全文获取类型
收费全文 | 507篇 |
免费 | 27篇 |
专业分类
电工技术 | 8篇 |
化学工业 | 155篇 |
金属工艺 | 3篇 |
机械仪表 | 6篇 |
建筑科学 | 10篇 |
矿业工程 | 1篇 |
能源动力 | 14篇 |
轻工业 | 114篇 |
石油天然气 | 2篇 |
无线电 | 33篇 |
一般工业技术 | 66篇 |
冶金工业 | 58篇 |
原子能技术 | 1篇 |
自动化技术 | 63篇 |
出版年
2024年 | 5篇 |
2023年 | 9篇 |
2022年 | 22篇 |
2021年 | 26篇 |
2020年 | 25篇 |
2019年 | 21篇 |
2018年 | 18篇 |
2017年 | 25篇 |
2016年 | 22篇 |
2015年 | 12篇 |
2014年 | 26篇 |
2013年 | 44篇 |
2012年 | 42篇 |
2011年 | 35篇 |
2010年 | 20篇 |
2009年 | 19篇 |
2008年 | 18篇 |
2007年 | 17篇 |
2006年 | 15篇 |
2005年 | 8篇 |
2004年 | 9篇 |
2003年 | 7篇 |
2002年 | 9篇 |
2001年 | 6篇 |
2000年 | 6篇 |
1999年 | 1篇 |
1998年 | 17篇 |
1997年 | 10篇 |
1996年 | 8篇 |
1995年 | 5篇 |
1994年 | 5篇 |
1993年 | 4篇 |
1992年 | 2篇 |
1991年 | 1篇 |
1990年 | 1篇 |
1989年 | 2篇 |
1986年 | 2篇 |
1985年 | 1篇 |
1984年 | 2篇 |
1983年 | 3篇 |
1981年 | 1篇 |
1979年 | 1篇 |
1978年 | 1篇 |
1974年 | 1篇 |
排序方式: 共有534条查询结果,搜索用时 15 毫秒
11.
In this study, the transport properties of poly(styrene‐isobutylene‐styrene) (SIBS) were determined as a function of sulfonation level (0–94.9%) and counter‐ion substitution (Ba+2, Ca+2, Mg+2, Mn+2, Cu+2, K+1) for fuel cell applications. Increasing the sulfonation level improved the ion exchange capacity (IEC) of the membranes up a maximum (1.71 mequiv/g), suggesting a complex three‐dimensional network at high sulfonation levels. Results show that proton conductivity increases with IEC and is very sensitive to hydration levels. Methanol permeability, although also sensitive to IEC, shows a different behavior than proton conductivity, suggesting fundamental differences in their transport mechanism. The incorporation of counter‐ion substitution decreases both methanol and proton transport. Methanol permeability seems to be related to the size of the counter‐ion studied, while proton conductivity is more sensitive to water content, which is also reduced upon the incorporation of counter‐ions. To complement the studies, selectivity (i.e., proton conductivity/methanol permeability) of the studied membranes was determined and compared to Nafion® 117. © 2013 Wiley Periodicals, Inc. J. Appl. Polym. Sci., 2013 相似文献
12.
Michelle Leali Costa Mirabel Cerqueira Rezende Jane Maria Faulstich de Paiva Edson Cocchieri Botelho 《Polymer-Plastics Technology and Engineering》2013,52(10):1143-1153
Two different carbon/epoxy prepreg materials were characterized and compared using thermal (DSC, TGA, and DMA) and rheological analyses. A prepreg system (carbon fiber preimpregnated with epoxy resin F584) that is currently used in the commercial airplane industry was compared with a prepreg system that is a prospective candidate for the same applications (carbon fiber prepreg/epoxy resin 8552). The differences in the curing kinetics mechanisms of both prepreg systems were identified through the DSC, TGA, DMA, and rheological analyses. Based on these thermal analysis techniques, it was verified that the curing of both epoxy resin systems follow a cure kinetic of n order. Even though their reaction heats were found to be slightly different, the kinetics of these systems were nevertheless very similar. The activation energies for both prepreg systems were determined by DSC analysis, using Arrhenius's method, and were found to be quite similar. DMA measurements of the cured prepregs demonstrated that they exhibited similar degrees of cure and different glass transition temperatures. Furthermore, the use of the rheological analysis revealed small differences in the gel temperatures of the two prepreg systems that were examined. 相似文献
13.
