Conformational transition of Poly (vinylbenzyltrimethylammonium chloride) (PVBTMAC) brush in the presence of Hofmeister anions

This study pertains to the conformational changes of Poly (vinylbenzyltrimethylammonium chloride) (PVBTMAC) brush onto SiO₂-coated resonator; which was further incorporated by using quartz crystal microbalance with dissipation (QCM-D) in the presence of Hofmeister series of anions as a function of ionic strength. Gradual shrinkage of highly extended PVBTMAC followed by loose inhomogeneous layer was on account of change in frequency (?f) and dissipation (??D) at low ionic strength. On the contrary, the increase in ionic strength collapses chains and dense homogenous layer is formed. The chaotropic anions comparativley bring drastic change in frequency unlike kosmotropic anions. This is because weakly hydrated chaotropic anions form strong ion pair with weakly hydrated trimethyl ammonium group on the PVBTMAC brush and as a result strong counter ion condensation was observed on polymer chain. Thus, the apparent mass associated with PVBTMAC chains increases that accounts for large change in ?f.     

Performance Model of a WIMAX 2.0 All-IP 4G System

4G is promising a wireless broadband with data rates up to 1Gbps. The two candidate technologies for 4G are the Advanced Long Term Evolution (Advanced LTE) which is based on the 3GPP standards and the WiMAX 2.0 based on the IEEE 802.16 family of standards. The common feature of both technologies is that they will provide All-IP connectivity with flexible bit rates and quality of service guarantees for multiple classes of services including voice, mainly using voice over IP, data and video services. Most of the performance studies of 4G technologies use highly complex and sophisticated simulations due to the multiple complexity factors in investigating 4G technologies such as All-IP flexible bit rates, adaptive coding and modulation as well as the multi-services provided. These factors usually make any modelling attempt very difficult. This paper presents a numerical/analytical model for a 4G WiMAX cell based on a multi-dimensional Continuous-Time Markov Chain (CTMC) model. Performance measures were derived for the key performance indicators such as throughput and average bit rate per cell and per service class. By assuming minimum acceptable bit rates for certain quality of service guarantees, we derived measures for blocking probabilities. The model has been formulated and solved using MOSEL-2 (Modelling Specification and Evaluation Language) which captures the key features of a 4G system that affect services at session/call level. The resuls obtained from the model using sample parameters show that, the model can provide very useful insight to system behavior and can give good first indication to the performance of such a complex system.     

Integration of seawater desalination with power generation

The economic benefits of integrating seawater desalination with power plants are discussed, starting from the first principles of thermodynamics. The concepts of the “fuel-use performance ratio” and the “power loss” method are described in the context of their usage for thermal cycle evaluation and desalination process selection, both with conventional steam cycles and with combined cycle power plants. A thermo-economic model is introduced to evaluate water and power costs and rates of return in dual-purpose power/desalination applications. The future of integrated power and desalination plants is discussed with reference to the growing role of seawater reverse osmosis (SWRO) in the desalination arena. A case study is presented to evaluate the benefits of integrating SWRO with existing power/desalination plants in the Middle East. Subject to the assumptions of the study, it is concluded that repowering and retrofitting would result in a nearly three-fold increase in the power generating capacity and an over six-fold increase in the water output, without requiring any expansion of the seawater intake system. Based on natural gas fuel, the repowered plant would also result in a 70% increase in the fuel efficiency of the station and a drastic reduction in the cost of water production. For a privatization scenario, an economic analysis is used to show that attractive rates of return would be obtained if a developer were to purchase and refurbish the existing plant, selling the products on a build own and operate (BOO) basis. In preparation for this promising application, the need for pilot plant testing at existing power/desalination stations, together with research and development work in membrane technology for high temperature operation, is emphasized.     

Phasic firing time locked to cocaine self-infusion and locomotion: dissociable firing patterns of single nucleus accumbens neurons in the rat

The activity of single nucleus accumbens (NAcc) neurons of rats was extracellularly recorded during intravenous cocaine self-administration sessions (0.7 mg/kg per infusion, fixed ratio 1). We reported previously that NAcc neurons showed a change, usually a decrease, in firing rate during the first 1 min after the cocaine-reinforced lever press. This postpress change was followed by a progressive reversal of that change, which began within the first 2 min after the press and was not complete until the last 1 min before the next lever press (termed the change + progressive reversal firing pattern). In the present study we documented a regular pattern of locomotion that occurred in parallel with the change + progressive reversal firing pattern. This observation suggested that discharges time locked to locomotion may determine the change + progressive reversal firing pattern. However, 55% of the neurons failed to show firing time locked to locomotion that could have contributed to the change + progressive reversal firing pattern. Moreover, for all neurons, the change + progressive reversal firing pattern was apparent even if the calculation of firing rate excluded all periods of locomotion. The present data showed that the change + progressive reversal firing pattern is not solely attributable to phasic changes in firing time locked to the execution of locomotion. The change + progressive reversal firing pattern closely mirrors changes in drug level and dopamine overflow observed by previous researchers and may thus be a component of the neurophysiological mechanism by which drug level regulates drug-taking behavior during an ongoing self-administration session.     

