首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   6418篇
  免费   360篇
  国内免费   12篇
电工技术   90篇
综合类   10篇
化学工业   1324篇
金属工艺   184篇
机械仪表   317篇
建筑科学   133篇
矿业工程   2篇
能源动力   311篇
轻工业   594篇
水利工程   21篇
石油天然气   8篇
武器工业   1篇
无线电   1077篇
一般工业技术   1303篇
冶金工业   522篇
原子能技术   57篇
自动化技术   836篇
  2024年   7篇
  2023年   76篇
  2022年   125篇
  2021年   210篇
  2020年   159篇
  2019年   158篇
  2018年   185篇
  2017年   183篇
  2016年   219篇
  2015年   192篇
  2014年   297篇
  2013年   418篇
  2012年   431篇
  2011年   471篇
  2010年   356篇
  2009年   348篇
  2008年   375篇
  2007年   290篇
  2006年   223篇
  2005年   227篇
  2004年   191篇
  2003年   164篇
  2002年   152篇
  2001年   118篇
  2000年   114篇
  1999年   114篇
  1998年   204篇
  1997年   139篇
  1996年   125篇
  1995年   81篇
  1994年   56篇
  1993年   63篇
  1992年   36篇
  1991年   24篇
  1990年   23篇
  1989年   24篇
  1988年   25篇
  1987年   25篇
  1986年   9篇
  1985年   21篇
  1984年   13篇
  1983年   15篇
  1982年   7篇
  1981年   7篇
  1980年   12篇
  1978年   13篇
  1977年   9篇
  1976年   10篇
  1974年   8篇
  1972年   6篇
排序方式: 共有6790条查询结果,搜索用时 15 毫秒
101.
As various forms of social media are spreading, we often witness that an idea of an individual user drives macroscopic changes. From the perspectives of product development and marketing, the opinions left by potential consumers in online social network can generate big ripple effects. This study analyzes the user opinions in online space to grasp preferences toward various products psychologically categorized by users. We also suggest an aspect of the market mentally configured by users using network modeling while following the framework of economic sociology. Existing analyses on online market place are mainly dealing with structural issues such as inter-actor relationships and status measurement. This study, however, analyzes complex preferences regarding diverse products and brands and derives a new model for inter-market connections. We expect that our study will provide important consequences on digital marketing and community design of corporations planning word of mouth effect in online space.  相似文献   
102.
Graft copolymerization of acrylonitrile (AN) and methyl methacrylate (MMA) onto polychloroprene (CR) was carried out using benzoyl peroxide as initiator. The effects of mole ratio of AN to MMA, reaction temperature, reaction time, solvent, and initiator concentration on the graft copolymerization were examined. It was found that the thermal stability and weatherability of the AN—CR—MMA graft copolymer (ACM) were considerably better than those of CR.  相似文献   
103.
A three-dimensional model is proposed for both furnace-side and wall-side heat transfer in circulating fluidized beds with membrane walls. Following previous publications (Int. J. Heat Mass Transfer (2003a, b)), a core-annulus flow structure is employed in the model, with consideration of the membrane wall influence on bed hydrodynamics. The model couples radiation, conduction and convection on the furnace side to conduction and convection on the wall side. Radiation in the wall layer is simulated by the moment method. A finite-element method is employed to solve the set of non-linear, partial differential equations. The solution is demonstrated for a typical example. The model gives predictions of suspension-to-wall heat transfer which show satisfactory agreement with published experimental data.  相似文献   
104.
A comparative analysis of epoxidized natural rubber samples by 1H and 13C n.m.r., titrimetric, elemental and d.s.c. techniques has been made. Whereas the titrimetric method is only applicable at low epoxy contents (< 15 mol%) both n.m.r. methods give reasonable precision over the compositional range of 20–75 mol%. Elemental analysis appears less reliable. D.s.c. analysis through measurement of Tg provides the highest precision of measurement but requires independent calibration by one or more of the primary methods. The epoxy content may also be related to the polymer density.  相似文献   
105.
The effects of platinum (Pt) and silver (Ag) metallisation in the photocatalytic oxidation of resorcinol at pH 3 ± 0.5 have been investigated. The photocatalytic degradation of resorcinol was significantly improved by Pt/TiO2, while the presence of Ag/TiO2 enhanced the initial photocatalytic degradation rate of resorcinol slightly. Likewise, the photocatalytic mineralisation of resorcinol continued to be enhanced by Pt/TiO2, but it was retarded when Ag/TiO2 was used.

The function of Pt and Ag deposits on the surface of TiO2 has been found to be markedly influenced by the interaction of resorcinol and its degradation products with the metal deposits. The presence of Pt or Ag on the surface of TiO2 altered the distribution of degradation products of resorcinol as well as the production of photoactive species for the photocatalytic oxidation of resorcinol. The X-ray photoelectron spectroscopy (XPS), zeta potential and transmission electron microscopy (TEM) analyses have indicated that the contrasting effect of Pt and Ag deposits were governed by the oxidation states and the catalytic property of metal deposits. In addition to that, it has been found that the roles of metal deposits are specific and should not be generalised.  相似文献   

106.
