Derivation of an aquatic predicted no-effect concentration for the synthetic hormone, 17 alpha-ethinyl estradiol

17alpha-Ethinyl estradiol (EE2) is a synthetic estrogen widely used in combination with other steroid hormones in oral contraceptives and in the contraceptive patch. EE2 has been detected in sewage treatment plant effluents in the low nanogram -per-liter range and occasionally in surface waters in the U.S., U.K., Canada, Brazil, Germany, and elsewhere. The mode of action is receptor-mediated, and estrogen receptors exist in mammals and other vertebrates. A large number of studies on the effects of EE2 on aquatic organisms exist. One hundred English language studies published between 1994 and 2007, one as yet unpublished study, and findings published in conference proceedings (in German) were compared to published data quality criteria to identify the most relevant studies for deriving a predicted no-effect concentration (PNEC). Reproduction in fish was identified as the most sensitive end point in aquatic species. A species sensitivity distribution was constructed using no observed effect concentrations (NOECs) for reproductive effects from 39 papers in 26 species, resulting in a median hazardous concentration at which 5% of the species tested are affected (HC5,50) of 0.35 ng/L. After comparing this HC5,50 to all of the laboratory and field-derived toxicity information available for EE2, we recommend using 0.35 ng/L as the PNEC for EE2 in surface water. This PNEC is below 95% of the existing NOECs for effects on reproduction and is also below virtually all of the NOECs for vitellogenin induction in the key fish reproduction studies.     

Sustainability of biofuels in Latin America: Risks and opportunities

Several Latin American countries are setting up biofuel programmes to establish alternative markets for agricultural commodities. This is mainly triggered by the current success of Brazilian bioethanol production for the domestic market and for export. Furthermore, the global biofuel market is expected to increase due to ambitious biofuel programmes in the EU and in the USA. Colombia, Venezuela, Costa Rica and Guatemala are focusing on bioethanol production from sugarcane whereas biofuel production in Argentina is based on soy biodiesel. Recent developments of the biofuel sector take place extremely rapid especially in Argentina, which became one of the five largest biodiesel producers in the world in 2008. Till date no specific biofuel sustainability certification systems have been implemented in Latin American, as well as on global level. This fact and the predominant use of food crops for biofuel production raise concerns about the sustainability of biofuel production related to environmental and social aspects. This paper provides an overview of the hotspots of conflicts in biofuel production in Latin America. It investigates presently available sustainability tools and initiatives to ensure sustainable biofuel production in Latin America. Finally, it provides an outlook on how to integrate sustainability in the Latin American biofuel sector.     

卷帘式彩色LCoS显示器的对比度改善

卷帘式彩色LCoS(硅上液晶)显示必须展现其快速和高对比度两项特性。这些要求推动了成像核心的液晶和光学系统的设计选择。我们发现，输入方向必须沿着入射偏振方向，且须选择一种补偿性的45TN0效应。高对比度需要对界面反射提出严格的要求。线栅PBS能实现高的对比度且能简化系统结构。在关注上述问题的同时，我们曾报告过，在视屏上的时序对比度为800:1。采用90TN0效应，其对比度可以更高，但会有一些光效损失。采用这种效应所测时序对比度为2000:1。     

Solution‐Processed Organic Tandem Solar Cells

A solution‐processed polymer tandem cell fabricated by stacking two single cells in series is demonstrated. The two bulk‐heterojunction subcells have complementary absorption maxima at λ_max ～ 850 nm and λ_max ～ 550 nm, respectively. A composite middle electrode is applied that serves both as a charge‐recombination center and as a protecting layer for the first cell during spin‐coating of the second cell. The subcells are electronically coupled in series, which leads to a high open‐circuit voltage of 1.4 V, equal to the sum of each subcell. The layer thickness of the first (bottom) cell is tuned to maximize the optical absorption of the second (top) cell. The performance of the tandem cell is presently limited by the relatively low photocurrent generation in the small‐bandgap polymer of the top cell. The combination of our tandem architecture with more efficient small‐bandgap materials will enable the realization of highly efficient organic solar cells in the near future.     

