Treatment of wastewater containing toxic chromium using new activated carbon developed from date palm seed

The use of a new activated carbon developed from date palm seed wastes, generated in the jam industry, for removing toxic chromium from aqueous solution has been investigated. The activated carbon has been achieved from date palm seed by dehydrating methods using concentrated sulfuric acid. The batch experiments were conducted to determine the adsorption capacity of the biomass. The effect of initial metal concentration (25-125mgl(-1)), pH, contact time, and concentration of date palm seed carbon have been studied at room temperature. A strong dependence of the adsorption capacity on pH was observed, the capacity increase as pH value decrease and the optimum pH value is pH 1.0. Kinetics and adsorption equilibrium were studied at different sorbent doses. The adsorption process was fast and the equilibrium was reached within 180min. The maximum removal was 100% for 75mgl(-1) of Cr(+ concentration on 4gl(-1) carbon concentration and the maximum adsorption capacity was 120.48mgg(-1). The kinetic data were analyzed using various kinetic models - pseudo-first order equation, pseudo-second order equation, Elovich equation and intraparticle diffusion equation - and the equilibrium data were tested using several isotherm models, Langmuir, Freundlich, Koble-Corrigan, Redlich-Peterson, Tempkin, Dubinin-Radushkevich and Generalized isotherm equations. The Elovich equation and pseudo-second order equation provide the greatest accuracy for the kinetic data and Koble-Corrigan and Langmuir models the closest fit for the equilibrium data. Activation energy of sorption has also been evaluated as 0.115 and 0.229kJmol(-1).     

Luminescence of composites based on oxide aerogels incorporated in silica glass host matrix

This paper deals with the elaboration and photoluminescence (PL) examination of oxide powder (OP = ZnO, Al₂O₃, SnO₂, TiO₂) incorporated in silica host matrix. OP, in the first step, was prepared by a sol–gel method using supercritical drying of ethyl alcohol. The obtained powder, in a second step, was incorporated in silica aerogel monolith using tetraethylorthosilicate as SiO₂ precursor and ethyl alcohol supercritical conditions for drying. In the third step, silica aerogel containing oxide powders were heated under natural atmosphere at 1200 °C for 2 h to form the composites that exhibited a strong PL bands at Vis–IR range. Photoluminescence excitation (PLE) measurements show different origins of the emission. It was suggested that OH-related radiative centres and non-bridging oxygen hole centres (NBOHCs) defects resulting from thermal treatment and crystallization at the interfaces between OP and silica host matrix, were responsible for the bands at 400–600 and 700–900 nm respectively.     

Predicting the Crushing Behavior of Axially Loaded Elliptical Composite Tubes Using Artificial Neural Networks

In this research work, the artificial neural networks (ANN) technique is used in predicting the crushing behavior and energy absorption characteristics of axially-loaded glass fiber/epoxy composite elliptical tubes. Predictions are compared to actual experimental results obtained from the literature and are shown to be in good agreement. Effects of parameters such as network architecture, number of hidden layers and number of neurons per hidden layer are also considered. The study shows that ANN techniques can effectively be used to predict the crushing response and the energy absorption characteristics of elliptical composite tubes with various ellipticity ratios subjected to axial loading.     

Synthesis of novel magnetic iron metal-silica (Fe-SBA-15) and magnetite-silica (Fe(3)O(4)-SBA-15) nanocomposites with a high iron content using temperature-programed reduction

Magnetic iron metal-silica and magnetite-silica nanocomposites have been prepared via temperature-programed reduction (TPR) of an iron oxide-SBA-15 (SBA: Santa Barbara Amorphous) composite. TPR of the starting SBA-15 supported Fe(2)O(3) generated Fe(3)O(4) and FeO as stepwise intermediates in the ultimate formation of Fe-SBA-15. The composite materials have been characterized by means of x-ray diffraction, high resolution transmission electron microscopy and SQUID (superconducting quantum interference device) magnetometry. The Fe oxide and metal components form a core, as nanoscale particles, that is entrapped in the SBA-15 pore network. Fe(3)O(4)-SBA-15 and Fe-SBA-15 exhibited superparamagnetic properties with a total magnetization value of 17?emu?g(-1). The magnetite-silica composite (at an Fe(3)O(4) loading of 30%?w/w) delivered a magnetization that exceeded values reported in the literature or obtained with commercial samples. Due to the high pore volume of the mesoporous template, the magnetite content can be increased to 83%?w/w with a further enhancement of magnetization.     