This study was conducted to investigate the effects of reaction pH condition and hardener type on the reactivity, chemical structure, and molecular mobility of urea–formaldehyde (UF) resins. Three different reaction pH conditions, such as alkaline (7.5), weak acid (4.5), and strong acid (1.0), were used to synthesize UF resins, which were cured by adding four different hardeners (ammonium chloride, ammonium sulfate, ammonium citrate, and zinc nitrate) to measure gel time as the reactivity. FTIR and 13C‐NMR spectroscopies were used to study the chemical structure of the resin prepared under three different reaction pH conditions. The gel time of UF resins decreased with an increase in the amount of ammonium chloride, ammonium sulfate, and ammonium citrate added in the resins, whereas the gel time increased when zinc nitrate was added. Both FTIR and 13C‐NMR spectroscopies showed that the strong reaction pH condition produced uronic structures in UF resin, whereas both alkaline and weak‐acid conditions produced quite similar chemical species in the resins. The proton rotating‐frame spin–lattice relaxation time (T1ρH) decreased with a decrease in the reaction pH of UF resin. This result indicates that the molecular mobility of UF resin increases with a decrease in the reaction pH used during its synthesis. © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 88: 2677–2687, 2003  相似文献   
107.
The detergency profiles of sodium salt α-sulfonated methyl esters derived from palm stearin (α-SMEPS) and polyoxyethylene (20) sorbitan monoesters (POESE) in mixed micelle systems were evaluated as a function of the weight ratios of α-SMEPS/POESE [polyoxyethylene (20) sorbitan monolaurate (12), polyoxyethylene (20) sorbitan monostearate (18∶0), and polyoxyethylene (20) sorbitan monooleate (18∶1)] at different water hardness values (5.12, 51.2, and 512.0 ppm CaCO3) and temperatures (20, 30, 45, and 65°C), respectively. All the mixtures of α-SMEPS/POESE (12, 18∶0, and 18∶1) systems exhibited a synergistic effect at 65°C in the absence of hardness. This was evaluated by measuring the percentage of soil removed. The systems showed an increase in detergency with both the temperature and water hardness. Maximal detergency was observed with 5.12 ppm CaCO3 in the mixed surfactant solution.  相似文献   
108.
Minimum spouting velocities in conical spouted beds have been obtained from pressure drops versus the superficial gas velocity curves, based on both increasing and decreasing the superficial gas velocity. It has been shown that the minimum spouting velocity from decreasing the superficial gas velocity is lower than from increasing the superficial gas velocity in most cases. This phenomenon is similar to that in conventional spouted beds and different from the early works. The experimental results also showed that there isn't significant difference in the pressure drop and Ums under identical operating conditions between semi‐circular and circular conical spouted beds, and the same Ums can be obtained from absolute pressure drops at any position above the gas inlet. The Ums is found to increase with increasing the cone angle and static bed height, as well as the gas inlet diameter to a less extent.  相似文献   
109.
Hotmelt pressure sensitive adhesives (PSAs) usually contain styrenic block copolymers like styrene–isoprene–styrene (SIS), SBS, SEBS, tackifier, oil, and additives. These block copolymers individually reveal no tack. Therefore, a tackifier is a low molecular weight material with high glass transition temperature (Tg), and imparts the tacky property to PSA. The SIS block copolymer with different diblocks was blended with hydrogenated dicyclopentadiene (H‐DCPD tackifier), which has three kinds of Tg. PSA performance was evaluated by probe tack, peel strength, and shear adhesion failure temperature. PSA is a viscoelastic material, so that its performance is significantly related to the viscoelastic properties of PSAs. We tested the viscoelastic properties by dynamic mechanical analysis and the thermal properties by differential scanning calorimeter to investigate the relation between viscoelastic properties and PSA performance. © 2006 Wiley Periodicals, Inc. J Appl PolymSci 102: 2839–2846, 2006  相似文献   
110.
Semi‐interpenetrating polymer network (semi‐IPN) and fully interpenetrating polymer network (full‐IPN) hydrogels composed of alginate and poly(N‐isopropylacrylamide) were prepared with γ‐ray irradiation. The semi‐IPN hydrogels were prepared through the irradiation of a mixed solution composed of alginate and N‐isopropylacrylamide (NIPAAm) monomer to simultaneously achieve the polymerization and self‐crosslinking of NIPAAm. The full‐IPN hydrogels were formed through the immersion of the semi‐IPN film in a calcium‐ion solution. The results for the swelling and deswelling behaviors showed that the swelling ratio of semi‐IPN hydrogels was higher than that of full‐IPN hydrogels. A semi‐IPN hydrogel containing more alginate exhibited relatively rapid swelling and deswelling rates, whereas a full‐IPN hydrogel showed an adverse tendency. All the hydrogels with NIPAAm exhibited a change in the swelling ratio around 30–40°C, and full‐IPN hydrogels showed more sensitive and reversible behavior than semi‐IPN hydrogels under a stepwise stimulus. In addition, the swelling ratio of the hydrogels continuously increased with the pH values, and the swelling processes were proven to be repeatable with pH changes. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 100: 4439–4446, 2006  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号