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81.
Several samples of chitosan with different degrees of deacetylation and of different molecular weights were tested for the coagulation–flocculation of organic suspensions. Organic suspensions were prepared by mixing mushroom powder with tap water. Experiments were carried out at pH 5, pH 7, and pH 9. Because decreasing the pH reduced the amount of chitosan required to reach the required turbidity, at pH 9, a high concentration of chitosan was required to achieve the required treatment levels, whereas the difference was less significant between pH 7 and pH 5 (the required concentration of chitosan was halved). Though viscosity, correlated to the molecular weight of chitosan, affected treatment performance, its influence on the efficiency of coagulation–flocculation could be substantially reduced by slightly increasing the concentration of the polymer. This is of importance in the processing of industrial effluents: the aging of a chitosan solution, which may cause partial depolymerization, and loss of viscosity, will have a limited impact on process efficiency. The degree of deacetylation also has a limited effect on treatment performance, especially when the degree of deacetylation exceeds 90%. © 2005 Wiley Periodicals, Inc. J Appl Polym Sci 98: 2070–2079, 2005 相似文献
82.
The cure kinetics and mechanisms of an epoxy oligomer based on diglycidyl ether of bisphenol A (DGEBA), polymerized with a liquid aromatic diamine based on diethyl toluene diamine (DETDA 80), and its blends with poly(ether imide) (PEI) at concentrations of 0–15 wt % were studied with differential scanning calorimetry under dynamic and isothermal conditions. The kinetic analyses were performed with a phenomenological approach. The reaction mechanism of the blends remained the same as that of the neat epoxy. However, the addition of PEI had a marked effect on the cure kinetics in the DGEBA/DETDA 80 system. The rate of reaction decreased with an increase in the thermoplastic content. Diffusion control was incorporated to describe the cure behavior of the blends in the latter stages. Greater diffusion control was observed as the PEI concentration increased and the cure temperature decreased. Polymer blends based on this epoxy/liquid aromatic diamine had not been previously studied from a kinetic viewpoint. © 2005 Wiley Periodicals, Inc. J Appl Polym Sci 96: 660–672, 2005 相似文献
83.
The crystallization kinetics and morphology development of pure isotactic polypropylene (iPP) homopolymer and iPP blended with atactic polypropylene (aPP) at different aPP contents and the isothermal crystallization temperatures were studied with differential scanning calorimetry, wide‐angle X‐ray diffraction, and polarized optical microscopy. The spherulitic morphologies of pure iPP and larger amounts of aPP for iPP blends showed the negative spherulite, whereas that of smaller amounts of aPP for the iPP blends showed a combination of positive and negative spherulites. This indicated that the morphology transition of the spherulite may have been due to changes the crystal forms of iPP in the iPP blends during crystallization. Therefore, with smaller amounts of aPP, the spherulitic density and overall crystallinity of the iPP blends increased with increasing aPP and presented a lower degree of perfection of the γ form coexisting with the α form of iPP during crystallization. However, with larger amounts of aPP, the spherulitic density and overall crystallinity of the iPP blends decreased and reduced the γ‐form crystals with increasing aPP. These results indicate that the aPP molecules hindered the nucleation rate and promoted the molecular motion and growth rate of iPP with smaller amounts of aPP and hindered both the nucleation rate and growth rate of iPP with larger amounts of aPP during isothermal crystallization. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 103: 1093–1104, 2007 相似文献
84.
为获得有抗氧化活性的工业用酵母菌株,对2株来源于原料乳中有较强抗氧化活性的酵母菌进行鉴定.根据菌株的表型、生理生化特征和基因型的特性,初步将这2株菌鉴定为毕赤氏发酵酵母(Pichia fermentans).将这2株酵母菌在高温灭菌(UHT)牛乳中培养以研究其对牛乳主要成分的影响,结果表明:这2株酵母能在UHT牛乳中产乙醇,具有促进蛋白水解活性与脂肪水解活性的能力,能有效提高乳中的游离氨基酸和脂肪酸的含量. 相似文献
85.
