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排序方式: 共有9195条查询结果,搜索用时 15 毫秒
81.
High‐performance shape‐memory polyurethane block copolymers, prepared with two types of poly(tetramethylene glycol) (PTMG) used as soft segments, were investigated for their mechanical properties. Copolymers with a random or block soft‐segment arrangement had higher stresses at break and elongations at break than those with only one kind of PTMG. Random copolymers with fewer interchain interactions showed higher elongation than block copolymers. All the copolymers had shape‐recovery ratios higher than 80%. In dynamic mechanical testing, the glass‐transition behavior clearly depended on the soft‐segment arrangement: random copolymers had only one glass‐transition peak, whereas block copolymers showed two separate glass‐transition peaks. Overall, the control of the soft‐segment arrangement plays a vital role in the development of high‐performance shape‐memory polyurethane. © 2004 Wiley Periodicals, Inc. J Appl Polym Sci 93: 2410–2415, 2004 相似文献
82.
Water management plays an important role in obtaining high performance from a polymer electrolyte membrane fuel cell (PEMFC).
To reduce the volume and energy consumption of widely-used bubble humidifiers, membrane humidifiers were fabricated by using
an ultrafiltration (UF) membrane and Nafion membranes. The performance of the membrane humidifiers was examined as a function
of gas flow rate and operating temperature. A single cell was operated using the UF membrane humidifiers exhibiting almost
the same performance with that employing bubble humidifiers. 相似文献
83.
The effects of estrogen-induced hyperlipidemia on plasma lipid peroxidation, fatty acid composition and osmotic fragility
of erythrocytes in chickens were studied. Young male chickens implanted with estrogen for three wk developed a marked hyperlipidemia.
Plasma levels of triglyceride, cholesterol and phospholipid were elevated 68-, four- and 24-fold, respectively, over controls.
There was also a two-fold increase in plasma lipid peroxidation measured by the thiobarbituric acid test. Vitamin E supplement
(1,000 IU/kg diet) reduced the plasma lipid peroxidation to the control level, but had no effect on the plasma lipid content.
Estrogen-induced hyperlipidemia resulted in changes in the fatty acid composition of membrane lipids of erythrocytes. The
major changes were an increase in oleic acid from 10.0% to 14.2% and a decrease in linoleic acid from 31.3% to 26.0%. The
erytrocytes with an altered membrane fatty acid composition were found to have an increased osmotic fragility. It was apparent
that there was a direct correlation between the oleic acid content and the osmotic fragility of erythrocytes. 相似文献
84.
Electrophoretic deposition of carbon nanotubes 总被引:1,自引:0,他引:1
Aldo R. Boccaccini Johann Cho Judith A. Roether Boris J.C. Thomas E. Jane Minay Milo S.P. Shaffer 《Carbon》2006,44(15):3149-3160
Electrophoretic deposition (EPD) has been gaining increasing interest as an economical and versatile processing technique for the production of novel coatings or films of carbon nanotubes (CNTs) on conductive substrates. The purpose of the paper is to present an up-to-date comprehensive overview of current research progress in the field of EPD of CNTs. The paper specifically reviews the preparation and characterisation of stable CNT suspensions, and the mechanism of the EPD process; it includes discussion of pure CNT coatings and CNT/nanoparticle composite films. A complete discussion of the EPD parameters is presented, including electrode materials, deposition time, electrode separation, deposition voltage and resultant electric field. The paper highlights potential applications of the resulting CNT and CNT/composite structures, in areas such as field emission devices, fuel cells, and supercapacitors. 相似文献
85.
A heating process for obtaining free-standing carbon nanotube emitters is presented with the aim of improving field-emission properties from the screen-printed multiwalled carbon nanotube (MWCNT) films. Using an atmosphere with an optimum combination of nitrogen and air for heat treatment of CNT films, the CNT emitters can be made to protrude from the surface. This allows for a high emission current and the formation of very uniform emission sites without special surface treatment. The morphological change of the CNT film by this technique has eliminated additional processing steps, such as surface treatment which may result in secondary contamination and damage to the film. Despite its simplicity the process provides a high reproducibility in emission current density which makes the films suitable for practical applications. 相似文献
86.
Summary The cyclopolymerization of 1,8-diethynylnaphthalene(DEN) and its copolymerization with diethyl dipropargylmalonate(DEDPM) were carried out by various transition metal catalysts. MoCl5-based catalyst was found to be very effective and gave almost a quantitative polymer yield. The resulting dark-brown homopolymer(PDEN) was partially soluble in chloroform, tetrahydrofuran, and dimethyl sulfoxide, whereas copolymer (1:1) with number avaerage molecular weight
of 2.1x104 by GPC showed good solubility in those solvents. The structure of the polymers was analysed by IR, NMR, and UV-VIS spectroscopies. From the spectral and solubility data, it is proposed that cyclized products with the conjugated system are formed. Room temperature conductivities of the I2-doped homo and copolymer were found to be about 7.5x10-3 and 5.1x10-3 S/cm, respectively. 相似文献
87.
Sung-Yong Cho Seung-Shik Park Seung-Jai Kim Tae-Young Kim 《Korean Journal of Chemical Engineering》2006,23(4):638-644
Adsorption and desorption characteristics of the 2-methyl-4-chlorophenoxyacetic acid (MCPA) from aqueous solution onto the
activated carbon (GAC, F-400) were studied. Adsorption equilibrium capacities of the MCPA increased with decreasing pH and
temperature of the solution. Adsorption equilibrium of the MCPA could be represented by the Sips equation. The internal diffusion
coefficients were determined by comparing the experimental concentration decay curves with those predicted from surface diffusion
model and pore diffusion model. The adsorption model based on the linear driving force approximation (LDFA) was used for simulating
the adsorption behavior of the MCPA in a fixed bed. Over ninety five percent desorption of the MCPA could be obtained using
distilled water. 相似文献
88.
89.
Seong-Youl Bae Du-Hyon Cho Hee-Taik Kim Hidehiro Kumazawa 《Korean Journal of Chemical Engineering》1994,11(2):127-130
Sorption equilibria and permeation rates for oxygen and carbon dioxide in polycarbonate membrane were measured at different
temperature between 30 and 60°C and at pressures up to 2.5 MPa. The pressure dependence of mean permeability coefficient to
oxygen obeyed the conventional dual-mode mobility model, whereas that to carbon dioxide followed a modified dual-mode mobility
model with concentration-dependent diffusivities, as that of polystyrene to the same gas did. 相似文献
90.
Young-Ho Lee Shin-Guk Kim Tae-Yong Kuc Jong-Koo Park Sang-Hoon Ji Yong-Seon Moon Young-Jo Cho 《International Journal of Control, Automation and Systems》2014,12(2):390-398
A virtual target tracking approach is proposed for kinematic control of mobile robot. In the controller, linear and angular velocity inputs are generated by using the local data of robot position and orientation along with the estimated velocity of target object. Applying the proposed approach to a cooperative robot group with arbitrary number of multiple mobile robots, it is possible to create various robot formations for cooperative navigation and tracking of moving object. The developed controller is shown to be stable and convergent through theoretical proof and a series of experiments. 相似文献