Functionalized [2]Rotaxanes

The synthesis of a series of dumbbell-shaped compounds, which can act as a host (e.g., toward alkali metal cations) and as a guest (e.g., toward cyclobis(paraquat-p-phenylene)) in a supramolecular context is described. The self-assembly of [2]pseudorotaxanes and [2]rotaxanes, in which cyclobis(paraquat-p-phenylene) encircles polyether chains intercepted in their middles by a hydroquinone ring and terminated at each end by 12-crown-4, 15-crown-5, monoaza-18-crown-6, 18-crown-6, or adamantyl groups, is achieved using either threading, clipping, or slipping procedures. All the [2]pseudorotaxanes and [2]rotaxanes are characterized in solution by spectroscopic means and, in the case of two of the [2]rotaxanes, by X-ray crystal structures in the solid state. In the presence of metal ions, [2]pseudorotaxanes carrying 12-crown-4 or 15-crown-5 stoppers can be disassembled in solution. The research shows how one kind of complexation can affect another kind of complexation—manifesting itself in a physical change in the system and so acting as a prototype of a potential molecular device.     

Secure sensors data acquisition and communication protection in eHealthcare: Review on the state of the art

Recent advances in hardware technology have led to the development of low cost, power efficient and more feature rich devices that are amongst the most critical parts of communication networks. These devices or sensors can now sense data with more accuracy, process it by themselves and send it to the neighboring node or the sink node. However, robust and reliable security mechanisms are not yet properly implemented on these sensors due to their limited energy and computation power. Sensors also play a very important role in eHealthcare systems where ubiquitous patient monitoring is performed. As data is generated from the sensor nodes, reliable, secure and attack-resistant data acquisition and transmission is important for an efficient eHealthcare systems. This survey focuses on security issues of sensors data acquisition and transmission protocols, describing their main security features and comparing them in the context of a secure eHealthcare system. A taxonomy of open issues and future challenges is also discussed with respect to specific security metrics described in the paper.     

Conceptual framework for the security of mobile health applications on Android platform

Mobile Health (mHealth) applications are readily accessible to the average user of mobile devices, and despite the potential of mHealth applications to improve the availability, affordability and effectiveness of delivering healthcare services, they handle sensitive medical data, and as such, have also the potential to carry substantial risks to the security and privacy of their users. Developers of applications are usually unknown, and users are unaware of how their data are being managed and used. This is combined with the emergence of new threats due to the deficiency in mobile applications development or the design ambiguities of the current mobile operating systems. A number of mobile operating systems are available in the market, but the Android platform has gained the topmost popularity. However, Android security model is short of completely ensuring the privacy and security of users’ data, including the data of mHealth applications. Despite the security mechanisms provided by Android such as permissions and sandboxing, mHealth applications are still plagued by serious privacy and security issues. These security issues need to be addressed in order to improve the acceptance of mHealth applications among users and the efficacy of mHealth applications in the healthcare systems. Thus, this paper presents a conceptual framework to improve the security of medical data associated with Android mHealth applications, as well as to protect the privacy of their users. Based on the literature review that suggested the need for the intended security framework, three-distinct and successive phases are presented, each of which is described in a separate section. First, discussed the design process of the first phase to develop a security framework for mHealth apps to ensure the security and privacy of sensitive medical data. The second phase is discussed who to achieve the implementation of a prototypic proof-of-concept version of the framework. Finally, the third phase ending discussed the evaluation process in terms of effectiveness and efficiency for the proposed framework.     

A sustainability comparison between drilling and milling for hole-enlargement in machining of hardened steels

Abstract

Hole-making is one of the most important processes of metal shaping domain. Although, drilling is a commonly used approach to cut holes in metallic parts, the process cannot be completed with the cutting action of one drill bit if the work material is hard and diameter of the hole is large. Usually, a drill having diameter equal to the required diameter of the hole is utilized to enlarge a predrilled hole of a smaller diameter. In this work, we have investigated sustainability of using another method of enlarging a pre-drilled hole, namely side and end milling and compared it with the drilling-based approach. The work material used in the study is a high carbon steel, which is heat-treated to two distinct levels of surface hardness. Besides process type and work material hardness, the other two parameters tested in the investigation are cutting speed and depth of hole. A total of 16 experiments were performed to generate data regarding the sustainability measures, namely hole surface roughness, specific cutting energy and tool wear. Process choice (drilling or milling) for hole-enlargement was found to possess a significant effect on all the measured responses. Analyses carried out on the experimental data revealed that although the drilling-based option led to an immensely better surface finish, the milling-based option performed better with respect to the other measures of economic and environmental sustainability.     

Emergence of time‐dependent material properties in chain extended polyureas

In this article, we report the emergence of material properties of polyurea over a finite time frame. Due to the rapid isocyanate–amine reaction, polyurea formation occurs practically instantaneously. Despite being an “instant‐curing” system, the material properties of polyurea evolve substantially with time: phenomenon, which warrants a methodical study. The curing process of polyurea formulations, containing both aliphatic and aromatic chain extender, has been studied systematically with an aim to gain insight into the time frame associated with its curing and subsequent stress relaxation. Formulations containing aromatic chain extender mandated relatively lesser time to “gel,” but the complete disappearance of NCO absorbance mandated much longer periods ～7 h. Interestingly, in all the formulations, mechanical properties improved with time and reached their optimal properties over a period of 15 days. This improvement has been attributed to several processes simultaneously occurring within the matrix; the foremost being the relaxation of internal stresses which tend to buildup in the polymer during the spray coating process. In addition, significant changes occur in the internal morphology of segmented polymers, which in turn is a result of H‐bond rearrangement.     

