Energy intensity of a clean break

Institute of Mining, Siberian Branch, Academy of Sciences of the USSR, Novosibirsk. Translated from Fiziko-Tekhnicheskie Problemy Razrabotki Poleznykh Iskopaemykh, No. 1, pp. 114–118, January–February, 1989.     

'EUROPART'. Airborne particles in the indoor environment. A European interdisciplinary review of scientific evidence on associations between exposure to particles in buildings and health effects

The relevance of particle mass, surface area or number concentration as risk indicators for health effects in non-industrial buildings has been assessed by a European interdisciplinary group of researchers (called EUROPART) by reviewing papers identified in Medline, Toxline, and OSH. Studies dealing with dermal effects or cancer or specifically addressing environmental tobacco smoke, house dust-mite, cockroach or animal allergens, microorganisms and pesticides were excluded. A total of 70 papers were reviewed, and eight were identified for the final review: Five experimental studies involving mainly healthy subjects, two cross-sectional office studies and one longitudinal study among elderly on cardiovascular effects. From most studies, no definite conclusions could be drawn. Overall, the group concluded that there is inadequate scientific evidence that airborne, indoor particulate mass or number concentrations can be used as generally applicable risk indicators of health effects in non-industrial buildings and consequently that there is inadequate scientific evidence for establishing limit values or guidelines for particulate mass or number concentrations.     

Uptake of cadmium, zinc, copper, lead and chromium in the pacific oyster. Crassostrea gigas. Grown in the tamar river. Tasmania

Hundreds of oysters and mud samples from 15 sites along the Tamar River were analysed for cadmium, copper, zinc, lead and chromium. The widely accepted concept of enrichment factors of up to several hundred thousand, describing accumulation by oysters of cadmium, zinc and copper from seawater has been found to be grossly misleading. Concentrations found for these three metals in oysters were only 10–40 times the concentrations in inhabited muds. Concentrations of metals in muds may be used to indicate whether a potential oyster bed would produce oysters that were grossly contaminated. Approximately 1 ppm cadmium in mud could result in oysters containing at least 25 ppm, i.e. 4–5 ppm wet wt. Similarly. 100 ppm zinc in mud could produce oysters containing at least 4000 ppm. i.e. 800–1000 ppm wet wt. Three heavy metal accumulation processes were discernible. Copper and chromium appeared to be absorbed up to a maximum weight that was limited by the size of the oyster and was independent of the amount of metal in the mud. Lead was not absorbed through any physiological demand, but was randomly incorporated at sites containing high concentrations in the mud. Zinc and cadmium were accumulated by a process that depended primarily on the concentrations of these metals in the mud at each site. Mean dry wt concentrations of metals in oysters and mud samples ranged from: 4.2–134 ppm and 0·4 to 5·7 ppm cadmium; 200–1700 ppm and 3–224 ppm copper: 0 135 ppm and 4–1500 ppm lead: 1–37 ppm and 2–88 ppm chromium; 1700 14.000 ppm and 20–500 ppm zinc. respectively.     

Treatment of gas-phase methanol in conventional biofilters packed with lava rock

The performance of laboratory scale methanol-degrading biofilters packed with lava rock was checked during almost 1 yr under different conditions. The biomass concentration and biomass adaptation of the inoculum dramatically affected the start-up and the performance of the systems during the first stages of operation. A fast start-up was obtained when using concentrated and adapted inocula, while diluted or non-adapted inocula proved to be much less efficient. The performance of the reactor during long-term operation was significantly affected by the toxic load and moisture content of the gas. Critical loads between 120 and 280 g/m(3)h were reached during different phases of the study. The reactor had a high stability to EBRT changes when working at values between 48.0 and 91.1s, showing little or no negative effect when decreasing the EBRT. Hardly any difference was observed regarding performance when using either a downflow or upflow feed, although slightly better results were obtained when working in a downflow mode.     

