Very Large Photoconduction Enhancement Upon Self‐Assembly of a New Triindole Derivative in Solution‐Processed Films

A new carbazole‐related small molecule exhibiting self‐assembly into ordered nanostructures in solution‐processed cast films has been synthesized and its charge‐photogeneration and ‐transport properties have been investigated. Large photoconductivity was measured in the amorphous state while an enormous improvement in the photoconduction properties was observed when the molecules spontaneously organized. Photocurrents increased upon self‐assembly by up to four orders of magnitude, mostly due to the drastic enhancement of the charge photogeneration. A greatly favorable arrangement of the aromatic cores in the resulting nanostructures, which were characterized by X‐ray analysis, may explain these improvements. Photocurrents of mA cm^?2, on/off ratios of 10⁴ and quantum efficiencies of unity at low field and light intensity, which are among the best values reported to date, along with the simplicity of fabrication, give this readily‐available organic system great potential for use in plastic optoelectronic devices.     

Vitamins as Active Agents for Highly Emissive and Stable Nanostructured Halide Perovskite Inks and 3D Composites Fabricated by Additive Manufacturing

The use of non-toxic and low-cost vitamins like α-tocopherol (α-TCP, vitamin E) to improve the photophysical properties and stability of perovskite nanocrystals (PNCs), through post-synthetic ligand surface passivation, is demonstrated for the first time. Especially interesting is its effect on CsPbI₃ the most unstable inorganic PNC. Adding α-TCP produces that the photoluminescence quantum yield (PLQY) of freshly prepared and aged PNCs achieves values of ≈98% and 100%, respectively. After storing 2 months under ambient air and 60% relative humidity, PLQY is maintained at 85% and 67%, respectively. α-TCP restores the PL features of aged CsPbI₃ PNCs, and mediates the radiative recombination channels by reducing surface defects. In addition, the combination of α-TCP and PNCs facilitates the chemical formulation to prepare PNCs-acrylic polymer composites processable by additive manufacturing. This enables the development of complex shaped parts with improved luminescent features and long-term stability for 4 months, which is not possible for non-modified PNCs. A PLQY ≈92% is reached in the 3D printed polymer/PNC composite, the highest value obtained for a red-emitting composite solid until now as far as it is known. The passivation shell provided by α-TCP makes that PNCs inks do not suffer any degradation process avoiding the contact with the environment and preserve their properties after reacting with polar monomers during composite polymerization.     

Review of antenna technologies for very high frequency Data Exchange Systems

The Automated Identification System (AIS) was originally developed as a terrestrial system tracking vessels near the coastline. Dedicated channels were allocated within the spectrum historically reserved for maritime applications in the very high frequency (VHF) band, enabling long range communications, up to a few kilometers. There have been various initiatives in the last decade that extended this system with a space segment, enabling global monitoring of vessels beyond the range of terrestrial stations. Recently, the World Radiocommunication Conference has allocated frequencies for the extension of this system to a two-way VHF Data Exchange System (VDES) via satellite. This requires to adapt spaceborne antenna solutions previously developed for AIS, particularly for missions using small satellites and CubeSats. This paper provides a timely review of existing VHF antenna solutions and new concepts under development which could be applicable to VDES missions. Some key metrics are identified to provide a comparative study between various candidate solutions. Considering the range of possible missions, from secondary payloads on-board larger satellites to dedicated constellations, it is believed that a number of antenna products can find application in future VDES space-based infrastructure.     

Crystal Size,Morphology, and Growth Mechanism in Bio‐Inspired Apatite Nanocrystals

Bio‐inspired apatite nanoparticles precipitated in the presence of citrate ions at increasing maturation times are characterized in terms of structure, size, morphology, and composition through advanced X‐ray total scattering techniques. The origin of the platy crystal morphology, breaking the hexagonal symmetry, and the role of citrate ions is explored. By cross‐coupling the size and shape information of crystal domains with those obtained by atomic force microscopy on multidomain nanoparticles, a plausible mechanism underlying the amorphous‐to‐crystal transformation is reconstructed. In the present study, citrate plays the distinct roles of inducing the platy morphology of the amorphous precursor and controlling the thickness of the Ca‐deficient apatite nanocrystals. These findings can open new scenarios also in bone mineralization, where citrate might have a broader role to play than has been thought to date.     

