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991.
Patricia Muñoz-Escalona Shreyes Melkote Kai Liu 《Journal of Materials Engineering and Performance》2005,14(5):582-590
In recent years, the finite element method (FEM) has become the main tool for simulating the metal cutting process because
research based on trial and error is time consuming and requires high investment. Early studies were done by different investigators.
In this research AISI 52100, hardened steel (62 HRC) was selected for an orthogonal machining process as well as metal cutting
simulation using the software DEFORM-2D. This software is based on a forging process and has been adapted to an orthogonal
machining process. The results of simulated cutting forces were compared with experimental cutting force data to validate
the orthogonal cut simulation. Also, the surface roughness was measured, and the influence of the stress, strain, and temperature
on the surface roughness was studied. 相似文献
992.
993.
稳定态二氧化氯杀菌剂的制备及应用 总被引:3,自引:0,他引:3
稳定态二氧化氯(C1O2)是一新型杀菌消毒剂,具有高效、广谱、安全的特性,适用范围广,不产生对人体有害物质。介绍了稳定态ClO2的性质、检测、制备条件及其在有关领域的应用。 相似文献
994.
995.
996.
在反应温度为45~75℃,NY 健化剂浓度为0.093mol/L,水比为6~10的反应条件下,对均相催化水合法合成乙二醇动力学进行了研究。测定了反应速率常数及反应过程中溶液 pH 值的变化。依据实验结果,提出了反应机理,建立了反应动力学方程,并利用 Levenberg-Marquardt 方法回归了动力学参数。研究结果表明:在 NY 催化剂存在下,均相催化水合法合成乙二醇反应对环氧乙烷浓度是一级反应,其表观活化能为71113.8 J/mol 和指前因子3.05×10~9 min~(-1)。相对直接水合法而言,NY 催化剂降低了反应的活化能,大大提高了反应速度。 相似文献
997.
Tanya Kmecko Xiaoyu Wang Patty Wisian-Neilson 《Journal of Inorganic and Organometallic Polymers and Materials》2007,17(2):413-421
Summary The surface reactivity of poly(methylphenylphosphazene), PMPP, and its derivatives containing silane, PMPP-SiH, and alcohol,
PMPP-OH, substituents was investigated. These polymers were fabricated into films by casting from THF solutions and reactions
were carried out at the interface between solid film samples and solutions. The surface of PMPP was successfully modified
by deprotonation under dilute conditions followed by reactions with RMe2SiCl [where R = CH=CH2, and H]. While surfaces of PMPP-OH were not readily modified, those containing Si-H groups reacted with oxygen when heated
and with carbon tetrachloride. The polymer surfaces were examined by contact angle measurements, attenuated total reflectance
infrared spectroscopy (ATR-IR), and scanning electron microscopy (SEM).
We dedicate the paper to Christopher W. Allen in recognition of his outstanding contributions to inorganic ring and polymer
chemistry. 相似文献
998.
E. I. Basaldella J.C. Tara G. Aguilar Armenta M. E. Patiño Iglesias 《Journal of Porous Materials》2007,14(3):273-278
Samples of mesoporous silica SBA-15 were prepared under hydrothermal conditions where Cu cations were incorporated to the
structure by impregnation in order to compare the adsorption behavior in the presence and absence of this element. The adsorption/desorption
equilibrium isotherms of propylene, propane, and N2 were measured to evaluate their usefulness in the propane/propylene separation.
All the adsorption isotherms of SBA-15 measured in the absence of Cu cations were described by the Freundlich equation, while
the adsorption isotherms of propane on Cu/SBA-15 were better represented by the Henry equation and those of propylene were
satisfactorily described by the Langmuir model in the range P < 100 Torr. The adsorption uptake of propylene increased and that of propane decreased in Cu/SBA-15 as compared to the amounts
observed in the SBA-15 sample. The presence of Cu atoms in the adsorbent lattice increased the selectivity towards propylene.
Under some working conditions the adsorbed amount of propylene in Cu/SBA-15 sample was totally reversible and the propane
uptake, negligible. 相似文献
999.
1000.