Stress-strain response of a cast 319-T6 aluminum under thermomechanical loading

The stress-strain behavior of cast 319-T6 aluminum-copper alloys with three different secondary dendrite arm spacings (SDASs) was studied at high temperatures and under thermomechanical deformation, exposing marked cyclic softening. A two state-variable unified inelastic constitutive model proposed earlier was modified to describe the stress-strain responses of these alloys by considering the variation of hardening and recovery functions of back-stress and drag stress. The SDAS was incorporated in the model as a length-scale parameter, and the material constants were determined systematically from experiments on a cast 319-T6 aluminum with small and large SDASs. The capabilities of the constitutive model were checked by the comparisons of simulations to experiments in the small-strain regime (<0.005). The results show that the model provides successful simulations for material response after thermal exposure at high temperature and cyclic transient stress-strain behavior. The causes of mechanical behaviors at the macro scale are discussed based on microstructural changes during thermal exposure.     

Propylene Epoxidation: High-Throughput Screening of Supported Metal Catalysts Combinatorially Prepared by Rapid Sol–Gel Method

The gas phase oxidation of propylene using molecular oxygen was studied on a variety of supported metal catalysts. The most promising PO activity was obtained for Cu supported on high surface area SiO₂ and the multimetallic systems exhibit synergistic effects that increased the desired PO yield by several folds for Ag promoted with Cu on SiO₂ after screening a large number of catalysts by a high throughput testing technique.     

Swage casting of A380 alloy

Swage casting is a new casting technique which combines the advantages of squeeze, centrifugal and semi-solid casting methods. In this new casting method, components with one rotating axis can be produced on a swage casting machine from molten metal in a one-step operation. A shape like a “bomb-body” is chosen to demonstrate the advantages of this new method by using A380 Al–Si–Cu alloy. The same alloy is also cast with centrifugal and squeeze casting methods. In this study, the swage casting method and its features are briefly described. The final microstructures, mechanical properties and amount of porosity of the cast pieces produced by squeeze, centrifugal and swage casting methods are compared. Swage cast pieces showed a different composition of microstructure that consists of fine dendritic particles at the chill ends and a mixture of spherical and rosette shaped particles at the core. The swage cast pieces also have a slightly higher mechanical strength as indicated by tensile strength and Brinell hardness values.     

Experimental determination of the overall heat loss coefficient for energy requirement of greenhouse heating

This paper presents an experimental determination of energy requirement for greenhouse heating. The overall heat loss coefficient, heat input, the control factor for air‐tightness, the rate of heat loss and the thermal screen effectiveness were calculated. The relationships between the overall heat loss coefficient and the wind speed, and the outside temperature were modelled, including the measured and calculated values. It was found that the thermal screen effectiveness was 16 and 19.8% for the polyethylene (PE) and polyester screens, respectively. Copyright © 2005 John Wiley & Sons, Ltd.     

Static and dynamic bifurcations associated with a double-zero eigenvalue

This paper is concerned with the static and dynamic bifurcation phenomena exhibited by a nonlinear autonomous system in the vicinity of a double-zero eigenvalue. It is demonstrated analytically that such a coincident critical point is often located on the intersection of the divergence and flutter boundaries of the system. The analysis is performed via a new 'unification technique' which is based on an intrinsic perturbation procedure. The new approach is capable of yielding information about stability of solutions as well as incipient and secondary bifurcations. Indeed, the stability properties of the system and secondary Hopf bifurcations are discussed conveniently, and explicit results concerning post-critical solutions are presented. An illustrative example is analysed.     

Mechanical Properties and Corrosion Behavior of As-Cast Mg-Zn-Zr-(La) Magnesium Alloys

The effects of La content on the mechanical properties and corrosion behavior of as-cast Mg-Zn-Zr (ZK) magnesium alloys were investigated. The results showed that La addition to ZK60 alloy resulted in a considerable grain refinement and an increase in the volume fraction of second phases by formation of Mg-Zn-La ternary phase. The tensile tests were performed at both room and elevated temperatures. At room temperature, the yield and tensile strengths and elongation-to-fracture significantly increased with 0.2 wt.% La addition, then deteriorated slightly with increasing La additions above 0.2 wt.%. At 200 °C, the yield and tensile strengths continually improved and elongation-to-fracture decreased with increasing La content due to the presence of thermally stable Mg-Zn-La phase. Immersion and electrochemical corrosion tests revealed that the formation of Mg-Zn-La phases led to a higher amount of cathodic sites and preferential corrosion propagation, and thus a decrease in the corrosion resistance of ZK60 alloys.