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851.
Plasma‐Assisted Synthesis and Surface Modification of Electrode Materials for Renewable Energy 下载免费PDF全文
Shuo Dou Li Tao Ruilun Wang Samir El Hankari Ru Chen Shuangyin Wang 《Advanced materials (Deerfield Beach, Fla.)》2018,30(21)
Renewable energy technology has been considered as a “MUST” option to lower the use of fossil fuels for industry and daily life. Designing critical and sophisticated materials is of great importance in order to realize high‐performance energy technology. Typically, efficient synthesis and soft surface modification of nanomaterials are important for energy technology. Therefore, there are increasing demands on the rational design of efficient electrocatalysts or electrode materials, which are the key for scalable and practical electrochemical energy devices. Nevertheless, the development of versatile and cheap strategies is one of the main challenges to achieve the aforementioned goals. Accordingly, plasma technology has recently appeared as an extremely promising alternative for the synthesis and surface modification of nanomaterials for electrochemical devices. Here, the recent progress on the development of nonthermal plasma technology is highlighted for the synthesis and surface modification of advanced electrode materials for renewable energy technology including electrocatalysts for fuel cells, water splitting, metal–air batteries, and electrode materials for batteries and supercapacitors, etc. 相似文献
852.
Kaya Demir Vijay Sukumaran Yoichiro Sato Abderrahim El Amrani Koushik Ramachandran Raghuram Pucha P. Markondeya Raj Venkatesh Sundaram Rao Tummala 《Journal of Materials Science: Materials in Electronics》2018,29(15):12669-12680
Glass is an ideal substrate material to enable 2.5D and 3D packaging of ICs at low cost and high performance. However, it is a brittle material and is prone to failures during fabrication and operation. Large coefficient of thermal expansion (CTE) mismatch between copper and glass leads to thermomechanical stresses that can lead to glass cracking and delamination from glass interfaces. This paper focuses on modeling and reliability characterization of copper-plated through-package-vias (TPV) in glass packages. Thermomechanical simulations were carried out to obtain design guidelines for reliable TPVs in glass. Test-vehicles with different glass thicknesses and copper TPV fabrication conditions were fabricated for thermal cycling tests, resistance monitoring and failure analysis. The reliability characterization results showed good thermomechanical reliability of TPVs in ultra-thin glass panels. 相似文献
853.
Khadija El Cheikh Chafika Djelal Yannick Vanhove Patrick Pizette Sébastien Rémond 《Advanced Powder Technology》2018,29(1):130-141
Wall roughness plays a crucial role in granular medium - rough wall interface friction. In this study, an experimental device has been designed to study the influence of boundary conditions, more specifically wall roughness, on the behavior of sheared granular medium. The study is based on use of an analog model, and consists of simulating roughness by means of notches and grains in the medium by monodisperse beads and on use of a numerical model based on the discrete element method. The test protocol entails displacing at fixed speed notched rods under confined granular medium. Movement of the beads layer near the rods as well as friction of the beads against the rods are both studied herein. Results indicate that the parameter controlling friction at the granular medium - rough wall interface is primarily the depth of beads embedment in surface asperities. The objective of the associated numerical modeling is to supplement the experimental results. 相似文献
854.
El‐Sayed A. El‐Dahshan Mahmoud M. Bassiouni 《International journal of imaging systems and technology》2018,28(2):132-148
This study proposes an image classification methodology that automatically classifies human brain magnetic resonance (MR) images. The proposed methods contain four main stages: Data acquisition, preprocessing, feature extraction, feature reduction and classification, followed by evaluation. First stage starts by collecting MRI images from Harvard and our constructed Egyptian database. Second stage starts with noise reduction in MR images. Third stage obtains the features related to MRI images, using stationary wavelet transformation. In the fourth stage, the features of MR images have been reduced using principles of component analysis and kernel linear discriminator analysis (KLDA) to the more essential features. In last stage, the classification stage, two classifiers have been developed to classify subjects as normal or abnormal MRI human images. The first classifier is based on K‐Nearest Neighbor (KNN) on Euclidean distance. The second classifier is based on Levenberg‐Marquardt (LM‐ANN). Classification accuracy of 100% for KNN and LM‐ANN classifiers has been obtained. The result shows that the proposed methodologies are robust and effective compared with other recent works. 相似文献
855.
S. Zouhair M. Monkade M. Bourass A. El Antari M. El Bouziani M. Madani A. Alrajhi 《Journal of Superconductivity and Novel Magnetism》2018,31(12):3949-3957
In this work, we study the Ising model with mixed spins S = ?1/2 and S = ?3/2 on the hypercubic lattice and the random crystal field at the sublattice with S =?3/2 described by a two peaks law. To achieve this, we use an approximation of position space renormalization group (PSRG) namely Migdal-Kadanoff in which we use both the free energy derivative and the flow in the parameter space of the Hamiltonian. For all values of the random probability, the critical behavior is determined via the critical exponents at the second-order fixed points while at low temperatures; the discontinuities of the of the free energy derivative provide the positions of the first-order transitions. The introduction of a minimal amount of disorder causes a change in the phase diagram showing the relevance of disorder for d =?2 and d =?3. The second-order transition remains always with the same critical exponents as those of the pure model, and a new first-order transition appears at very low temperature. Also, a comparison with other similar works is given. 相似文献
856.
