Vinyl acetate monomer—a pilot plant study

The kinetics of the reaction of acetic acid and acetylene over zinc acetate-activated carbon catalyst was investigated over a wide range of process variables in a pilot reactor. Although various catalytic reaction mechanisms were postulated, the rate of reaction was most satisfactorily correlated by a mechanism of surface reaction between charged adsorbed acetic acid and acetylene, which assumes that the rate controlling step was the irreversible charged adsorption of acetylene and acetic acid.     

The effect of tension during drying on the structure and mechanics of poly(p-phenylene benzobisthiazole) fibers

The effect of tension during drying on the structure and mechanics of poly(p-phenylene benzobisthiazole) (PBT) fibers has been investigated. The application of tension during drying on PBT fibers spun from anisotropic solutions of PBT/Polyphosphoric acid (PPA) results in an enhancement of tensile modulus and yield strength with a reduction in strain to break. The alterations in the tensile properties can be attributed to the straightening of the wet fibrillar network and the reduction in the axial compressive stresses which develop during drying. Modifications in the mechanical behavior of PBT fibers through tension drying can be achieved regardless of the initial spin draw ratio of the fiber. Additionally, tension drying provides a means to maximize the potential stiffness of PBT fibers which have a low spin draw ratio. Lastly, these investigations show that in the processing of PBT fibers, preventing the onset of buckling and aligning the wet fibrillar network with tension during drying is more effective in enhancing the tensile properties than straightening the dried buckled fibers.     

Colour in flat-panel CRTs

Picture-on-the-wall television has long been a dream of display engineers throughout the world. This vision, combined with the enormous growth in applications for electronic displays over recent years, has resulted in major efforts aimed at achieving a cathode-ray tube design which is both flat and thin. Moreover, there is evidence of increasing activity in this field, in spite of the many advances being made with other flat-panel display technologies. The author provides an introduction to the wide range of flat-panel CRT designs, and describes some of the leading approaches to the achievement of colour in these displays. Some photographic results are also included     

Constriction resistance at high signal frequencies

This paper describes the dependence of constriction resistance on signal frequency. This dependence was calculated for circular constrictions ranging in diameter from 10 to 100 /spl mu/m, and for frequencies ranging from dc to 1 GHz. The results indicate that the magnitude of constriction resistance does not deviate appreciably from values predicted by Holm's classical analytical expression, as long as the skin depth is large compared with the constriction radius. For skin depths that are much smaller than the constriction radius, constriction resistance decreases with increasing frequency to an apparent limiting value independent of the constriction radius. At high frequencies, constriction resistance constitutes only one of two components of the total connection resistance measured in practice. The second component of connection resistance is determined by details of the geometry and dimensions of the contact interface, and increases with signal frequency.     

Nash equilibrium bidding strategies in a bilateral electricitymarket

This paper examines bidding strategies in a bilateral market in which generating companies submit bids to loads. A load accepts electricity delivery from the generator with the lowest bid at its bid price as long as this price is not higher than the load's willingness to pay. Necessary and sufficient conditions of Nash equilibrium (NE) bidding strategy are derived based on a generic generating cost matrix and the loads' willingness to pay vector. The study shows that in any NE, efficient allocation is achieved. Furthermore, all Nash equilibria are revenue equivalent for the generators. Based on the necessary and sufficient conditions, this problem is formulated as an optimal assignment problem. Network optimization techniques are applied to calculate NE bid prices for the generators     

A wavelet-based procedure for process fault detection

To detect faults in a time-dependent process, we apply a discrete wavelet transform (DWT) to several independently replicated data sets generated by that process. The DWT can capture irregular data patterns such as sharp "jumps" better than the Fourier transform and standard statistical procedures without adding much computational complexity. Our wavelet coefficient selection method effectively balances model parsimony against data reconstruction error. The few selected wavelet coefficients serve as the "reduced-size" data set to facilitate an efficient decision-making method in situations with potentially large-volume data sets. We develop a general procedure to detect process faults based on differences between the reduced-size data sets obtained from the nominal (in-control) process and from a new instance of the target process that must be tested for an out-of-control condition. The distribution of the test statistic is constructed first using normal distribution theory and then with a new resampling procedure called "reversed jackknifing" that does not require any restrictive distributional assumptions. A Monte Carlo study demonstrates the effectiveness of these procedures. Our methods successfully detect process faults for quadrupole mass spectrometry samples collected from a rapid thermal chemical vapor deposition process     

A Proposed Receiver Structure for Optical Communication Systems that Employ Heterodyne Detection and a Semiconductor Laser as a Local Oscillator

Coherent heterodyne detection in optical communication is degraded by phase instabilities present when a semiconductor laser is used as a local oscillator. Postdetection processing that accounts for these instabilities is suggested, based on a diffusion-process model for oscillator instabilities and a maximum-likelihood sequence-estimator of information symbols modulating the received light.     

ENHANCEMENT OF DRYING RATES FOR SLAB-LIKE MATERIALS IN A FLUIDIZED DESICCANT DRYING MEDIUM

The kinetics of drying of slab-like materials in- mersed in a fluidized bed of silica gel particles at a relatively low temperature, 30 °C, is studied. As a re- sult of desiccant particle action large surface-to-bed moisture fluxes and, consequently, large drying rates are attained. For all examined materials (cardboard, veneer, asbestos and ceramic plates) the drying times in the desiccant fluidized bed are much shorter than those in the empty apparatus with the same air flow, temperature and humidity. A simple, diffusional model of the drying based upon a mean mass capacity concept is developed. The drying curves calculated from the model are in good agreement with the experimental ones.     

Further studies on polyamides from bisacid a2

Earlier work on the low temperature solution polyamidation of bisacid A2 has raised a number of structural problems. Work carried out more recently showed that the problem of apparent nonisostoichiometry could be reasonably satisfactorily explained. The present paper reports the synthesis and investigates the properties of a further series of polyamides based upon Bisacid A2. More importantly, however, a detailed characterization and evaluation of the new polymers with respect to their structures is presented. This enabled us to compare the various structures in the light of the experimental evidence provided by a number of analytical and spectroscopic techniques, solution behavior, molecular weight, and thermal, morphological, and mechanical properties. Some work was also done on the effect of incorporating a small amount of a trifunctional monomer into the polyamide system.