Synthesis and thermal,mechanical and gas permeation properties of aromatic polyimides containing different linkage groups

Two series of aromatic polyimides containing various linkage groups based on 2,7‐bis(4‐aminophenoxy)naphthalene or 3,3′‐dimethyl‐4,4′‐diaminodiphenylmethane and different aromatic dianhydrides, namely 4,4′‐(4,4′‐isopropylidenediphenoxy)bis(phthalic anhydride), 4,4′‐(hexafluoroisopropylidene)bis(phthalic anhydride), 3,3′,4,4′ benzophenonetetracarboxylic dianhydride, 9,9‐bis[4‐(3,4‐dicarboxyphenoxy)phenyl]fluorene dianhydride and 4,4′‐(4,4′‐hexafluoroisopropylidenediphenoxy)bis(phthalic anhydride), were synthesized and compared with regard to their thermal, mechanical and gas permeation properties. All these polymers showed high thermal stability with initial decomposition temperature in the range 475–525 °C and glass transition temperature between 208 and 286 °C. Also, the polymer films presented good mechanical characteristics with tensile strength in the range 60–91 MPa and storage modulus in the range 1700–2375 MPa. The macromolecular chain packing induced by dianhydride and diamine segments was investigated by examining gas permeation through the polymer films. The relationships between chain mobility and interchain distance and the obtained values for gas permeability are discussed. © 2014 Society of Chemical Industry     

Investigation of metallic nanoparticles adsorbed on the QCM sensor by SEM and AFM techniques

Quartz crystal microbalance (QCM) is known as a very sensitive device used for determination of mass quantity adsorbed on sensor surface. Its detection limits are in the range of ng cm\(^{-2}\). The adsorption mechanism of metallic nanoparticles on QCM sensor was investigated by scanning electron microscopy (SEM) and atomic force microscopy (AFM). This study aims to highlight the importance of QCM applications in nanoparticles deposition field. The layers formed through adsorption process, induced by the oscillations of the QCM sensor, were investigated by AFM for surface topography and for particle mean size values. The morphology of layers and nanoparticles dimensions were determined by SEM. For a more complex investigation of the nanoparticles adsorption mechanism, the chemical composition of layers was achieved using SEM coupled with energy dispersive X-ray spectrometer (SEM-EDS). This preliminary research involved a new approach in characterization of metallic nanoparticles layers to achieve functional assembled monolayers.     

Grey and black optical solitary waves,and modulation instability analysis to the perturbed nonlinear Schrödinger equation with Kerr law nonlinearity

This paper addresses the nonlinear Schrödinger equation (NLSE) with Kerr law nonlinearity and perturbation terms in optical fibre. A class of grey and black optical solitary wave solutions of this equation are retrieved by adopting an appropriate solitary wave ansatz solution. These types of solitary waves play a vital role in understanding various physical phenomena in nonlinear systems. This lead to a constraint condition on the solitary wave parameters which must hold for the solitary waves to exist. Moreover, the modulation instability (MI) analysis of the model is studied by employing the concept of linear-stability analysis (LSA) and the MI gain spectrum is got. Physical interpretations of the acquired results are demonstrated. It is hoped that the results reported in this paper can enrich the nonlinear dynamical behaviours of the equation.     

Evolving improvised ideation from humour constructs: A new method for collaborative divergence

This paper reviews and applies key principles from improvised comedy (“improv”) to overcome common barriers in effective group ideation, resulting in the formulation and presentation of a new creative idea generation method. The emergence of an innovative product design can be compared to the telling of a funny joke: both combine seemingly unconnected ideas in a way that is both surprising and satisfying. Our research expands upon this link between humour and creativity, and operationalizes the improv principles best suited to the conceptual design process. A workshop‐based methodology was used to select, develop, and refine the method protocol and facilitation technique. Participant feedback and observations have demonstrated how this approach can expand the solution space to support the generation of bold, innovative ideas. Finally, we present a step‐by‐step guide for the new “design improv” method and discuss its potential value in the generation of creative ideas in a group ideation context.     

Molecular dynamics simulation of diffusion of O2 and CO2 in amorphous poly(ethylene terephthalate) and related aromatic polyesters

The diffusion of small molecules through polymers is important in many areas of polymer science, such as gas barrier and separation membrane materials, polymeric foams, and in the processing and properties of polymers. Molecular simulation techniques have been applied to study the diffusion of oxygen and dioxide of carbon as small molecule penetrants in models of bulk amorphous poly(ethylene terephthalate) and related aromatic polyesters. A bulk amorphous configuration with periodic boundary conditions is generated into a unit cell whose dimensions are determined for each of the simulated aromatic polyesters in the cell to have the experimental density. The aim for this research is to explore and investigate the diffusion of gases through bulk amorphous poly(ethylene terephthalate) and related aromatic polyesters. The diffusion coefficients for O₂ and CO₂ were determined via NVE molecular dynamics simulations using the Dreiding 2.21 molecular mechanics force field over a range of temperatures (300, 500 and 600 K) using up to 30 ns simulation time. We have focussed on the influence of the temperature, polymer dynamics, number of aromatic rings, ortho-, meta-, para-isomers, density and free volume distribution on the diffusion properties. Correlation of diffusion coefficients with free volume, temperature, number of aromatic rings, ortho-, meta- and para-isomers was found.     

