Transport of K in PVC matrix membranes containing valinomycin

We report impedance measurements on PVC matrix membranes which contain KBPh₄ with varying proportions of valinomycin. In agreement with our earlier measurements the value of the bulk membrane resistance (R_b) is much larger in the presence of valinomycin, indicating that the mobility of K⁺ is greatly reduced by the valinomycin. R_b shows a linear variation with valinomycin/K⁺ ratio between 0 and 1, but it is invariant at higher valinomycin/K⁺ ratios. Thus there is no evidence for a special transport mechanism for K⁺ in these membranes.     

Drying cellulose triacetate in a dryer with a vibrational fluidized bed

Conclusions The process of drying cellulose triacetate in a vibrating bed has been studied.For final drying of cellulose triacetate before solution, it is recommended to use an industrial specimen of a unit with a vibrating bed having a capacity of 2700 kg/h.This assembly can be used to dry other fibre-forming disperse polymeric materials containing strongly bound moisture.Translated from Khimicheskie Volokna, No. 3, pp. 49–51, May–June, 1984.     

Spalling of Flat Plates by Thermal Shock

A model is presented for the thermal shock damage in plates subjected to a sudden rise in temperature. Spalling is assumed to follow localized buckling caused by the thermally induced compressive stresses above subsurface flaws. The minimum size o flaw required to cause spalling is determined as a function of the material properties of the plate, the temperature rise, the position of the paw, and the time after the thermal shock.     

Phase Studies Concerning Sintering in Aluminas Doped with Ti4+

Previous solid state analyses of sintering in Ti⁴⁺-doped-commercial alumina are shown to be in error because a liquid phase exists in the appropriate region of the Al₂O₃−TiO₃−Na₂Ophase diagram at least by 1350^°C, a temperature lower than that at which "solid state" studies were conducted. It is suggested that liquid-phase sintering is a much more common occurrence than was realized formerly.     

The function of bleaching earths in the processing of palm,palm kernel and coconut oils

The results presented in the literature, which attempt to elucidate the mechanisms by which triglyceride oils are bleached by earths, are reviewed. The impact of this work and how the mechanistic proposals affect changes in oil properties are considered, with particular emphasis on the needs of the palm oil processor. Important properties include color, metals and phosphorus content and oxidative stability of the oil. Investigations made in our own laboratories have been aimed at elucidating the effect of varying physical and chemical properties of the bleaching earth on the quality of bleached and deodorized oils. Techniques used in this work are pore-size distribution, surface area, scanning and transmission electron microscopy and a variety of chemical and X-ray analysis methods. The ability to vary such parameters in montmorillonite clays by alteration of process conditions to give materials with specific performance characteristics is demonstrated. Comparisons are made between acid-activated montmorillonites and other clay types.     

Optical networks for local loop applications

Some of the options for optical technology within the local loop environment are examined. In particular, passive shared access networks have been considered in some detail. These networks show great promise for delivering existing telephone services to small to medium business customers (4-30 lines) economically by the early 1990s. Extending fiber to the home will also be possible by virtue of a similar passive network infrastructure for customers requiring new broadband services beyond the single telephone line. For one-line plain old telephone service (POTS) customers, an intermediate approach of terminating the fiber network at the final network distribution point, with copper retained for the final leg, may be used prior to the provision of broadband services. A key feature of the passive optical network architecture is the use of wavelength-division multiplexing (WDM) as an upgrade strategy, allowing graceful upgrading from telephone services to multichannel high-definition television (HDTV) on gigabit/second bearers and full two-way switched broadband services employing wavelength routing across the network     

Long-term transients in a reactor under forced concentration cycling

In the approach to a cycle-invariant state in the forced feed concentration cycling of the CO oxidation over a NiO catalyst, a very long transient has been observed lasting 80 ks or more. This transient appears to be associated only with CO pretreatment of the catalyst and is not a general phenomenon. The slow convergence to the cycle-invariant state reported in certain modelling calculations in the literature appears to have a different cause.