-production activity of plasma-treated Ti3C2Tx MXene modified graphitic carbon nitride

Plasma processing technology, as a promising method to enhance photocatalytic activity of catalyst, is gradually attracting extensive interest from researchers. However, the main mechanism of plasma-treated photocatalyst on hydrogen production is not clear. In this work, 2D Ti₃C₂T_x MXene is selected as a co-catalyst of graphitic carbon nitride (g-C₃N₄), which carries out a plasma treatment (500°C) under N₂/H₂ atmosphere. Due to plasma treatment, there is a higher proportion Ti–O functional groups on surface of layered Ti₃C₂T_x MXene, especially for Ti⁴⁺. The obtained g-C₃N₄/p-Ti₃C₂T_x photocatalyst with sandwich-like structure shows an enhanced photocatalytic activity. The rate of hydrogen generation of CN/pTC3.0 sample without Pt co-catalyst is 25.4 and 2.4 times that of pure g-C₃N₄ and CN/TC3.0 samples, respectively. The improved photocatalytic activity is attributed to presence of Ti⁴⁺ due to plasma treatment, which can capture photo-induced electron from g-C₃N₄ and improve the separation of electrons and holes after visible light irradiation. The cyclic hydrogen production of the photocatalyst demonstrates good photocatalytic stability. In addition, this method of plasma treatment under N₂/H₂ atmosphere is feasible to develop a high-performance co-catalyst, which can be extended to other photocatalysts with two-dimensional structure for photocatalytic water-splitting applications.     

纳米晶抗EMI材料及相应滤波器研究

基于Ｈｅｒｚｅｒ理论,对Ｃｏ基薄带材料的纳米晶化及软磁性能改善进行了大量实验研究,解决了晶化中薄带变脆和内层绝缘磁耦合问题,成功地研制出用于射频域的抗ＥＭＩ无源滤波器。测试结果表明其有着优良的抗噪性能。     

Mechanism study of the Mn-substituted magnesium borate: Decreased sintering temperature and improved dielectric property

The influence of manganese substitution on the sintering and dielectric properties of Mg₃B₂O₆ (MBO) was studied, and the detailed mechanism of variation was discussed using density functional theory calculations. The characterization method involved a network analyser, differential–thermal analyses, thermomechanical analyses, X-ray diffraction, and scanning electron microscopy. Manganese substitution formed a two-phase system (MBO and Mg₂B₂O₅), improved the dielectric property, densified the microstructure, lowered the activation energy, decreased the crystallite size, modified the band structure property, and strengthened the covalency of MgO₆ octahedron. The 7% mole substitution of manganese to magnesium improved the dielectric properties of MBO to 7.06 for ε_r and 61 100 GHz at 15 GHz for Q × f, −54.8 ppm/°C for τ_f. The intrinsic densification temperature decreased from 1350 to 1175°C with 97.7% relative density.     

塔式太阳能热发电系统性能模型及其仿真研究

结合塔式太阳能热发电系统中主要设备的机理模型和变工况下的运行方式,建立一套能完整反映电站工作过程的性能模型.发电系统在太阳法向直射辐照度扰动下的动态过程研究结果表明:吸热器出口熔盐温度、表面最高温度、散热功率的过渡过程较平缓,效率在瞬时突变后会逐渐恢复到接近扰动发生前的水平;吸热器出口熔盐温度、表面最高温度、散热功率与...