Catalytic Partial Oxidation of Methanol and Methyl Mercaptan: Studies on the Selectivity of TiO2 and CeO2 Supported V2O5 Catalysts

Catalyst samples based on vanadium, cerium and titanium oxides were prepared using sol–gel method and wet impregnation. Several analytical techniques were used to characterize catalysts. The best activity and selectivity in the partial oxidation of methanol and methyl mercaptan were observed for the catalyst sample with the composition of 3 % V₂O₅/Ti_0.1–Ce_0.9O₂.     

Bio‐hybrid nanocomposite coatings from sonicated chitosan and nanoclay

Nanocomposite films and coatings with improved properties were produced from ultrasonic dispersed chitosan and hydrophilic bentonite nanoclay. Bio‐hybrid coatings were applied onto argon–plasma‐activated LDPE coated paper. The intercalation of chitosan in the silicate layers was confirmed by the decrease of diffraction angles as the chitosan/nanoclay ratio increased. Nanocomposite films and multilayer coatings had improved barrier properties against oxygen, water vapor, grease, and UV‐light transmission. Oxygen transmission was significantly reduced under all humidity conditions. In dry conditions, over 99% reduction and at 80% relative humidity almost 75% reduction in oxygen transmission rates was obtained. Hydrophilic chitosan was lacking the capability of preventing water vapor transmission, thus total barrier effect of nanoclay containing films was not more than 15% as compared with pure chitosan. Because to very thin coatings (≤1 μm), nanoclay containing chitosan did not have antimicrobial activity against test strains. All coating raw materials were “generally recognized as safe” (GRAS) and the calculated total migration was in all cases ≤6 mg/dm², thus the coatings met the requirements set by the packaging legislation. Processing of the developed bio‐hybrid nanocomposite coated materials was safe as the amounts of released particles under rubbing conditions were comparable with the particle concentrations in a normal office environment. © 2010 Wiley Periodicals, Inc. J Appl Polym Sci, 2010     

Moderate anisotropy in the electrical conductivity of bulk MWCNT/epoxy composites

Bulk aligned multi-walled carbon nanotube films and their epoxy composites were prepared and their DC and AC conductivity studied. Nanotube films of up to 2 mm thickness were grown by catalytic chemical vapor deposition. Composites of nanotubes were made by infiltrating the films with a commercial epoxy. DC electrical resistivities in the axial direction of as-grown and purified films were found to be ∼1.2 Ωmm and ∼3.4 Ωmm, respectively. For the transverse direction the resistivity values were higher only with a factor of ∼2. In the case of composites, anisotropy is more pronounced showing more than an order of magnitude higher resistivity in the transverse direction (∼71.4 Ωmm) as compared to the axial value (∼4.2 Ωmm). AC behavior of the films investigated between 1 MHz and 3 GHz shows the presence of inductive and capacitive components at frequencies above ∼100 MHz. The moderate anisotropy for both DC and AC electrical properties are explained on the basis of the films’ structure combined with percolation theory and equivalent circuit models.     

Electromagnetic field computation in semiconductor laser resonators

An electromagnetic method based on rigorous diffraction theory of gratings is applied to the analysis of fields in semiconductor laser cavities. The method is based on the Fourier modal method; it is fully rigorous for infinitely periodic resonators and highly accurate for single resonators when absorbing boundary conditions are applied. Fundamental-mode intracavity and near-field distributions are evaluated for some selected geometries, and resonance frequencies are predicted.     

Note — Preliminary Applications of Response Surface Modelling to the Evaluation of Optimal Growth Conditions for Beer‐spoiling Pediococcus damnosus

Beer‐spoiling lactic acid bacteria (LAB) belong to the most harmful contaminants in the brewing industry and various rapid molecular detection methods have been introduced for the detection of these organisms. However, the enrichment cultivation steps needed prior to detection by molecular methods can extend the duration of the analytical procedure by up to several days. The use of brewery‐specific enrichment cultivation media has been recommended due to the large variety within the group of LAB, as well as differences in the microbes encountered at the breweries. In contrast to using a general medium that may support only the growth of some LAB, the combination of several media could allow detection of all relevant LAB. The aim of the present study was to show the effects of shifts in the cultivation conditions and media on the growth of beer‐spoiling LAB using one of the most frequently encountered species, Pediococcus damnosus, as an example. Based on the variable analysis, significant factors could be recognized and their effects on lag‐times and growth rates were compared by means of response surface modelling.     