Job search website for illiterate users of Pakistan

Illiteracy is a major hurdle in socio-economic development of Pakistan. Research in the Information and Communication Technology (ICT) can help in tackling this issue by developing solutions tailored for illiterate population. The work presented within this paper proposes a job search website for illiterate population of KPK province of Pakistan. The designed website does not require any human assistance while searching a job. Moreover, the website uses culturally relevant graphical and audio content. The usability of the website is tested according to the ISO-9241-11 specification. Furthermore, we have studied the effect of the participants’ characteristics, i.e., their age, computer and mobile usage experience on the usability of the website. The results show that the participants found the website usable. Specifically, they could search suitable jobs with a minimal number of clicks and in less time as compared to the usual task completion rates reported throughout the literature. None of the participants’ characteristics were found to be affecting the usability of the website. These results suggest a promising potential of ICT solutions for providing services to illiterate population of Pakistan.     

Tuning the interlaminar shear strength and thermo-mechanical properties of glass fiber composites by incorporation of (3-mercaptopropyl) trimethoxysilane-functionalized carbon black

The incorporation of functionalized nanoscale fillers into traditional glass fiber/unsaturated polyester (GF/UPE) composites provides a more robust mechanical attributes. The current study demonstrates the potential of 3-mercaptopropyl trimethoxysilane (MPTS)-functionalized carbon black (f-CB) for enhancing the thermo-mechanical properties of GF composites. The composites infused with 1, 3 and 5 wt% of pristine and MPTS-functionalized CB were fabricated by hand lay-up and hot press processing. Tensile testing, interlaminar shear strength (ILSS) testing and dynamic mechanical analysis were used to evaluate the performance of nanocomposites. Fourier transform infrared spectroscopy validated the MPTS functionalization of CB. Pristine CB-loaded nanocomposites exhibited marginal improvement in ultimate tensile strength (UTS), ILSS and thermo-mechanical properties. However, with the addition of f-CB, the improvement in all the studied properties was more substantial. The inclusion of 5 wt% f-CB increased the elastic modulus and UTS by 16 and 22%, respectively, whereas the ILSS was enhanced by 36%, in comparison to the neat GF composite. The scanning electron microscope analysis of fractured ILSS samples revealed better fiber-matrix adhesion and compatibility in f-CB-loaded nanocomposites. At the same filler weight percentage, the storage modulus at 25 °C was ~ 19% higher than that of neat composite. The f-CB inclusion resulted in increment of T _g by ~ 13 °C over the T _g of neat GF/UPE composite (~ 109 °C). These improvements were due to the chemical connection of f-CB to the UPE matrix and GF surface. With such improvements in thermal and mechanical properties, these nanocomposites can replace the conventional GF composites with prominent improvements in performance.     

Parametric analysis of alternative energy conservation measures in an office building in hot and humid climate

The growth of demand for electrical energy in the rapidly expanding towns, cities and industries exceeds the growth of the power being made available. Therefore, energy conservation is becoming an increasingly important issue in Saudi buildings. The objective of this study was to investigate the impact of alternative energy conservation measures on energy requirements in office buildings in hot–humid climates. The study was conducted on a five-story office building located in Dammam, Saudi Arabia, which has been in use since 1998. Different types of HVAC systems were selected and different feasible and practical operational energy conservation measures (ECMs) were evaluated using the energy simulation software of Visual DOE 4.0. Previous studies conducted in this area were reviewed. Data was collected through review of design drawings, building audit and the analysis of 4 years of utility bills. All the collected data was analyzed and the utility bills data was used to calibrate the base case of the existing building using Visual DOE energy simulation software. Conclusions and recommendations were developed for conserving energy using various appropriate ECMs in office buildings in hot and humid climates.     

Physical and chemical modification of distillery sludge for Pb(II) biosorption

The waste distillery sludge from sugar-cane industry was pretreated physically (boiled, heated and autoclaved) as well as chemically (HCl, H(2)SO(4), H(3)PO(4), NaOH, Ca(OH)(2), Al(OH)(3), C(6)H(6), HCHO, CH(3)OH and C1(2)H(25)OSO(3)Na (sodium dodecyl sulphate (SDS)) for assessing the comparative sorption capacity of untreated and modified distillery sludge for Pb(II) biosorption from aqueous solutions. Experiments were conducted in shake flasks on a batch basis to access the effect of different experimental parameters such as pH, biosorbent dosage, biosorbent size, initial Pb(II) concentration and contact time. The uptake capacity 'q' (mg/g) of untreated and pretreated distillery sludge was in following order: NaOH (51.29+/-1.21)>HCl (49.82+/-1.22)>HCHO (49.56+/-1.14)>H(2)SO(4) (47.71+/-1.20)>HgCl(2) (45.32+/-1.06)>Ca(OH)(2) (44.01+/-1.18)>MeOH (43.73+/-1.23)>C(6)H(6) (42.72+/-1.19)>H(3)PO(4) (42.01+/-1.17)>SDS (40.87+/-1.27)>autoclaved (40.23+/-1.24)>Boiled (39.95+/-1.19)>heated (38.87+/-1.32)>Al (OH)(3) (38.30+/-1.14)>untreated (37.76+/-1.21). In further parameter studies, the optimized biosorbent size was 0.250 mm at pH 5 and best dose was 0.05 g of biosorbent. The applicability of the Langmuir and Freundlich models for sorption process was tested and best fitted model was Langmuir with the coefficient of determination (R(2)) value, 0.97, the process followed second order kinetic mechanism.