Objective and subjective evaluation of static 3D mesh compression

3D mesh compression is essential in the context of network-based virtual worlds, but so are objective and subjective fidelity of the reconstructed mesh to the original one. Unfortunately, it is difficult to establish a fair way to compare objectively two textured, triangular 3D meshes meant to approximate the surface of the same 3D object. We explain why by elaborating on how the geometric distance between two meshes can be estimated, after introducing some basic concepts related to mesh shape and a brief taxonomy of static 3D mesh coding techniques. We review a selection of such coding techniques, almost all of which deal only with the shape of the surface, and then focus on surface appearance, usually described separately with a texture to be mapped onto the 3D mesh at rendering time, and we also review existing techniques specifically devised to compress textures meant for 3D models. Finally, we discuss the even larger complexity of establishing any reasonable way to compare the subjective quality of the experience produced by two versions of the same 3D object, especially if different rendering methods may be used.     

Structural Changes in the BODIPY Dye PM567 Enhancing the Laser Action in Liquid and Solid Media

In the search for more efficient and photostable solid‐state dye lasers, newly synthesized analogs of the borondipyrromethene (BODIPY) dye PM567, bearing the polymerizable methacryloyloxypropyl group at position 2 (PMoMA) or at positions 2 and 6 (PDiMA), have been studied in the form of solid copolymers with methyl methacrylate (MMA). The parent dye PM567, as well as the model analogs bearing the acetoxypropyl group in the same positions, PMoAc and PDiAc, respectively, have been also studied both in liquid solvents and in solid poly(MMA) (PMMA) solution. Although in liquid solution PMoAc and PDiAc have the same photophysical properties as PM567, PDiAc exhibited a photostability up to 10 times higher than that of PM567 in ethanol under 310 nm‐irradiation. The possible stabilization factors of PDiAc have been analyzed and discussed on the basis of the redox potentials, the ability for singlet molecular oxygen [O₂(¹Δ_g)] generation, the reactivity with O₂(¹Δ_g), and quantum mechanical calculations. Both PMoAc and PDiAc, pumped transversally at 532 nm, lased in liquid solution with a high (up to 58 %), near solvent‐independent efficiency. This enhanced photostabilization has been also observed in solid polymeric and copolymeric media. While the solid solution of the model dye PDiAc in PMMA showed a lasing efficiency of 33 %, with a decrease in the laser output of ca. 50 % after 60 000 pump pulses (10 Hz repetition rate) in the same position of the sample, the solid copolymer with the double bonded chromophore, COP(PDiMA‐MMA), showed lasing efficiencies of up to 37 %, and no sign of degradation in the laser output after 100 000 similar pump pulses. Even under the more demanding repetition rate of 30 Hz, the laser emission from this material remained at 67 % of its initial laser output after 400 000 pump pulses, which is the highest laser photostability achieved to date for solid‐state lasers based on organic polymeric materials doped with laser dyes. This result indicates that the double covalent linkage of the BODIPY chromophore to a PMMA polymeric matrix is even more efficient than the simple linkage, for its photostabilization under laser operation.     

Packet loss analysis in optical packet-switched networks with limited deflection routing

We present an approximate analytical method for the evaluation of packet loss probability in synchronous optical packet-switched networks which operate under limited deflection routing with the contention resolution method based on priorities. Packets are lost because they are removed by nodes. They are removed because they experience too many deflections and stay prohibitively long in the network. Such packets have to be removed because they will be ignored by the transmission protocols (like TCP) and because the quality of their optical signal is unacceptable. Presented are results for the network in the topology of the torus of the two-dimensional grid, which operates at a steady state with the uniform load u, . The strength of our analysis is its novel mathematical approach, which is capable of providing very low packet loss probabilities. For the network composed of 100 nodes, we predict the packet loss probability as low as 10⁻⁹ or lower, while simulation provided results only at the order of 10⁻⁶. For a given permissible packet loss probability, our analysis provides the maximal network load and the number of allowed deflections. We verify the analysis with simulation in the cases for which simulation gave results.