Influence of the heat exchangers’ construction material on catalytic incineration

In industrial scale catalytic volatile organic compounds (VOCs) incineration it is sometimes observed that the VOC conversions are higher than expected, based on the laboratory scale experiments at the same temperatures. One reason for this is that the construction material of the industrial scale catalytic incinerator may have an effect on the total VOC conversion. In this study, the effect of construction material on VOC removal activity is studied through laboratory experiments, by thermodynamic calculations and by flow modelling. The results showed that copper and Aluzinc decreased the light-off temperature (T₅₀) of n-butyl acetate compared to thermal experiments. Copper and Aluzinc did not, however, further decrease the T₅₀ when they were introduced into the reactor packed with the catalyst. The higher total VOC conversion observed in the industrial scale incinerator is presumably due to the higher temperatures at the outlet of the catalyst, which is maintained by the heat exchangers.     

Rotation manifold <Emphasis Type="Italic">SO</Emphasis>(3) and its tangential vectors

In this paper, we prove that incremental material rotation vectors belong to different tangent spaces of the rotation manifold SO(3) at a different instant. Moreover, we show that the material tangent space as the tangent space at unity is not a possible definition yielding geometrically inconsistent results, although this kind of definition is widely adopted in applied mechanics community. In addition, we show that the standard Newmark integration scheme for incremental rotations neglects first order terms of rotation vector, not third order terms. Finally, we show that the rotation interpolation of extracted nodal values on the rotation manifold is not an objective interpolation under the observer transformation. This clarifies controversy about the frame-indifference of geometrically exact beam formulations in their finite element implementations.     

Antioxidative properties and enzymatic synthesis of ascorbyl FA esters

Efficient synthesis of unsaturated FA esters of ascorbic acid is possible with only a small excess of one of the reactants in t-amyl alcohol using Candida antarctica lipase as biocatalyst. Using free acids, we obtained yields that were comparable to yields reached using vinyl-activated acyl donors (71, 80, and 86% yields of esters with FA excesses of 1∶1, 1∶1.5, and 1∶2, respectively). As very low water activity is needed to achieve sufficiently high yields of product, molecular sieves were used to improve the ascorbyl ester yields. Ascorbyl oleate is more amorphous and has a much lower m.p. and lower enthalpy of fusion than ascorbyl palmitate. This leads to a higher solubility of ascorbyl oleate in oil, resulting in an increased antioxidant effect compared to that of the palmitate. In an accelerated storage test using deodorized rapeseed oil, samples incubated with ascorbyl palmitate showed noticeable oxidation after 1 wk of storage, whereas samples incubated with ascorbyl oleate displayed negligible oxidation for 9 and 4 wk at 30 and 40°C, respectively.     

Imputation of single-tree attributes using airborne laser scanning-based height, intensity, and alpha shape metrics

Forest inventories based on single-tree interpretation of airborne laser scanning (ALS) data often rely on an allometric estimation chain in which inaccuracies in the estimates of the diameter at breast height (DBH) propagate to other characteristics of interest such as the stem volume. Our purpose was to test nearest neighbor imputation by the k-Most Similar Neighbor (k-MSN) and the Random Forest (RF) methods for the simultaneous estimation of species, DBH, height and stem volume using ALS data. The predictors included computational alpha shape metrics and variables based on the height and intensity distributions in the ALS data. Separate data sets covering 1898 and 1249 dominant to intermediate trees in a typical Scandinavian stand structure were used for training and validation, respectively. RF proved to be a flexible method with an ability to handle 1846 predictors with no need for their reduction. Classification of Scots pine, Norway spruce and deciduous trees showed an accuracy of 78%, and the estimates of DBH, height and volume had root mean square errors of 13%, 3%, and 31%, respectively, when evaluated against the validation data. The two selection strategies implemented here reduced the number of candidate variables effectively without any substantial effect on the accuracy relative to the use of all predictors. Differences in k-MSN and RF imputations were marginal when the reduced sets of variables were used. Estimation accuracies could be maintained practically unchanged with only 12.5% of the initial reference data (237 trees), provided the distribution of the observations was similar in the reference and target data. Since we used information collected in the field for extracting the ALS point clouds for individual trees, our results represent an optimal case and should nevertheless be validated against automated tree delineation.