How nanoparticles encapsulating fluorophores allow a double detection of biomolecules by localized surface plasmon resonance and luminescence

The paper shows how polysiloxane particles encapsulating fluorophores can be successfully used to detect biotin-streptavidin binding by two types of technique. After functionalization of the particles by streptavidin, the fixation of the biomolecule can indeed be detected by a shift of the localized surface plasmon resonance of the biotinylated gold dots used as substrate and by the luminescence of the fluorophores evidenced by scanning near-field optical microscopy. The development of particles allowing such a double detection opens a route for increasing the reliability of biological detection and for multi-labelling strategies crossing both detection principles.     

Probing the structure of heterogeneous diluted materials by diffraction tomography

The advent of nanosciences calls for the development of local structural probes, in particular to characterize ill-ordered or heterogeneous materials. Furthermore, because materials properties are often related to their heterogeneity and the hierarchical arrangement of their structure, different structural probes covering a wide range of scales are required. X-ray diffraction is one of the prime structural methods but suffers from a relatively poor detection limit, whereas transmission electron analysis involves destructive sample preparation. Here we show the potential of coupling pencil-beam tomography with X-ray diffraction to examine unidentified phases in nanomaterials and polycrystalline materials. The demonstration is carried out on a high-pressure pellet containing several carbon phases and on a heterogeneous powder containing chalcedony and iron pigments. The present method enables a non-invasive structural refinement with a weight sensitivity of one part per thousand. It enables the extraction of the scattering patterns of amorphous and crystalline compounds with similar atomic densities and compositions. Furthermore, such a diffraction-tomography experiment can be carried out simultaneously with X-ray fluorescence, Compton and absorption tomographies, enabling a multimodal analysis of prime importance in materials science, chemistry, geology, environmental science, medical science, palaeontology and cultural heritage.     

Effect of Nitrogen Alloying on Sulphur Behaviour during ESR of AISI M41 Steel

In this work, the effects of nitrogen alloying, physical properties and chemical composition of slag used in electro‐slag refining (ESR) on phosphorus and sulphur contents of AISI M41 high speed steel have been studied. The experiments were conducted with two high speed steel grades which were melted in an induction furnace (IF). The first grade is the standard AISI M41 high‐speed steel and the second one is nitrogen alloyed M41 (denoted M41N). The produced ingots were ESR remelted under three grades of calcium fluoride based slag. Results showed that the ESR process has no effect on the phosphorus content in steel but it is a good tool in removing sulphur. This study shows that a high desulphurization rate can be achieved by ESR process by optimizing slag properties where the viscosity and oxidation reactions play an important role in sulphur removal. Nitrogen alloying was found to retard sulphur removal.     

剪力墙和薄壁开口截面作为支撑的高层建筑抗震计算的简化方法

对高度方向性能恒定,不对称的建筑结构,提出了近似的抗震分析手算方法。通过剪力墙和薄壁开口截面结构的结合,增加了建筑物的刚度。基于连续技术和达朗伯原理,推导了自由振动的控制方程和相应的特征值问题。应用伽辽金技术,提出了一个通用的方法对剪力墙和薄壁开口截面结构的耦合振动进行自由振动分析。     

Measurement of Frequency-Dependent Dynamic Properties of Soils Using the Resonant-Column Device

Dynamic properties of soils are commonly evaluated at resonance; thus, their variation with frequency is difficult to measure. A nonresonance (NR) method has been recently used for testing soils at low frequencies and strain levels below the linear threshold shear strain. However, the NR method has not been validated with the standard resonant method for different shear strain levels. In this study, the NR method is used to measure the dynamic properties of soils at low and midstrain levels for a maximum frequency bandwidth between 5 and 100?Hz using the resonant-column device. A new transfer function (NTF) equation is introduced to compare the dynamic properties measured using the NR method and the conventional transfer function approach. Experimental results for two sands and a sand–bentonite–mud mixture are presented for different strain and stress confinement levels. Results from the NR method compare well with the standard resonant column method at the resonant frequency if the strain levels are the same. The NTF approach can be used to measure the dependence of phase velocity of shear waves with frequency. However, the NTF method cannot be used to measure the variation of material damping with frequency. On the other hand, the NR method can be used to measure the degradation curves of wave velocity and material damping ratio as a function of frequency.