Daniel Serrano Jean Peyrelasse Christian Boned Daniel Harran Philippe Monge 《应用聚合物科学杂志》1990,39(3):679-693
The percolation model has been applied to the study of gelation of the TGDDM-DDS system (tetraglycidyldiaminodiphenylmethane–diaminodiphenylsulfone) at a mass concentration of 100–30. For each temperature the experimental viscosity curves are satisfactorily described by a percolation law. Using the degree of chemical reactions, X, as a variable, a very clear change in the reaction mechanism with temperature can be shown. Then a rate of advancement of effective reactions, Y, is defined. This value only takes intermolecular-type reactions into account, and is probably the only variable on which viscosity depends in a percolation law: η = B(1 ? Y/Yc)?p. We obtain Yc= 0.45 and p= 2.0. Comparing Xc and Yc at the gel point, we obtain information on the proportion of intramolecular reactions with temperature. It is also demonstrated that the critical percolation threshold agrees closely with the gel point determined experimentally on log G″= f(t) curves. 相似文献
86.
The different low temperature coordination modes of ethylene and butadiene on a platinum (111) face, (110) face and on a palladium (111) face are compared on the basis of extended Hückel calculations. The nature of the chemical interaction between the olefin and the surface is detailed and the electronic factors that govern the coordination mode of the hydrocarbon are underlined. The different surfaces are modelled by a 49 or a 44 atoms cluster. A correction is applied in the calculation in order to minimize the artefact introduced by this cluster representation of an extended surface. For the adsorption, the respective importance of two electrons interactions and four electrons repulsions is the key point for the determination of the preferred mode. The di- coordination is more stable on platinum (111) but on the platinum (110) face the coordination yields the same adsorption energy than the di- one. This is roughly the same result for the palladium (111) face. The mode is there favored by a decrease of the four electrons repulsions caused either by a smaller number of metal neighbours for the surface atom (Pt(110)) or by a reduced radial expansion of the metal orbitals (Pd(111)). This coordination is associated with a smaller hybridization of the ethylene molecule. The results are extended to the adsorption of butadiene and this allows a qualitative explanation of the better selectivity for butadiene partial hydrogenation on palladium compared with platinum. 相似文献
87.
Abraho Silvia Insfran Emilio Sluters Arthur Vanderdonckt Jean 《Software and Systems Modeling》2021,20(5):1335-1349
Software and Systems Modeling - Adapting the user interface of a software system to the requirements of the context of use continues to be a major challenge, particularly when users become more... 相似文献
88.
Virginie Boy Wajdi Ben Khalifa Lucie Drvillon Yves Leme Thomas Lendormi Jean‐Louis Lanoisell 《加拿大化工杂志》2021,99(1):120-134
An original drying process combining air impingement and intermittent drying was studied on apple slices and mango cubes. The influence of four operating parameters (air velocity, drying/tempering periods, upper height, and air temperature) on the drying time and on the drying rate was evaluated. Continuous and intermittent drying were compared. The intermittency α = 1/7 (τon = 10 seconds and τoff = 60 seconds) gave the best results. A time savings of 54% for apple and 67% for mango was reached. In continuous drying, a time savings of 4620 seconds was observed by increasing the air velocity from 6 to 40 m s?1 for apple. Air temperatures of 328 K for apple and of 328 K or 338 K for mango were determined as optimum to prevent case‐hardening. Experimental results were fitted with the analytical solution of Fick's second law and the modified Page equation (average values R2 = 0.985 and 0.961, for apple and mango, respectively). For both products, the apparent moisture diffusivity Dapp, the drying constant k, the drying coefficient n, and the activation energy Ea, were identified. Activation energies calculated from the analytical solution were 30.3 and 36.8 kJ mol?1 and were 25.4 and 30.0 kJ mol?1 using the modified Page equation for apple and mango, respectively. Mango has an increased temperature sensitivity and thus will need less energy for drying than apple. 相似文献
89.
90.
Extracting Microfacet‐based BRDF Parameters from Arbitrary Materials with Power Iterations
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Jonathan Dupuy Eric Heitz Jean‐Claude Iehl Pierre Poulin Victor Ostromoukhov 《Computer Graphics Forum》2015,34(4):21-30
We introduce a novel fitting procedure that takes as input an arbitrary material, possibly anisotropic, and automatically converts it to a microfacet BRDF. Our algorithm is based on the property that the distribution of microfacets may be retrieved by solving an eigenvector problem that is built solely from backscattering samples. We show that the eigenvector associated to the largest eigenvalue is always the only solution to this problem, and compute it using the power iteration method. This approach is straightforward to implement, much faster to compute, and considerably more robust than solutions based on nonlinear optimizations. In addition, we provide simple conversion procedures of our fits into both Beckmann and GGX roughness parameters, and discuss the advantages of microfacet slope space to make our fits editable. We apply our method to measured materials from two large databases that include anisotropic materials, and demonstrate the benefits of spatially varying roughness on texture mapped geometric models. 相似文献