Aggregate stability of ZrO2 aqueous sols in electrolyte solutions

The aggregate stability of submicron and nanosized ZrO₂ aqueous sols of different origins and different dispersities at pH 3–10 in the KCl concentration range 10^?3–10^?1 M is investigated by flow ultramicroscopy and photometry. The results obtained are analyzed in the framework of the extended Derjaguin-Landau-Verwey-Overbeek theory and the Muller-Martynov theory of reversible aggregation. The extension of boundary layers of water near the surface of the ZrO₂ particles is estimated.     

Tellurium clusters in channels of the porous silica ZSM-11

The distribution and structure of tellurium nanoclusters synthesized in crystal channels of the porous silica ZSM-11 are investigated using the maximum-entropy method and the Rietveld analysis. It is shown that the intercalated tellurium atoms are arranged in channels of the ZSM-11 zeolite not randomly but in the form of scraps of infinite chains similar to those observed in massive tellurium. The distances between the nearest neighbor tellurium atoms vary in the range 2.53(4)–2.70(3) ?. The clusters Te₄ are formed at the intersections of channels in the structure. These clusters have the form of distorted tetrahedra in which the tellurium atoms are separated by distances of 2.53(4) and 2.90(4) ?. Original Russian Text ? A.E. Lapshin, Yu.F. Shepelev, Yu.I. Smolin, E.A. Vasil’eva, 2008, published in Fizika i Khimiya Stekla.     

A fragmentary model of vitreous As<Subscript>2</Subscript>S<Subscript>3</Subscript>

The X-ray scattering intensity curves for vitreous As₂S₃ are experimentally measured using soft (copper) and hard (molybdenum) X rays. The inclusion of all the specific features revealed in the experimental scattering intensity curves makes it possible to obtain the experimental atomic radial distribution function (ARDF) in the ordering range up to ～1 nm. The experimental ARDF is interpreted in the framework of the fragmentary model. A comparison of the experimental ARDF with the model ARDF calculated from the crystal structure data obtained for orpiment demonstrates that the corrugated layers inherent in crystalline As₂S₃ are retained in the glass structure but the characteristic interlayer interatomic distances are absent. The layers are joined together through the As₄S₅ molecular clusters. Microcrystals consisting of several unit cells are absent in the glass structure, which involves only the structural fragments of both crystalline analogs. One of the possible variants of their joining is proposed.     

γ-Absorption express analysis of the moisture content of coal concentrate in coke production

Coal concentrate with minimum moisture content is used for coke production in metallurgy. At various enterprises, the moisture content is determined by weighing [1]. However, this method is slow and is undertaken in the laboratory. To reduce the loss of production, accelerated monitoring of the moisture content in industrial conditions is required.     

Study of medium-cement concrete based on mixed Chamotte-periclase chromite filler

The possibility is demonstrated of using an addition of periclase-chromite filler (PCF) prepared from PCF grade broken material articles in medium-cement concrete with chamotte filler. The effect of this addition on cement hardening duration, strength and heat resistance is considered. Translated from Novye Ogneupory, No. 8, pp. 42–46, August 2008.     

Software for computing dusty air flows in ventilation systems

Programs are presented for calculating dusty air flow in ventilation systems, which have been derived from the method of singular integral equations. They allow one to construct flow lines and determine the velocity pattern for the air in a closed rectangular region with outlet, flow, and extraction holes; a study is made on the dust particle behavior in the aerodynamic field in which there may be a rotating cylinder or pumping cylinder; determinations are made of the concentration and grain-size composition of the dust in the extraction hole; one can construct flow lines and single-particle paths in multicoupled regions of potential flows containing any number of rotating cylinders and cylinder pumps. Translated from Novye Ogneupory, No. 5, pp. 53–58, May, 2008.