Assessment of physical techniques to regenerate active slag filters removing phosphorus from wastewater

Active slag filters are an emerging technology for removing phosphorus (P) from wastewater. Currently, the lifespan of these filters is limited by their available reactive sites. An increasing number of researchers suggest that drying active filters can renew their P removal capacity, although there has only been one research paper that has achieved regeneration. Hence, this study investigated techniques to regenerate the P removal efficiency of exhausted melter slag filter media which had successfully treated effluent for 5 years in the field before becoming inactive. Several techniques were performed to expose fresh surface sites on the slag, including: (1) drying; (2) agitation; and (3) crushing of the slag granules. Crushing resulted in the best regeneration of P removal efficiency by the slag, however, after just 2 months the renewed P removal efficiency of the crushed slag fell back to a similar level to that exhibited by exhausted slag. Furthermore, none of the other physical methods caused long-term rejuvenation of the exhausted slag to remove P from effluent. Scanning electron microscopy revealed that none of the regeneration techniques exposed substantial new phosphorus adsorption sites on the slag granules. These findings therefore challenge the validity of the existing dogma that active slag filters can be effectively regenerated by simple physical treatments, indicating further research is required to optimise active filter performance.     

Flow Visualization in a Pocketed Thrust Washer

The objectives of this study were to experimentally and numerically investigate oil flow in surface-pocketed thrust washers. In order to achieve the experimental aspects of this investigation, a thrust washer test rig was designed and developed to visualize the lubricant flow at the contact interface. A novel approach for creating the pockets was developed to allow optical inspection of the lubricant during thrust washer operation. The thrust washers were fabricated using a glass disk with a thin layer of steel shim stock adhered to the surface. The micrometer-thick shim stock was machined using an Nd:YAG laser to create the circular pocket geometries and then glued to the glass disk. A mirror and camera were placed below the semitransparent washer to observe the lubricant flow in the pocket. The results obtained from this configuration illustrate a cavitation bubble forming on the leading edge of the pocket followed by a sharp transition back to liquid. The size of the cavitation area was found to be a function of rotational speed, nominal bearing pressure (NBP), viscosity, and pocket geometry. The cavitation area ratio (gaseous region divided by the pocket area) increased for greater speeds and higher viscosities and decreased for larger pocket diameters, deeper pockets, and higher NBPs. The friction force for various thrust washer designs was also measured as a function of load, speed, and lubricant. The results showed that shallower, wider pockets provided the lowest friction. It was found that, generally, the conditions that minimize friction also result in a stable cavitation region. ANSYS Fluent computational fluid dynamics software was used to develop a three-dimensional model of the pocketed thrust washer utilizing the full Navier-Stokes equations to investigate the cavitation and pressure distribution occurring at the contact and corroborate the experimental results.     

An Automated Dual-Wavelength Spectrophotometer Optimized for Phytochrome Assay

ABSTRACT

A microcomputer-controlled dual-wavelength spectrophotometer suitable for automated phytochrome assay is described. The optomechanical unit provides for sequential irradiation of the sample by the two measuring wavelengths with intervening dark intervals and for actinic irradiation to inter-convert phytochrome between its two forms. Photomultiplier current is amplified, converted to a digital value and transferred into the computer using a custom-designed IEEE-488 bus interface. The microcomputer calculates mathematically both absorbance and absorbance difference values with dynamic correction for photomultiplier dark current. In addition, the computer controls the operating parameters of the spectrophotometer via a separate interface. These parameters include control of the durations of measuring and actinic irradiation intervals and their sequence. Because the data are processed solely within the microcomputer, except for the initial linear amplification, any output desired can be obtained, including automated determination of not only total phytochrome content, but also of the proportions present in the far-red- and red-absorbing forms.     