Collagen-hydroxyapatite composite enhances regeneration of calvaria bone defects in young rats but postpones the regeneration of calvaria bone in aged rats

The potential differences in bone repair of calvaria defects treated with a collagen sponge (HELISTAT) or a collagen-hydroxyapatite composite (HEALOS) in young and aged rats were evaluated at 8 weeks after surgery. A histomorphometric analysis of new bone formation and an evaluation of angiogenesis, mast cell, and eosinophil local infiltration were performed. Evaluation showed that HELISTAT induced a similar amount of new bone in both young and aged rats. However this occurred to a lesser degree than in young rats treated with HEALOS. The largest number of blood vessels was present in the defects of aged rats treated with HEALOS, and the number of mast cells was highest in the defects treated with HELISTAT in both young and aged rats. Eosinophils were present to the greatest extent in defects treated with HEALOS in comparison to defects treated with HELISTAT in both young and aged rats. Collagen-hydroxyapatite composite (HEALOS) enhances calvarial bone repair more than collagen sponge alone (HELISTAT) in young rats but not in aged rats at 8 weeks after surgery. HEALOS appears to induce a more intense inflammatory response than HELISTAT especially in aged rats.     

High-throughput SNP genotyping by SBE/SBH

Despite much progress over the past decade, current single nucleotide polymorphism (SNP) genotyping technologies still offer an insufficient degree of multiplexing when required to handle user selected sets of SNPs. In this paper we propose a new genotyping assay architecture combining multiplexed solution-phase single-base extension (SBE) reactions with sequencing by hybridization (SBH) using universal DNA arrays such as all k-mer arrays. Simulation results on datasets both randomly generated and extracted from the NCBI dbSNP database suggest that the SBE/SBH architecture provides a flexible and cost-effective alternative to genotyping assays currently used in the industry, enabling genotyping of up to hundreds of thousands of SNPs per assay     

Surface properties of aromatic polymer film during thermal treatment

Aromatic polyimide films are processed from polyamic acid solutions. This process involved the simultaneous loss of solvent and chemical conversion of polyamic acid to polyimide, and implied structural reorganization which led to changed physical properties. Polymer films generated from benzophenonetetracarboxylic dianhydride and 4,4′-diamino-3,3′-dimethyl diphenylmethane have been investigated at different stages of thermal treatment. The surface polarity, which was determined by the presence of polar COOH and CONH groups, changed during polyamic acid thermal treatment. These polar groups were removed step by step by imidization process leading to the modification of the physical properties of the polymer film.     

Thermoelastic influence functions and solution to a locally mixed BVP for a strip

This article presents in closed form new influence functions for displacements and stresses to a boundary value problems (BVP) of thermoelasticity within a strip, caused by a unit point heat source. We also obtain the respective new integration formula of Green’s type, which directly determines the thermal stresses in the form of integrals of the products between specified internal heat sources, temperature, or heat flux prescribed on boundary and derived thermoelastic influence functions (kernels). The general Green’s type integral formula permits to derive new solution to one particular BVP of thermoelasticity for a strip in the form of elementary functions. Graphical representation of thermal stresses, created by an internal point heat source and by a boundary temperature, is included.     

Influence functions, integral formulas, and explicit solutions for thermoelastic spherical wedges

In this study, new exact Green’s functions and a new exact Green-type integral formula for a boundary value problem (BVP) in thermoelasticity for some spherical wedges with mixed homogeneous mechanical boundary conditions are derived. The thermoelastic displacements are subjected to a heat source applied in the inner points of the spherical wedges and to a mixed non-homogeneous boundary heat conditions. When the thermoelastic Green’s function is derived, the thermoelastic displacements are generated by an inner unit point heat source, described by Dirac’s δ-function. All results are obtained in elementary functions that are formulated in a special theorem. Exact solutions in elementary functions for two particular BVPs of thermoelasticity for spherical wedges also are included. In these particular BVPs, the thermoelastic displacements are subjected to a constant temperature (in the first particular BVP) or to a constant heat source (in the second particular BVP). In both BVPs, the constant temperature or the constant heat source is given on the segment of the radius of the quarter-space. On the boundary half-planes of the quarter-space zero temperature and zero heat flux are prescribed.