Infrared absorption enhancement of C60 by overlaying thin silver island films

Normal-incidence infrared absorption has been observed for silver overlaid C(60) thin films formed on surface-oxidized Si(111) substrates as a function of the silver or C(60) film thickness. The absorption spectra exhibit bands at 1429 and 1180 cm(-1) due, respectively, to the infrared active T(lu) (4) and T(lu) (3) modes of C(60) in multi-layers. Additionally, two bands appear at 1442 and 1370 cm(-1). The former band is caused by activation of the infrared inactive (Raman active) A(g) (2) mode via electron transfer from the silver to adsorbed C(60), and the latter is assigned to the T(1u) (4) mode red-shifted by the charge transfer. These bands are all enhanced in intensity dependent either upon the silver or C(60) thickness, i.e., the largest absorption enhancement is obtained for 25-monolayers-thick silver and 12-nm-thick C(60). Under atomic force microprobe inspection, the average size and height of the islands in the overlaid 25-monolayers-thick silver change with underlying C(60) film thickness. The influence of the C(60) film structure upon the silver film and in turn the absorption intensity is strongly suggested.     

Delivery of medical multimedia contents through the TCP/IP network using RealSystem

We developed a low cost, user-friendly multimedia delivery system, to provide medical lectures saved as multimedia contents to persons engaged in medicine. This system was created using the RealSystem package with the TCP/IP network. Users can review lectures and medical meeting presentations with video and audio through the Internet, whenever convenient. Each medical source of video and slide has been clearly displayed on a screen. Members of medical associations or medical students can easily review the most interesting parts of these files. This system is being used efficiently in distance learning and aids the diffusion of the latest information and technology to busy physicians and medical students.     

Determination of captafol,cyhexatin, 1-naphthylacetic acid and quintozene in apple,Japanese pear and melon by simultaneous extraction

A simple and rapid method is described for the determination of the non-registered pesticides, captafol, quintozene (PCNB), cyhexatin and 1-naphthylacetic acid (NAA), in fruits. These pesticides were extracted with acidified acetone, then captafol and PCNB were purified with a Florisil mini column and analyzed by GC-ECD. Cyhexatin was ethylated with ethylmagnesium bromide, and the ethyl derivative was analyzed by GC-FPD (Sn filter). NAA was purified with liquid-liquid extraction and determined by HPLC equipped with a fluorescence detector. These analytes were identified with GC/MS or LC/MS. The minimum identified concentration of the pesticides was below 0.2 ng per injection, which corresponds to a detection limit of below 0.02 microgram/g in the original samples. Recoveries of the pesticides spiked at 0.1 microgram/g into apple, Japanese pear and melon were greater than 61%.     

A location model for smart environments

This paper presents a location model for location-aware and user-aware services in smart environments. It can be dynamically organized like a tree based on geographical containment, such as that in a user–room–floor–building hierarchy and each node in the tree can be constructed as an executable software component. The model is unique in existing approaches because it enables location-aware services to be managed without any database servers, it can be managed by multiple computers, and it can provide a unified view of the locations of not only physical entities and spaces, including users and objects, but also computing devices and services. A prototype implementation of this approach was constructed on a Java-based mobile agent system. This paper presents the rationale, design, implementation, and applications of the prototype system.     

Shape oscillation of bubbles in a row excited by ultrasonic vibration

Behaviors of bubble(s) exposed to an ultrasonic vibration are focused. Size of the bubbles interested in the present study is of O(1 mm) in diameter. The bubbles were injected through the micro syringe to the test fluid (water or water/surfactant mixture) filled in the rectangular tank. Ultrasonic vibration was irradiated to the bubble(s) after the detachment of the bubble from the tip of the syringe; thus the bubbles were exposed to the periodic oscillation in rising the test fluid. The authors clearly detect radial and shape oscillations under the large-amplitude vibration by use of high-speed camera. Preferable mode number of the shape oscillation, and the transition process from the radial to the shape oscillation are discussed.     

