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991.
992.
    
Vapochromic behavior is employed to selectively monitor the vapor changes in surrounding environment, particularly for toxic gas leaking and floating detection. Thus, sensitive trapping and accurate response to different toxic vapors are critical factors in vapochromic sensing. In this work, a self‐assembled hybrid that consists of fluorescent organic octahedron encapsulated by metal–organic polyhedron (MOP) is reported. The fluorescent octahedron is used as a responsive sensor to probe various solvent vapors, while the MOP is employed as a protector to prevent the corrosion of solvents to the organic octahedron. The hybrid exhibits remarkable vapochromic behavior to different solvents, and shows the highest selectivity and sensitivity specifically to acetone. In addition, acetone vapor under different conditions is utilized for further studying the response mechanism of the hybrid. This work presents a promising vapochromic sensor with good stability, selectivity, and sensitivity. The study is expected to open up the applicability of MOP‐based hybrids for specific molecular capture, interim storage, controlled release, and advanced sensing.  相似文献   
993.
994.
995.
    
The paper deals with a novel flame retardant and its application in waterborne coatings. The flame retardant was synthesized from hexachloro-cyclo-triphosphazene by nucleophilic substitution with allylamine. Functionalized emulsion copolymers bearing in the structure hexaallylamino-cyclo-triphosphazene were prepared by the semicontinuous emulsion polymerization. The latexes were used as the main component of transparent coating systems cured by melamine formaldehyde resin. The incorporation hexaallylamino-cyclo-triphosphazene did not affect transparency, flexibility, and toughness of resulting coatings and increased their flame stability in terms of the amount of smoke release and maximum average rate of heat emission indicating a slower flame spread during the material combustion.  相似文献   
996.
    
The main objective of this paper is to determine material composition, structure, and chosen mechanical and thermo-physiological comfort properties of selected kinesiology tape. The results of experiments show that kinesiology tape is a non-linear elastic and porous composite material. Warp yarns are core-spun elastic yarns, while weft yarns are 100% cotton yarns. Fabric has a plain weave and its back side is equipped with an adhesive. Tensile strength of kinesiology tape ranges from 80 to 180 N depending on the tape width. In a relaxed state, porosity together with air permeability and other heat and mass transfer characteristics are mainly affected by the compact layer of adhesive on the surface of woven fabric. During tensioning, pores are expanding and therefore transfer of air and water vapor is significantly increased and at the same time heat transfer is reduced which can positively affect wearer comfort.  相似文献   
997.
This paper presents the design of model-based globally linearizing control (GLC) structure for a distillation process within the differential geometric framework. The model of a nonideal binary distillation column, whose characteristics were highly nonlinear and strongly interactive, is used as a real process. The classical GLC law is comprised of a transformer (input-output linearizing state feedback), a nonlinear state observer, and an external PI controller. The tray temperature based short-cut observer (TTBSCO) has been used as a state estimator within the control structure, in which all tray temperatures were considered to be measured. Accordingly, the liquid phase composition of each tray was calculated online using the derived temperature-composition correlation. In the simulation experiment, the proposed GLC coupled with TTBSCO (GLC-TTBSCO) outperformed a conventional PI controller based on servo performances with and without measurement noise as well as on regulatory behaviors. In the subsequent part, the GLC law has been synthesized in conjunction with tray temperature based reduced-order observer (GLC-TTBROO) where the distillate and bottom compositions of the distillation process have been inferred from top and bottom product temperatures respectively, which were measured online. Finally, the comparative performance of the GLC-TTBSCO and the GLC-TTBROO has been addressed under parametric uncertainty and the GLC-TTBSCO algorithm provided slightly better performance than the GLC-TTBROO. The resulting control laws are rather general and can be easily adopted for other binary distillation columns.  相似文献   
998.
Using three different densities, requirement of waterhyacinth biomass for adequate nutrient depletion was examined in simulated models of wastewater of two different trophy. Density dependent removal of phosphate and nitrate was pronounced in low nutrient levels. The results indicated greater preference of N over P when space and nutrients were limitless, whereas, preferential uptake of P over N occurred at high density of both nutrient levels. It is concluded that the required level of orthophosphate of water was achieved at high density of low nutrient enrichment after 12 days of waterhyacinth introduction, suggesting their immense potentials for reclamation of eutrophic water and induction of grazing food chain.  相似文献   
999.
Sewage water treatment plants (STPs) are frequently associated with the release of xenobiotics and, consequently, with biological responses of fish to these substances. The impact of three STPs situated on small streams was assessed in 2009. Brown trout (Salmo trutta fario L.), captured upstream and downstream of these STPs, were used as biomonitors. The concentrations of 39 organic pollutants (PCBs, OCPs, PBDEs, HBCDs, and MCs), and the biological responses related to oxidative stress (lipid peroxidation and carbonyl protein), and antioxidant responses (superoxide dismutase, glutathione peroxidase and glutathione reductase) were measured. Through chemometrics of these parameters, three groups with 97.62% of the total accumulated variance were distinguished. Integration of the assessed biomarkers using the IBR index, ranked environment impact on sites as: DS Pacov > DS Prachatice > DS Brloh > US Pacov > US Prachatice > US Brloh (most to least affected). STPs are a major source of xenobiotic pollution in streams of the Czech Republic. The combined use of chemical analysis and biological responses is necessary to validate the efficacy of a battery of biomarkers chosen to detect environmental stress due to pollution.  相似文献   
1000.
    
https://doi.org/10.1051/ita/1987210303231  相似文献   
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