Shelf life extension of minimally processed cabbage and cucumber through gamma irradiation

The influence of irradiation of minimally processed cabbage and cucumber on microbial safety, texture, and sensory quality was investigated. Minimally processed, polyethylene-packed, and irradiated cabbage and cucumber were stored at refrigeration temperature (5 degrees C) for 2 weeks. The firmness values ranged from 3.23 kg (control) to 2.82 kg (3.0-kGy irradiated samples) for cucumbers, with a gradual decrease in firmness with increasing radiation dose (0 to 3 kGy). Cucumbers softened just after irradiation with a dose of 3.0 kGy and after 14 days storage, whereas the texture remained within acceptable limits up to a radiation dose of 2.5 kGy. The radiation treatment had no effect on the appearance scores of cabbage; however, scores decreased from 7.0 to 6.7 during storage. The appearance and flavor scores of cucumbers decreased with increasing radiation dose, and overall acceptability was better after radiation doses of 2.5 and 3.0 kGy. The aerobic plate counts per gram for cabbage increased from 3 to 5 log CFU (control), from 1.85 to 2.93 log CFU (2.5 kGy), and from a few colonies to 2.6 log CFU (3.0 kGy) after 14 days of storage at 5 degrees C. A similar trend was noted for cucumber samples. No coliform bacteria were detected at radiation doses greater than 2.0 kGy in either cabbage or cucumber samples. Total fungal counts per gram of sample were within acceptable limits for cucumbers irradiated at 3.0 kGy, and for cabbage no fungi were detected after 2.0-kGy irradiation. The D-values for Escherichia coli in cucumber and cabbage were 0.19 and 0.17 kGy, and those for Salmonella Paratyphi A were 0.25 and 0.29 kGy for cucumber and cabbage, respectively.     

Optimised synthesis of ZnO‐nano‐fertiliser through green chemistry: boosted growth dynamics of economically important L. esculentum

Mounting‐up economic losses to annual crops yield due to micronutrient deficiency, fertiliser inefficiency and increasing microbial invasions (e.g. Xanthomonas cempestri attack on tomatoes) are needed to be solved via nano‐biotechnology. So keeping this in view, the authors’ current study presents the new horizon in the field of nano‐fertiliser with highly nutritive and preservative effect of green fabricated zinc oxide‐nanostructures (ZnO‐NSs) during Lycopersicum esculentum (tomato) growth dynamics. ZnO‐NS prepared via green chemistry possesses highly homogenous crystalline structures well‐characterised through ultraviolet and visible spectroscopy, Fourier transform infrared spectroscopy, X‐ray diffraction and scanning electron microscope. The ZnO‐NS average size was found as small as 18 nm having a crystallite size of 5 nm. L. esculentum were grown in different concentrations of ZnO‐NS to examine the different morphological parameters includes time of seed germination, germination percentage, the number of plant leaves, the height of the plant, average number of branches, days count for flowering and fruiting time period along with fruit quantity. Promising results clearly predict that bio‐fabricated ZnO‐NS at optimum concentration resulted as growth booster and dramatically triggered the plant yield.Inspec keywords: zinc compounds, II‐VI semiconductors, wide band gap semiconductors, nanostructured materials, nanofabrication, ultraviolet spectra, visible spectra, Fourier transform infrared spectra, X‐ray diffraction, scanning electron microscopy, crystallites, biomedical materials, nanomedicineOther keywords: ZnO‐nanofertiliser, green chemistry, boosted growth dynamics, L. esculentum, mounting‐up economic losses, micronutrient deficiency, fertiliser inefficiency, microbial invasions, Xanthomonas cempestri, nanobiotechnology, zinc oxide‐nanostructures, Lycopersicum esculentum, high‐homogenous crystalline structures, ultraviolet spectroscopy, visible spectroscopy, Fourier transform infrared spectroscopy, X‐ray diffraction, scanning electron microscopy, crystallite size, morphological parameters, seed germination, germination percentage, plant leaves, ZnO