Absolute Differential Cross-Sections for Elastic Electron Scattering from Sevoflurane Molecule in the Energy Range from 50–300 eV

We report the results of the measurements and calculations of the absolute differential elastic electron scattering cross-sections (DCSs) from sevoflurane molecule (C₄H₃F₇O). The experimental absolute DCSs for elastic electron scattering were obtained for the incident electron energies from 50 eV to 300 eV, and for scattering angles from 25° to 125° using a crossed electron/target beams setup and the relative flow technique for calibration to the absolute scale. For the calculations, we have used the IAM-SCAR+I method (independent atom model (IAM) applying the screened additivity rule (SCAR) with interference terms included (I)). The molecular cross-sections were obtained from the atomic data by using the SCAR procedure, incorporating interference term corrections, by summing all the relevant atomic amplitudes, including the phase coefficients. In this approach, we obtain the molecular differential scattering cross-section (DCS), which, integrated over the scattered electron angular range, gives the integral scattering cross-section (ICS). Calculated cross-sections agree very well with experimental results, in the whole energy and angular range.     

Divergent Effect of Central Incretin Receptors Inhibition in a Rat Model of Sporadic Alzheimer’s Disease

The incretin system is an emerging new field that might provide valuable contributions to the research of both the pathophysiology and therapeutic strategies in the treatment of diabetes, obesity, and neurodegenerative disorders. This study aimed to explore the roles of central glucagon-like peptide-1 (GLP-1) and gastric inhibitory polypeptide (GIP) on cell metabolism and energy in the brain, as well as on the levels of these incretins, insulin, and glucose via inhibition of the central incretin receptors following intracerebroventricular administration of the respective antagonists in healthy rats and a streptozotocin-induced rat model of sporadic Alzheimer’s disease (sAD). Chemical ablation of the central GIP receptor (GIPR) or GLP-1 receptor (GLP-1R) in healthy and diseased animals indicated a region-dependent role of incretins in brain cell energy and metabolism and central incretin-dependent modulation of peripheral hormone secretion, markedly after GIPR inhibition, as well as a dysregulation of the GLP-1 system in experimental sAD.     

Handoff performance in wireless DS‐CDMA networks

This paper analyses the performance of DS‐CDMA networks in the presence of call handoffs. We show that a handoff may violate the SINR requirements for other users, and thus cause an outage in the target cell. We propose to use the probability of such events as a possible metric for quality of service in networks with multiple traffic types, and derive the corresponding QoS parameters. A two‐level admission policy is defined: in tier 1 policy, the network capacity is calculated on the basis of the bound on outage probability. However, this policy does not suffice to prevent outage events upon handoffs for various traffic types, and henceforth, we propose an extension that reserves extra bandwidth for handoff calls, thus ensuring that handoff calls will not violate the outage probability bound. The overhead imposed by the extension is negligible, as the complete two‐tier admission control algorithm is executed only when a call is admitted into the network. Once admitted, calls can freely execute handoffs using the reserved bandwidth. The modified second‐tier bandwidth reservation policy is adaptive with respect to the traffic intensity and user's mobility and we show that it can provide satisfactory call (flow) quality during its lifetime. Analytical results for the QoS have been verified by the simulations. Copyright © 2002 John Wiley & Sons, Ltd.     

Migration of Plasticizer between Bonded Propellant Interfaces

Plasticizer migration across bonded propellant interfaces during cure has been shown to have a measurable effect on propellant properties compared to each propellant by itself. This shows that the curing period is significant to the migration phenomenon. The plasticizer migration has been shown to have a direct influence on tensile strength for short aging periods up to the point the plasticizer reaches equilibrium. The tensile data for short aging periods have been shown to follow an empirical equation connecting the physical characteristics of plasticizer migration with increasing propellant tensile strength. The diffusion coefficient has been evaluated on the basis of this relation from a plot of σ versus t^1/2 and was in good agreement with the diffusion coefficient from the plasticizer content data.     

Lineup and photo spread procedures: Issues concerning policy recommendations.