Light Emission in the Unipolar Regime of Ambipolar Organic Field‐Effect Transistors

Light emission from ambipolar organic field‐effect transistors (OFETs) is often observed when they are operated in the unipolar regime. This is unexpected, the light emission should be completely suppressed, because in the unipolar regime only one type of charge carrier is accumulated. Here, an electroluminescent diketopyrrolopyrrole copolymer is investigated. Local potential measurements by scanning Kelvin probe microscopy reveal a recombination position that is unstable in time due to the presence of injection barriers. The electroluminescence and electrical transport have been numerically analyzed. It is shown that the counterintuitive unipolar light emission is quantitatively explained by injection of minority carriers into deep tail states of the semiconductor. The density of the injected minority carriers is small. Hence they are relatively immobile and they recombine close the contact with accumulated majority carriers. The unipolar light output is characterized by a constant efficiency independent of gate bias. It is argued that light emission from OFETs predominantly originates from the unipolar regime when the charge transport is injection limited.     

Supporting affect regulation in children with multiple disabilities during psychotherapy: A multiple case design study of therapeutic attachment.

In a controlled multiple case design study, the development of a therapeutic relationship and its role in affect regulation were studied in 6 children with visual disabilities, severe intellectual disabilities, severe challenging behavior, and prolonged social deprivation. In the 1st phase, children had sessions with an experimental therapist stimulating therapeutic attachment, alternating with a control therapist providing positive personal attention only. In the 2nd phase, both therapists applied behavior therapy. Clients sought more proximity to the experimental therapist compared with the control therapist. Psychophysiological arousal (respiratory sinus arrhythmia and pre-ejection period) was lower when the experimental therapist applied behavior modification than when the control therapist did. Despite prolonged social deprivation, the attachment behavioral system appeared responsive to stimulation. The effects on affect regulation may explain the synergy between psychotherapy based on interpersonal and behavior modification approaches. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

On the low intensity bootstrap for triangular arrays of independent identically distributed random variables

In this work, we give a complete picture of the behavior of the low intensity bootstrap of linear statistics. Our setup is given by triangular arrays of independent identically distributed random variables and different normalizations related to the rates of bootstrap intensities. We show that the behavior of this low intensity bootstrap coincides with that of partial sums of a number of summands equal to the bootstrap resampling size. Agreement on the limit laws for different (small) bootstrap sizes is thus shown to be closely related to domains of attraction of α-stable laws. As a byproduct, we obtain local distributional properties of Lévy processes.     

用监控开关模式占空比的方法诊断LED

工程师们一般通过监控HB LED（高亮度发光二极管）的正向电压VF来判断LED的好坏。正向电压的大幅变化可能表明一只或一串LED有品质退化,或完全损坏。对于多只串联的LED,其正向电压之和可以达到40V以上,如果电压不是以地为基准,则需要差动测量。除了大电压和差动测量的挑战以外,     

Qualitative and quantitative assessment of interior moisture buffering by enclosures

The significance of interior humidity in attaining sustainable, durable, healthy and comfortable buildings is increasingly recognised. Given their significant interaction, any interior humidity appraisal requires a qualitative and/or quantitative assessment of interior moisture buffering. While the effective moisture penetration depth and effective capacitance models allow quantified assessment, their reliance on the ‘moisture penetration depth’ necessitates comprehensive material properties and hampers their application to multidimensional interior objects. On the other hand, while various recently suggested protocols for the simple and fast measurement of the moisture buffer potential of interior elements allow qualitative assessment, none of these are currently dependable for a wide range of moisture production regimes.In response to these flaws, this paper introduces the production-adaptive characterisation of the moisture buffer potential of interior elements and corroborates their superposition toward a room-enclosure moisture buffer potential. It is verified that this enables qualitative comparison of enclosures in relation to interior moisture buffering. It is moreover demonstrated that it forms an alternative basis for quantitative evaluation of interior moisture buffering by the effective moisture penetration depth and effective capacitance models. The presented methodology uses simple and fast measurements only and can also be applied to multimaterial and/or multidimensional interior elements.