The influence of the drawing parameters and temperature rise on the prediction of chevron crack formation in wire drawing

The objective of the present work is to predict the formation of chevron crack in copper wire drawing process. The first part of this paper is to determine the chevron crack formation initiated by a central burst inside the wire material using experimental tests. These results are compared with results from a series of numerical simulations using the Cockcroft?CLatham fracture criterion. The second part of this work concerns the determination of a curve that divides the chevron and safe zones for a better wire drawing process. The conditions of central burst defects formation along the wire axis depend on drawing parameters and friction coefficient between the die and the wire. The friction coefficient is defined as a linear function of temperature rise which is measured close to the wire-die interface. The obtained results show that the friction coefficient depending on temperature rise during wire drawing has an impact on the damage of copper wire.     

Chlor-alkali electrolysis with oxygen depolarized cathodes: history,present status and future prospects

The historical development, current status and future prospects of chlor-alkali electrolysis with oxygen depolarized cathodes (ODCs) are summarized. Over the last decades, membrane chlor-alkali technology has been optimized to such an extent that no substantial reduction of the energy demand can be expected from further process modifications. However, replacement of the hydrogen evolving cathodes in the classical membrane cells by ODCs allows for reduction of the cell voltage and correspondingly the energy consumption of up to 30%. This replacement requires the development of appropriate cathode materials and novel electrolysis cell designs. Due to their superior long-term stability, ODCs based on silver catalysts are very promising for oxygen reduction in concentrated NaOH solutions. Finite-gap falling film cells appear to be the technically most mature design among the several ODC electrolysis cells that have been investigated.

Fatigue life estimation after crack repair in 6005 A-T6 aluminium alloy using the cold expansion hole technique

In this paper, the hole drilling (HD) and the cold expansion (CE) processes, which were used as a technique for crack repair, were investigated in order to estimate the beneficial effects on fatigue crack initiation (FCI). The FCI life is defined as the number of cycles to initiate a new crack of 0.2 mm on the surface of the specimen. Three hole radii and three degrees of cold expansion (DCE%) values were tested after a crack propagation period. Crack retardation after the CE process was observed. This phenomenon is due to two mechanisms: retardation owing to both geometric and mechanical effects, which is produced by the stress concentration at the drilled hole, and the large strain‐induced compressive residual stresses around the hole. In this report, the influence of the loading conditions was studied. For high values of the stress intensity factor range ΔK_ρ around the hole (based on the pseudo crack length a + ρ), the number of cycles corresponding to crack initiation N_i is low. At the edge of the hole, the maximum stress range can be approximated by the following formula: Δσ_max = 2ΔK_ρ /√πρ , where ρ is the hole radius and ΔK_ρ is the related stress intensity factor range.The FCI life extension, defined by the number of cycles corresponding to crack re‐initiation N_i , is related to the relative maximum stress range ratio R_σ = [(Δσ_max )/(Δσ_max )_th ] where (Δσ_max )_th is the value of the threshold maximum stress range obtained when N_i = 2 × 10⁶ cycles. The relationship between N_i and R_σ may be written as a power function.     

Misfit Layer Compounds: A Platform for Heavily Doped 2D Transition Metal Dichalcogenides

Transition metal dichalcogenides (TMDs) display a rich variety of instabilities such as spin and charge orders, Ising superconductivity, and topological properties. Their physical properties can be controlled by doping in electric double-layer field-effect transistors (FET). However, for the case of single layer NbSe₂, FET doping is limited to ≈ 1 × 10¹⁴ cm⁻², while a somewhat larger charge injection can be obtained via deposition of K atoms. Here, by performing angle-resolved photoemission spectroscopy, scanning tunneling microscopy, quasiparticle interference measurements, and first-principles calculations it is shown that a misfit compound formed by sandwiching NbSe₂ and LaSe layers behaves as a NbSe₂ single layer with a rigid doping of 0.55–0.6 electrons per Nb atom or ≈ 6 × 10¹⁴ cm⁻². Due to this huge doping, the 3 × 3 charge density wave is replaced by a 2 × 2 order with very short coherence length. As a tremendous number of different misfit compounds can be obtained by sandwiching TMDs layers with rock salt or other layers, this work paves the way to the exploration of heavily doped 2D TMDs over an unprecedented wide range of doping.     

Editorial: Mobile Networks in the Era of Big Data

Mobile Networks and Applications -     

Investigation of microstructure-property relantionships of magnesia-hercynite refractory composites by a refined digital image correlation technique

Industrial magnesia-spinel bricks destined for thermal shock applications often show more flexibility and improved crack growth resistance. Components from the spinel structure group are usually added to promote microcracking coming from thermal expansion mismatch. This leads to the development of toughening mechanisms that are very effective in improving the crack propagation resistance.Magnesia-hercynite composites were investigated in order to highlight their fracture process, with regard to their microstructure, by using Digital Image Correlation (DIC). The direct measurement of displacement fields between digital images of the reference state and the deformed one has provided valuable information on material deformation during loading. The aim of this work was to investigate the fracture behaviour of refractories through the coupling of the Wedge Splitting Test (WST) and DIC. By using a refined DIC process transformation taking into account a discontinuity of displacement, called 2P-DIC, a more effective characterisation of the fracture behaviour was achieved.     

New measures for robustness in linear multivariable feedback systems

New measures for robustness are proposed for linear multivariable control systems. A new theorem is presented to account for the controllability of systems that contain an integrating element, in the presence of additive uncertainties. The theorem leads to the definition of a sufficient condition for robust integral controllability: robustness margin (RM). The ratio of robustness margins for competing control or processs structures can be used to discriminate between these structures. These measures are useful, especially in design stages, since their calculation depends only on steady state information. Applications to several published distillation systems show the merits of these robustness measures.     

First-Principles Study of Electronic Structure,Mechanical, and Thermoelectric Properties of Ternary Palladates CdPd<Subscript>3</Subscript>O<Subscript>4</Subscript> and TlPd<Subscript>3</Subscript>O<Subscript>4</Subscript>

Ternary palladates CdPd₃O₄ and TlPd₃O₄ have been studied theoretically using the generalized gradient approximation (GGA), modified Becke–Johnson, and spin–orbit coupling (GGA–SOC) exchange–correlation functionals in the density functional theory (DFT) framework. From the calculated ground-state properties, it is found that SOC effects are dominant in these palladates. Mechanical properties reveal that both compounds are ductile in nature. The electronic band structures show that CdPd₃O₄ is metallic, whereas TlPd₃O₄ is an indirect-bandgap semiconductor with energy gap of 1.1 eV. The optical properties show that TlPd₃O₄ is a good dielectric material. The dense electronic states, narrow-gap semiconductor nature, and Seebeck coefficient of TlPd₃O₄ suggest that it could be used as a good thermoelectric material. The magnetic susceptibility calculated by post-DFT treatment confirmed the paramagnetic behavior of these compounds.