This article examines the recommended changes to lineup reforms outlined by eyewitness researchers and the impact of these reforms on public policy as reflected in national guidelines for police identification procedures (Technical Working Group for Eyewitness Evidence, 1999). The limitations of these reforms are discussed. Alternative "best practices" for social science researchers, as well as for police, are proposed to minimize false-positive lineup selections and, consequently, convictions of innocent persons. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

The perspectives of natural deep eutectic solvents in agri-food sector

Abstract

The principles of ‘green chemistry’ are gaining importance in agri-food sector due to the need to reduce pollution from toxic chemicals, make industrial processes safer and more sustainable, and to offer ‘clean-labeled products’ required by the consumers. The application of natural deep eutectic solvents (NADES) – natural product-based green liquids is considered the promising alternative to conventional organic solvents. This review is intended to summarize and discuss recent advances related to physicochemical properties of NADES, their applications, compatibility with analytic techniques and toxicological profile, pointing out the challenges and necessary improvements for their wider utilization in agri-food sector. NADES allow extraction of wide range of food compounds and they are proven to be convenient for food-related applications. However, their potential for industrial scale-up utilization is not completely investigated. Examined NADES are readily biodegradable, but only preliminary studies on NADES toxicity which include limited number of NADES molecules are available. Apart from fundamental research dealing with NADES formation and the nature of the interactions and structure underpinning the liquid phase formation, the question of purity of NADES obtained by different synthetic methodologies need to be addressed in the future. Data on physicochemical properties of synthetized NADES are still needed as they are relevant for industrial applications.     

Abstract Interpretation based Verification of Logic Programs

This paper is an overview of our results on the application of abstract interpretation concepts to various problems related to the verification of logic programs. These include the systematic design of semantics modeling various proof methods and the characterization of assertions as abstract domains.     

Yttrium Bearing Silicon Carbide Matrices for Robust Ceramic Composites

Application of SiC‐based ceramic matrix composites (CMCs) in combustion environments demands the use of an environmental barrier coating (EBC) to prevent volatilization of the protective SiO₂ scale in flowing water vapor. The EBC only provides protection while present on the surface; cracking and spallation of the coating leaves the underlying SiC vulnerable to the oxidation–volatilization processes. A robust matrix material chemically tailored to regrow a yttrium silicate scale in the event of EBC loss has been developed by incorporating yttrium bearing species including YB₂, Y₂O₃, and Y₅Si₃ into the SiC. During oxidation a borosilicate glass helps seal cracks while Y₂O₃ and SiO₂ react to form Y₂Si₂O₇ for environmental protection. Candidate compositions were oxidized for 10 min to 100 h at 1400°C and for 24 h at 1500°C to understand the scale growth. The prospects for effectively applying this approach in CMCs are discussed.     

A new kernel development algorithm for edge detection using singular value ratios

The perceptual quality of an image is very sensitive to the degradation of the edge information which is usually caused by many video signal applications such as super-resolution and denoising. Hence, it is very important to detect and enhance the edge information of the image. In this research work, new sets of kernels for edge detection using ratios of singular values of an image are proposed, which results in more detailed detection of edges in the original image. The parameters, which are the elements of kernel matrices and the threshold value used for producing binary image after convolving the kernels with the image of the proposed method, are optimised to achieve more detailed edge detection of the image. The experimental results show that more detailed edges are detected by the proposed method compared to the conventional edge detection techniques.     

Motional heterogeneity and phase separation of semi-interpenetrating networks and mixtures based on functionalised polyurethane and polymethacrylate prepolymers

Semi-interpenetrating polymer networks (SIPNs) and polymer mixtures (1:1 mass ratio) based on segmented polyester polyurethane (PU) with carboxylic groups and methacrylic copolymer (PM) with tertiary amine groups were studied by the electron spin resonance (ESR) spin label method. The concentration of functional groups varied from 0 to 0.45 mmol g⁻¹ in both prepolymers. The ESR spectra of spin labelled PM component were used to characterise the heterogeneity of segmental motion and transitions due to the additional polymer interactions imposed by complementary functional groups. The results were deduced from the temperature dependent ESR spectra. Two component spectra reflect the effect of PU chains on segmental motion of the PM component below the macroscopic glass transition temperature, T_g. The ratio of the fast and slow component was related to the complex polymer-polymer interaction or extent of miscibility. Restrictions of segmental motion of PM chains increase with functional groups concentration and above certain concentration (0.25 mmol g⁻¹) PM segments in the network assess faster motion suggesting a change in the local packing density and domain structure. An increased miscibility and disorganisation of the ordered domains are confirmed by the loss of spherulitic morphology and crystallinity at higher functional groups concentration. PU/PM mixtures reveal similar motional behaviour as SIPNs of the same composition. However, the differences in the fractional amount of fast and slow motions confirm better interpenetration and interaction of the two polymers in the SIPNs. The results of motional heterogeneity and polymer interactions were complemented with the T_gs.