Anca Giorgiana Grigoras Marieta Constantin Vasile Cristian Grigoras Simona Isabela Dunca Lacramioara Ochiuz 《Reactive and Functional Polymers》2013,73(9):1249-1254
The physico-chemical properties of three grafted pullulans (P) having linked poly(3-acrylamidopropyl)trimethylammonium chloride (pAPTAC) as side chains (P-g-pAPTAC1, P-g-pAPTAC2 and P-g-pAPTAC3 with 22.53, 29.05, and 34.51 (wt.%) of pAPTAC content in polymer, respectively) and possessing polyelectrolyte character were determined by light scattering analysis. All grafted pullulan aqueous solutions were tested in the presence of 0.5 M NaCl, KCl, NaNO3 or KNO3. The biggest associations were recorded in 0.5 M NaCl aqueous solutions for P-g-pAPTAC1, P-g-pAPTAC2 and P-g-pAPTAC3 according to the maximum values for Rg extracted from MALLS (multiangle laser light scattering) measurements. Also, the dominant conformation in salted solution of these polyelectrolytes was random coil as Debye plot analysis revealed. Antibacterial activity was tested by Kirby–Bauer diffusion method and all grafted pullulans dissolved in aqueous solutions of 0.5 M NaCl have developed inhibition zone against Staphylococcus aureus (ATCC 25923). 相似文献
14.
Claudia M. TrentinAna P. Lima Isabela P. AlkimimCamila da Silva Fernanda de CastilhosMarcio A. Mazutti J. Vladimir Oliveira 《Fuel Processing Technology》2011,92(5):952-958
This work investigates the production of fatty acid ethyl esters (FAEE) from the transesterification of soybean oil in supercritical ethanol in a continuous catalyst-free process using carbon dioxide as co-solvent. The experiments were performed in a microtube reactor in the temperature range of 523 K to 598 K, from 10 MPa to 20 MPa, oil to ethanol molar ratio from 1:20 to 1:40, and co-solvent to substrates mass ratio from 0.05:1 to 0.2:1. Results showed that ethyl esters yield obtained increased with increasing addition of carbon dioxide to the system. Considerable reaction yields were achieved at 598 K, 20 MPa, oil to ethanol molar ratio of 1:20 and using a CO2 to substrate mass ratio of 0.2:1. 相似文献
15.
16.
Magalhaes KD Costa LS Fidelis GP Oliveira RM Nobre LT Dantas-Santos N Camara RB Albuquerque IR Cordeiro SL Sabry DA Costa MS Alves LG Rocha HA 《International journal of molecular sciences》2011,12(5):3352-3365
In the present study, six families of sulfated polysaccharides were obtained from seaweed Dictyopteris delicatula by proteolytic digestion, followed by acetone fractionation and molecular sieving on Sephadex G-100. Chemical analyses demonstrated that all polysaccharides contain heterofucans composed mainly of fucose, xylose, glucose, galactose, uronic acid, and sulfate. The fucans F0.5v and F0.7v at 1.0 mg/mL showed high ferric chelating activity (~45%), whereas fucans F1.3v (0.5 mg/mL) showed considerable reducing power, about 53.2% of the activity of vitamin C. The fucan F1.5v presented the most prominent anticoagulant activity. The best antiproliferative activity was found with fucans F1.3v and F0.7v. However, F1.3v activity was much higher than F0.7v inhibiting almost 100% of HeLa cell proliferation. These fucans have been selected for further studies on structural characterization as well as in vivo experiments, which are already in progress. 相似文献
17.