Impacts of Aerosol Aging on Laser Desorption/Ionization in Single-Particle Mass Spectrometers

Single-particle mass spectrometry (SPMS) has been widely used for characterizing the chemical mixing state of ambient aerosol particles. However, processes occurring during particle ablation and ionization can influence the mass spectra produced by these instruments. These effects remain poorly characterized for complex atmospheric particles. During the 2005 Study of Organic Aerosols in Riverside (SOAR), a thermodenuder was used to evaporate the more volatile aerosol species in sequential temperature steps up to 230°C; the residual aerosol particles were sampled by an aerosol mass spectrometer (AMS) and a single-particle aerosol time-of-flight mass spectrometer (ATOFMS). Removal of the secondary species (e.g., ammonium nitrate/sulfate) through heating permitted assessment of the change in ionization patterns as the composition changed for a given particle type. It was observed that a coating of secondary species can reduce the ionization efficiency by changing the degree of laser absorption or particle ablation, which significantly impacted the measured ion peak areas. Nonvolatile aerosol components were used as pseudo-internal standards (or “reference components”) to correct for this LDI effect. Such corrected ATOFMS ion peak areas correlated well with the AMS measurements of the same species up to 142°C. This work demonstrates the potential to accurately relate SPMS peak areas to the mass of specific aerosol components.

Copyright 2014 American Association for Aerosol Research     

Retraction of ‘Basu,S., Dahl,K.N. & Rohde,G.K. (2013) Localizing and extracting filament distributions from microscopy images. Journal of Microscopy, 250, 57–67. doi:10.1111/jmi.12018’

The above article, published online on 4 March 2013 in Wiley Online Library ( wileyonlinelibrary.com ), has been retracted by agreement between the authors, the journal Editor in Chief, Tony Wilson, the Royal Microscopical Society and John Wiley & Sons Ltd.  The retraction has been agreed following an investigation by an ad hoc advisory committee of senior faculty members assembled by the College of Engineering, Carnegie Mellon University. The committee concluded that all the parties involved acted honourably, but implicit misunderstandings and unintended miscommunications led to the unfortunate inclusion of several images used in the study without proper approval from the copyright owner.     

New multichannel electron energy analyzer with cylindrically symmetrical electrostatic field

This article discusses an electron energy analyzer with a cylindrically symmetrical electrostatic field, designed for rapid Auger analysis. The device was designed and built. The best parameters of the analyzer were estimated and then experimentally verified.     

Mass spectrometry of atmospheric aerosols--recent developments and applications. Part I: Off-line mass spectrometry techniques

Many of the significant advances in our understanding of atmospheric particles can be attributed to the application of mass spectrometry. Mass spectrometry provides high sensitivity with a fast response time to probe chemically complex particles. This review focuses on recent developments and applications in the field of mass spectrometry of atmospheric aerosols. In Part I of this two-part review, we concentrate on off-line mass spectrometry techniques, which require sample collection on filters but can provide detailed molecular speciation. In particular, off-line mass spectrometry techniques utilizing tandem mass spectrometry experiments and high resolution mass analyzers provide improved insight into secondary organic aerosol formation and heterogeneous reaction pathways through detailed structural elucidation at the molecular level.     

The computer modelling and the chemical kinetics of the rate of cure of epoxy resins

Conclusions  The combined techniques of radiolabelling and computer simulation provide a powerful way of monitoring the actual mechanisms and reactivity of epoxy cure. The information obtained from this treatment allows the understanding of the structure:activity relationships in epoxy cure reactions and permits the design of curing agents with improved or decreased reactivity. A decreased reactivity would be useful for improving the shelf-life of the resin. A decreased k₂ would lead to materials with good tack and drape properties. The potential for controllable B-staging is also evident in such a system with a reduced k₂.     

The marangoni effect and enhanced oil recovery Part 1. Porous media studies

The use of partitionable solutes, e.g., aliphatic alcohols, to enhance the recovery of trapped oil in reservoir rock, has been simulated using a ballotini-packed column initially flooded with kerosene, and subsequently lowered to an irreducible value by a water drive. Introduction of a “slug” of an alcohol effected an increased recovery, with n-propanol and sec-butanol giving the highest yields. Previous workers attributed such increased recovery to the formation of a “soluble front”, in which both oil and connate water are completely dissolved. However, we obtained similar recoveries using slugs with initial compositions lying on the miscibility boundary, which could not form soluble fronts. It was therefore concluded that Marangoni-induced oscillation of the trapped drops is the more likely explanation of the enhanced recovery.