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71.
Khamirul Amin Matori Loy Chee Wah Mansor Hashim Ismayadi Ismail Mohd Hafiz Mohd Zaid 《International journal of molecular sciences》2012,13(12):16812-16821
We report on a recycling project in which α-Al2O3 was produced from aluminum cans because no such work has been reported in literature. Heated aluminum cans were mixed with 8.0 M of H2SO4 solution to form an Al2(SO4)3 solution. The Al2(SO4)3 salt was contained in a white semi-liquid solution with excess H2SO4; some unreacted aluminum pieces were also present. The solution was filtered and mixed with ethanol in a ratio of 2:3, to form a white solid of Al2(SO4)3·18H2O. The Al2(SO4)3·18H2O was calcined in an electrical furnace for 3 h at temperatures of 400–1400 °C. The heating and cooling rates were 10 °C/min. XRD was used to investigate the phase changes at different temperatures and XRF was used to determine the elemental composition in the alumina produced. A series of different alumina compositions, made by repeated dehydration and desulfonation of the Al2(SO4)3·18H2O, is reported. All transitional alumina phases produced at low temperatures were converted to α-Al2O3 at high temperatures. The X-ray diffraction results indicated that the α-Al2O3 phase was realized when the calcination temperature was at 1200 °C or higher. 相似文献
72.
Bahaa‐eldin E. A. Rahim Ismail Yusoff Azmi M. Jafri Zainudin Othman Azman Abdul Ghani 《Water and Environment Journal》2012,26(4):490-503
Estimation of total water balance is a substantial issue for watershed modelling in order to simulate the major components of the hydrological cycle to determine the stress of different anthropogenic activities on the available water resources within a catchment. In this context, the fully distributed physically based MIKE SHE modelling system was used to simulate the individual hydrological components of the total water balance for the Paya Indah Wetlands (PIW) watershed in the west of Peninsular Malaysia. Results reveal that the overall water balance is predominantly controlled by climate variables. Application of the model to the PIW watershed provides detailed estimation of the total water balance for a first‐order catchment in which actual evapotranspiration (ET) represents approximately 65 and 58%, while overland flow (OL) to the PIW lake system represents 12.38 and 12.3% of the total rainfall during the calibration and validation periods, respectively. The difference of the inflow and outflow was taken as storage in depth. Overall, the model gives a reasonable output of total error of less than 1% of the total rainfall, which in turn indicates that the interaction among components is satisfactorily sustained. 相似文献
73.
Betül Sen Sultan Kuzu Enes Demir Tuğba Önal Fatih Şen 《International Journal of Hydrogen Energy》2021,46(24):13510-13514
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Polyethersulfone was sulfonated by changing the reaction time with sulfuric acid. The degree of sulfonation and ion exchange capacity were determined. Sulfonation of polyethersulfone was confirmed by FT-IR analysis and a new peak at 1025 cm?1. Inorganic materials such as carbon nanotubes, graphene, and kaolinite nanoparticles were synthesized. The effects of three nanoparticles on thermal stability and water uptake of sulfonated polyethersulfone were investigated. The morphology of membranes were also altered due to the addition of inorganic materials. The proton conductivity of the modified membranes increased with respect to increase in relative humidity. 相似文献