An extension of ASM2d including pH calculation

This paper presents an extension of the Activated Sludge Model No. 2d (ASM2d) including a chemical model able to calculate the pH value in biological processes. The developed chemical model incorporates the complete set of chemical species affecting the pH value to ASM2d describing non-equilibrium biochemical processes. It considers the system formed by one aqueous phase, in which biochemical processes take place, and one gaseous phase, and is based on the assumptions of instantaneous chemical equilibrium under liquid phase and kinetically governed mass transport between the liquid and gas phase. The ASM2d enlargement comprises the addition of every component affecting the pH value and an ion-balance for the calculation of the pH value and the dissociation species. The significant pH variations observed in a sequencing batch reactor operated for enhanced biological phosphorus removal were used to verify the capability of the extended model for predicting the dynamics of pH jointly with concentrations of acetic acid and phosphate. A pH inhibition function for polyphosphate accumulating bacteria has also been included in the model to simulate the behaviour observed. Experimental data obtained in four different experiments (with different sludge retention time and influent phosphorus concentrations) were accurately reproduced.     

A study of a water-reducing agent from cashew nutshell liquid

The water-reducing agent better known as superplasticizer is a recent development. A number of base materials have been used for the development of such water-reducing agents which can act better than ordinary plasticizers in concrete. The sulphonated salts of melamine, napthalene, lignin, hydroxycarboxylic acids and hydroxylated polymers are some typical compounds. Recently cashew nutshell liquid obtained from a natural product waste as a thick black phenolic compound has been converted into a water-reducing agent. This paper describes the results obtained on its effectiveness in influencing the rheological properties of flow, viscosity, particle size distribution, etc, of cement particles in hydrating cements and the water-reducing capabilities in cement mortars and concretes.     

Effect of agitation, turbidity, aluminium foil reflectors and container volume on the inactivation efficiency of batch-process solar disinfectors

We report the results of experiments designed to improve the efficacy of the solar disinfection of drinking water, inactivation process. The effects of periodic agitation, covering the rear surface of the container with aluminium foil, container volume and turbidity on the solar inactivation kinetics of Escherichia coli (starting population = 10(6) CFU ml(-1)) were investigated. It was shown that agitation promoted the release of dissolved oxygen from water with subsequent decrease in the inactivation rates of E. coli. In contrast, covering the rear surface of the solar disinfection container with aluminium foil improved the inactivation efficiency of the system. The mean decay constant for bacterial populations in foil-backed bottles was found to be a factor of 1.85 (std. dev. = 0.43) higher than that of non-foil-backed bottles. Inactivation rates decrease as turbidity increases. However, total inactivation was achievable in 300 NTU samples within 8 h exposure to strong sunshine. Inactivation kinetics was not dependent on the volume of the water container for volumes in the range 500-1500 ml.     

Elimination of beta-blockers in sewage treatment plants

beta-Blockers are used to treat high blood pressure as well as patients recovering from heart attacks. In several studies, they were detected in surface water, thus indicating incomplete degradability of these substances in sewage treatment plants (STPs). In this study, we determined the sorption coefficients (K(D)) and degradation rates of the four beta-blockers sotalol, atenolol, metoprolol and propranolol in sludge from an STP operating with municipal wastewater. The sorption coefficients (K(D), standard deviations in brackets) were determined as 0.04(+/-0.035), 0.04(+/-0.033), 0.00(+/-0.023) and 0.32(+/-0.058) Lg(-1)(COD), and the pseudo-first-order degradation rate constants were estimated to be 0.29(+/-0.02), 0.69(+/-0.05), 0.58(+/-0.05) and 0.39(+/-0.07) Ld(-1)g(-1)(COD) for sotalol, atenolol, metoprolol and propranolol, respectively. These values translate into a typical elimination in STPs (sludge concentrations of 4g(COD)L(-1) and a hydraulic retention time of 6h) of 25%, 37%, 44% and 50% for sotalol, propranolol, metoprolol and atenolol, respectively. These results are also confirmed by measurements in two municipal STPs for atenolol, sotalol and propranolol. The estimated eliminations are slightly too high for metoprolol.     

Environmental Implications of Treatment of Coastal Sewage Discharges

The environmental implications of implementing the requirement for treatment of coastal sewage prior to discharge, which were put forward in an EC draft Directive on municipal waste-water treatment, are examined. In order to establish the current situation, the results of a national survey of coastal and estuarine sewage discharges are presented. A review of the impact of sewage discharges on the marine environment is presented in conjunction with an assessment of the impact of sewage-treatment processes on the land and in the air. These aspects are integrated into overall conclusions about net environmental impact. Finally, a decision-tree approach to the assignment of priority to additional action required at individual locations is developed.