Martha Hernández-Orta Elías Pérez Luis Emilio Cruz-Barba Marco A. Sánchez-Castillo 《Journal of Materials Science》2018,53(12):8766-8785
Plasma-based technology is an alternative to produce universal polymer coatings with the appropriate requirements of robustness and stability for antibacterial applications. Here, we proposed a sequential two-step alternative to synthesize antibacterial polymer coatings. A non-isothermal plasma reactor, operated at atmospheric pressure (Patm) and room temperature (Troom), was used to induce free radical polymerization of 4-vinyl pyridine (4VP) on high-density polyethylene (PE). In a subsequent step, the poly-4VP (P4VP) films were treated with a bromoethane/He gas stream to produce quaternized P4VP (P4VPQ) films. Chemical structure of polymer films was validated by infrared and UV–visible spectroscopy, and morphology was evaluated by optical and atomic force microscopy; scanning electron microscopy was used to determine films thickness, which was then used to estimate the surface charge density. The bactericidal capacity was determined with a standard test by using Escherichia coli. Both types of films had an estimated charge density in the order of 1016 positive charges per cm2; P4VP films removed about 95–99% of bacteria, whereas 4PVPQ films eliminated 100%. The methodology proposed for the synthesis of antibacterial polymer coatings is simpler, faster, and more environmentally friendly than other plasma-based methods; operation at Troom and Patm may also have a significant effect on the economics and the ease of implementation of the process at commercial scale. The suggested approach may facilitate the development of new universal coatings, and operating plasma conditions could be extrapolated for engineering antibacterial coatings in industrial areas where bacterial attachment is of concern. 相似文献
857.
In research evaluation of single researchers, the assessment of paper and journal impact is of interest. High journal impact reflects the ability of researchers to convince strict reviewers, and high paper impact reflects the usefulness of papers for future research. In many bibliometric studies, metrics for journal and paper impact are separately presented. In this paper, we introduce two graph types, which combine both metrics in a single graph. The graphs can be used in research evaluation to visualize the performance of single researchers comprehensively. 相似文献
858.
M. Khelil Jean-Hugh Thomas L. Simon R. El Guerjouma M. Boudraa 《Journal of Nondestructive Evaluation》2017,36(2):31
The aim of this study is to characterize the structural noise for a better flaw detection in heterogeneous materials (steels, weld, composites...) using ultrasonic waves. For this purpose, the continuous wavelet transform is applied to ultrasonic A-scan signals acquired using an ultrasonic non destructive testing (NDT) device. The time-scale representation provided, which highlights the temporal evolution of the spectral content of the A-scan signals, is relevant but can lead to misinterpretation. The problem is to identify if each pattern from the wavelet representation is due to the structural noise or the flaw. To solve this problem, a detection technique based on statistical significance testing in the time-scale plane is used. Information about the structural noise signals is injected into the decision process using an autoregressive model, which seems relevant according to the spectral content of the signal. The approach is tested on experimental signals, obtained by ultrasonic NDT of metallic materials (austenitic stainless steel) then on a weld in this steel and indeed enables to distinguish the components of the signal as flaw echoes, which differ from the structural noise. 相似文献
859.
El Hassan Elkhattabi Mohamed Lakraimi Moha Berraho Ahmed Legrouri Radouan Hammal Layla El Gaini 《Bulletin of Materials Science》2017,40(4):745-751
Layered double hydroxides (LDHs), also called anionic clays, consist of cationic brucite-like layers and exchangeable interlayer anions. These hydrotalcite-like compounds, with Zn and Al in the layers and chloride in the interlayer space, were prepared following the coprecipitation method at constant pH. The effect of pH, aging time and anion concentration on the intercalation of fluorophosphate \((\hbox {PO}_{3}\hbox {F}^{2-}\), FP) in the [Zn–Al] LDH was investigated. The best crystalline material, with high exchange extent, was obtained by carrying out the exchange at 25\({^{\circ }}\hbox {C}\) in a 0.03 M FP solution at pH 7 with at least 42 h of aging time. A mechanism for the FP intercalation was confirmed by X-ray diffraction, infrared spectroscopy and thermogravimetry (TG) analyses (TG and DTG curves). 相似文献
860.
This article proposed a metamodel-based inverse method for material parameter identification and applies it to elastic–plastic damage model parameter identification. An elastic–plastic damage model is presented and implemented in numerical simulation. The metamodel-based inverse method is proposed in order to overcome the disadvantage in computational cost of the inverse method. In the metamodel-based inverse method, a Kriging metamodel is constructed based on the experimental design in order to model the relationship between material parameters and the objective function values in the inverse problem, and then the optimization procedure is executed by the use of a metamodel. The applications of the presented material model and proposed parameter identification method in the standard A 2017-T4 tensile test prove that the presented elastic–plastic damage model is adequate to describe the material's mechanical behaviour and that the proposed metamodel-based inverse method not only enhances the efficiency of parameter identification but also gives reliable results. 相似文献