Optical Burst Switching Router With 40-,10-Gb/s Bit-Rate Transparent Contention Resolution

We report a bit-rate transparent optical burst switching (OBS) router prototype using a fast 5 times 5 PLZT [(Pb,La)(Zr,Ti)O₃ ] optical matrix switch. Dynamic switching in a two-wavelength, 2 times 2 OBS switch is demonstrated. Contention resolution using a tunable Mach-Zehnder interferometer wavelength converter for both 40- and 10-Gb/s bursts is demonstrated for the first time. Error-free operation was achieved for both bit rates under the same settings, as required in autonomous networks     

COMPUTATIONAL METHODS THROUGH GENETIC ALGORITHMS FOR OBTAINING STACKELBERG SOLUTIONS TO TWO-LEVEL MIXED ZERO-ONE PROGRAMMING PROBLEMS

In this paper, we develop computational methods for obtaining Stackelberg solutions to two-level mixed zero-one programming problems in which the decision maker at the upper level controls zero-one variables and the decision maker at the lower level controls real variables. To illustrate two-level mixed zero-one programming problems, we formulate a facility location and transportation problem as a two-level mixed zero-one programming problem. We develop computational methods through genetic algorithms for obtaining Stackelberg solutions. To demonstrate the feasibility and efficiency of the proposed methods, computational experiments are carried out and comparisons between the methods based on the branch-and-bound techniques and the proposed methods are provided.     

Contents of barbaloin-related compounds in aloe drinks and their change during storage

The contents of barbaloin (BA), isoBA, aloin-dimers A, B, C, D and aloe-emodin (AE) in aloe drinks were investigated. BA and isoBA were detected in 30 of the 31 samples at the levels of 120-570 micrograms/mL and 120-580 micrograms/mL, respectively. Aloin-dimers A, B, C and D were detected in 8 of the 31 samples at the levels of 12-38 micrograms/mL, 13-39 micrograms/mL, 11-36 micrograms/mL and 16-69 micrograms/mL, respectively. AE was detected in all of the 31 samples at the levels of 0.03-1.3 micrograms/mL. When aloe drinks were stored for 4 weeks at 5 degrees C after opening the bottle, decrease of BA and isoBA, and increase of AE and aloin-dimers A, B, C and D were observed in most cases. However, in a few aloe drinks, all of BA, isoBA, aloin-dimers A, B, C, D and AE decreased. In these drinks, the existence of aloin-trimer was elucidated by LC/MS analyses. These data suggested that BA in aloe drinks is converted to the dimer and then to the trimer during storage.     

An application of the 2-nitrobenzenesulfenyl method to proteomic profiling of human colorectal carcinoma: A novel approach for biomarker discovery

In the development of novel biomarkers, the proteomic approach is advantageous because using it the cancer-associated proteins can be directly identified. We previously developed a 2-nitrobenzenesulfenyl (NBS) method to improve quantitative proteome analysis. Here, we applied this method to proteomic profiling of colorectal carcinoma (CRC) to identify novel proteins with altered expression in CRC. Each pair of tumor and normal tissue specimens from 12 CRC patients was analyzed, and approximately 5000 NBS-labeled paired peaks were quantified. Peaks with altered signal intensities (>1.5-fold) and occurring frequently in the samples (>70%) were selected, and 128 proteins were identified by MS/MS analyses as differentially expressed proteins in CRC tissues. Many proteins were newly revealed to be CRC related; 30 were reported in earlier studies of CRC. Six proteins that were up-regulated in CRC (ZYX, RAN, RCN1, AHCY, LGALS1, and VIM) were further characterized and validated by Western blot and immunohistochemistry. All six were found to be CRC-localized, either in cancer cells or in stroma cells near the cancer cells. These results indicate that the proteins identified in this study are novel candidates for CRC markers, and that the NBS method is useful in proteome mining to discover novel biomarkers.     

Influence of cold-rolling and annealing conditions on formability of aluminium alloy sheet

Using an Al-Mg-Cu alloy developed for auto body panels, strip sheets are experimentally produced by various cold-rolling and annealing procedures. Tensile and metallographic properties of the sheets and their relations are examined to attain high formability. The elongation is closely related to the grain size, and increases with the final annealing temperature. The rolling texture influences the plastic anisotropy, the Lankford value of the sheets. The comparatively high Lankford values are obtained under the condition that both the intermediate and the final annealing temperatures are higher and the reduction ratio after the intermediate annealing is smaller.