Moacir Fernandes Ferreira Júnior Elaine Angélica Ribeiro Mundim Guimes Rodrigues Filho Carla da Silva Meireles Daniel Alves Cerqueira Rosana Maria Nascimento de Assunção Marcos Marcolin Mara Zeni 《Polymer Bulletin》2011,66(3):377-389
Cellulose, obtained both from sugarcane bagasse and mango seeds, was used for synthesizing cellulose acetate in order to produce asymmetric membranes. These were compared to membranes of commercial cellulose acetate (Rhodia). All produced membranes were asymmetric, characterized by the presence of a dense skin and a porous support. Differences regarding the morphology of the surfaces as well as of the porous support can be noticed. Scanning Electron Microscopy (SEM) showed that the morphology of the superficial layer, responsible for transport, depends on the different lignin content of the starting material and also on the viscosity average molecular weight of the cellulose acetates produced from sugarcane bagasse, mango seed, and Rhodia’s commercial cellulose acetate. 相似文献
18.
Amanda Severo Vinícius Barreto Pedro Nicácio Matheus Souza Carlos Luna Marcus Fook Ingridy Silva Lorena Dantas Andreas Ries Renate Wellen 《应用聚合物科学杂志》2024,141(4):e54862
Epoxidized soybean oil (ESO) composites were cured with methyl tetrahydrophthalic anhydride (MTHPA) and 2,4,6-tris(dimethylaminomethyl)phenol (DEH 35) as a catalyst, sisal fibers were added at 10% and 30% of percent per weight. Composites curing was monitored using Fourier transform infrared spectroscopy, whereas the thermal stability and the degradation kinetics were investigated using thermogravimetry (TG). ESO/MTHPA/DEH35/S10 and ESO/MTHPA/DEH35/S30 composites displayed curing temperatures approximately 100°C lower related to ESO/MTHPA/DEH35, as well as higher degree of conversion. Sisal addition improved the thermal stability, shifting the weight loss shifting the weight loss onset to higher temperature (from 82 to 120°C). Thermal degradation energy was determined using Friedman, Kissinger-Akahira-Sunose and Ozawa-Flynn-Wall models. Sisal significantly increased , especially in the intermediate phase (α = 0.2 and 0.8). The degradation kinetics was investigated by TG, and the degradation mechanisms modeled using Kamal-Sourour, Sestack-Berggren, and 1st order (F1), showed excellent fit, with R2 > 0.99. Acquired results demonstrate that sisal fiber addition benefited the curing process and increased the thermal stability of ESO composites. 相似文献
19.
N. O. Ardiaca S. P. Bressa J. A. Alves O. M. Martínez G. F. Barreto 《Catalysis Today》2001,64(3-4):205-215
A study of the liquid-phase hydrogenation of 1,3-butadiene on commercial Pd/Al2O3 catalysts of the “egg-shell” type has been performed. Experimental conditions (40°C, 4 atm and high conversion of the di-olefin) were selected in accordance to industrial operating conditions employed for selective hydrogenation of 1,3-butadiene. Three experimental schemes were tested: a slurry reactor, a rotating-basket reactor, and a recirculation system with an external fixed-bed reactor. Significant drawbacks shown by the two former devices were mainly derived from the very high activity and the egg-shell structure of the catalysts. Instead, the recirculation system was found to be an excellent alternative.
Although Pd is present only within a very thin external layer (around 50–250 μm), strong diffusion effects impairing selectivity were observed. Plausible kinetic expressions corresponding to nine series–parallel overall reactions are derived from a mechanistic model. To deal with this network of fast reactions, a rather complex set of computational and predictive tools were employed. A worked out example from several replicates demonstrates the capability of both, experimental and data analysis procedures, for inferring kinetic parameters of the proposed model. 相似文献
20.
Caio Felippe Curitiba Marcellos Camila M. Senna Figueiredo Frederico W. Tavares Maurício Bezerra de Souza Jr. Paulo Laranjeira da Cunha Lage João Francisco Cajaiba da Silva Argimiro R. Secchi Amaro G. Barreto Jr. 《加拿大化工杂志》2020,98(11):2435-2450
An experimental methodology for inferring brine dissolution rate in monoethylene glycol (MEG) solutions at different temperatures using a webcam combined with a mathematical model is presented. The measurement system is designed to track the RGB (red, green, and blue) colour variations during the dissolution process. A dynamic model augmented with the population balance equation is applied to describe the dissolution process. Moreover, the dissolution rate is consistently related to the temperature and MEG concentration through the driving force based on the Gibbs energy and chemical affinity. The applied low-cost measurement apparatus proved to be a useful resource for tracking the dissolution dynamics in a wide range of undersaturation. 相似文献