An elastic–plastic asperity contact model and its application for micro-contact analysis of gear tooth profiles

This paper presents a continuous elastic–plastic asperity contact model with or without the consideration of friction to investigate the micro-contact properties of gear tooth profiles. The model for normal or side contact analysis is established according to Hertz contact theory and the asperity morphology feature, which yields to similar results as obtained from the model proposed by Chang W.R., Etsion I., and Bogy D.B. (CEB model) and the model proposed by Kogut L. and Etsion I. (KE model). More importantly, this model avoids the constant average contact stress as predicted by the CEB model, and the noncontinuous contact stress and deformation within the ultimate strength as given by the KE model. As a application of the present theoretical model in micro-contact analysis of rough tooth profiles, a finite element model (FE model) for elastic–plastic asperity in normal or side contact is established according to the measured surface parameters of a spur gear pair. It is shown that the extreme point of Von Mise stress of the asperities along the normal vector is ascertained by FE model, and that the extreme point is relative to the initial occurrence of the asperities plastic deformation. Compared with the present theoretical model, the similar normal contact stress along the contact radius is attained by FE model. Though the contact stress isogram in the specific plane in normal or side contact of the asperities is a circle or ellipse respectively when the plastic deformation is expanded from the inside of the asperities to their surfaces, it is in line with the distribution of elastic and plastic region of the theoretical model. Compared with CEB model, KE model, and FE model, the consistent results are attained by the present theoretical model in elastic–plastic asperity contact analysis. The results indicate that the theoretical model is applicable to the elastic–plastic asperity contact analysis on the rough surface of a spur gear drive.     

Precisely Aligned Monolayer MoS2 Epitaxially Grown on h‐BN basal Plane

Control of the precise lattice alignment of monolayer molybdenum disulfide (MoS₂) on hexagonal boron nitride (h‐BN) is important for both fundamental and applied studies of this heterostructure but remains elusive. The growth of precisely aligned MoS₂ domains on the basal plane of h‐BN by a low‐pressure chemical vapor deposition technique is reported. Only relative rotation angles of 0° or 60° between MoS₂ and h‐BN basal plane are present. Domains with same orientation stitch and form single‐crystal, domains with different orientations stitch and from mirror grain boundaries. In this way, the grain boundary is minimized and a continuous film stitched by these two types of domains with only mirror grain boundaries is obtained. This growth strategy is also applicable to other 2D materials growth.     

Transformation of monolayer MoS<Subscript>2</Subscript> into multiphasic MoTe<Subscript>2</Subscript>: Chalcogen atom-exchange synthesis route

Molybdenum ditelluride (MoTe2),which is an important transition-metal dichalcogenide,has attracted considerable interest owing to its unique properties,such as its small bandgap and large Seebeck coefficient.However,the batch production of monolayer MoTe2 has been rarely reported.In this study,we demonstrate the synthesis of large-domain (edge length exceeding 30 μm),monolayer MoTe2 from chemical vapor deposition-grown monolayer MoS2 using a chalcogen atom-exchange synthesis route.An in-depth investigation of the tellurization process reveals that the substitution of S atoms by Te is prevalently initiated at the edges and grain boundaries of the monolayer MoS2,which differs from the homogeneous selenization of MoS2 flakes with the formation of alloyed Mo-S-Se hybrids.Moreover,we detect a large compressive strain (approximately-10％) in the transformed MoTe2 lattice,which possibly drives the phase transition from 2H to 1T'at the reaction temperature of 500 ℃.This phase change is substantiated by experimental facts and first-principles calculations.This work introduces a novel route for the templated synthesis of two-dimensional layered materials through atom substitutional chemistry and provides a new pathway for engineering the strain and thus the intriguing physics and chemistry.     

Construction of point-line-plane (0-1-2 dimensional) Fe<Subscript>2</Subscript>O<Subscript>3</Subscript>-SnO<Subscript>2</Subscript>/graphene hybrids as the anodes with excellent lithium storage capability

The assembly of hybrid nanomaterials has opened up a new direction for the construction of high-performance anodes for lithium-ion batteries (LIBs). In this work, we present a straightforward, eco-friendly, one-step hydrothermal protocol for the synthesis of a new type of Fe₂O₃-SnO₂/graphene hybrid, in which zero-dimensional (0D) SnO₂ nanoparticles with an average diameter of 8 nm and one-dimensional (1D) Fe₂O₃ nanorods with a length of ~150 nm are homogeneously attached onto two-dimensional (2D) reduced graphene oxide nanosheets, generating a unique point-line-plane (0D-1D-2D) architecture. The achieved Fe₂O₃-SnO₂/graphene exhibits a well-defined morphology, a uniform size, and good monodispersity. As anode materials for LIBs, the hybrids exhibit a remarkable reversible capacity of 1,530 mA·g^?1 at a current density of 100 mA·g^?1 after 200 cycles, as well as a high rate capability of 615 mAh·g^?1 at 2,000 mA·g^?1. Detailed characterizations reveal that the superior lithium-storage capacity and good cycle stability of the hybrids arise from their peculiar hybrid nanostructure and conductive graphene matrix, as well as the synergistic interaction among the components.

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Improving the structural stability of Li-rich cathode materials via reservation of cations in the Li-slab for Li-ion batteries

High-capacity Li-rich cathode materials can significantly improve the energy density of lithium-ion batteries, which is the key limitation to miniaturization of electronic devices and further improvement of electrical-vehicle mileage. However, severe voltage decay hinders the further commercialization of these materials. Insights into the relationship between the inherent structural stability and external appearance of the voltage decay in high-energy Li-rich cathode materials are critical to solve this problem. Here, we demonstrate that structural evolution can be significantly inhibited by the intentional introduction of certain adventive cations (such as Ni²⁺) or by premeditated reservation of some of the original Li⁺ ions in the Li slab in the delithiated state. The voltage decay of Li-rich cathode materials over 100 cycles decreased from 500 to 90 or 40 mV upon introducing Ni²⁺ or retaining some Li⁺ ions in the Li slab, respectively. The cations in the Li slab can serve as stabilizers to reduce the repulsion between the two neighboring oxygen layers, leading to improved thermodynamic stability. Meanwhile, the cations also suppress transition metal ion migration into the Li slab, thereby inhibiting structural evolution and mitigating voltage decay. These findings provide insights into the origin of voltage decay in Li-rich cathode materials and set new guidelines for designing these materials for high-energy-density Li-ion batteries.

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Research on lease and sale of electric vehicles based on value engineering

Electric vehicles (EVs) acknowledged as potential means of transportation tools in the near future are widely accepted as the development trend of automobile industry due to its environment protection and fuel energy saving properties. As a product containing new technologies and concepts with little market experience and consumer identification, studying its life cycle operation modes will help to figure out an optimal approach to conduct EVs manufacturing and service. The two common operation modes, lease and sale of EVs, have their own advantages and weaknesses under different scenarios and consumer psychological status. Research and comparisons on the function, cost and value of two operation modes in full life cycle will simulate the rapid development of EVs forming a mature and dynamic operation mechanism. This paper utilised approaches in value engineering, putting forward customer requirements and technical elements of EV lease and sale based on quality assessment and customer-perceived value, proposing the metric method of function and cost coefficient by mathematical modelling, and conducting value coefficient analysis and comparison based on customer’s risk aversion psychology. An illustrative example raised for studying operation mode of three different kinds of EVs based on the analysis of value coefficient, providing guideline for manufacturer and servicers of EVs.