Antibacterial self-healing anticorrosion coatings from single capsule system

It is highly desirable to develop self-healing anticorrosion coatings with enhanced antibacterial function to prevent the scratched area to be fouled or corroded in harsh environments. Herein, we report antibacterial self-healing anticorrosion coatings via the simple incorporation of the easily synthesized single polymer microcapsule system. Well-defined polymer microcapsules containing isophorone diisocyanate (IPDI) as a healing agent and 4,5-dichloro-2-n-octyl-4-isothiazolin-3-one (DCOIT) as antibacterial molecules were synthesized by one-pot polymerization. The diameter and core fraction were around 30 μm and 90%, respectively. The active DCOIT content in the core material could be precisely controlled by adjusting the DCOIT/IPDI feeding ratio. The DCOIT/IPDI microcapsules-embedded protective coating exhibits an adaptive self-healing anticorrosion property, as shown by electrochemical test under the condition of the salt-water immersion. Furthermore, the self-healing coating showed efficient antibacterial function against Escherichia coli and Pseudomonas aeruginosa, which is due to the released active biocide molecules on the damaged surfaces. In contrast to other systems, this single capsule system without any catalyst is perspective for extending the service time of the antibacterial self-healing materials in harsh environment.     

Effects of the molecular structure from pitch fractions on the properties of pitch-based electrospun nanofibers

Mesophase pitch was separated into different pitch fractions to investigate the effect of pitch fractions on the properties of their nanofibers prepared by electrospinning. The evolution of different pitch fractions-derived nanofibers during stabilization and carbonization were explored, and the properties of the resultant carbon nanofibers (CNFs) as electrode materials for supercapacitor were compared. Results indicated that the hexane insoluble-toluene soluble (HI-TS) and toluene insoluble-tetrahydrofuran (THF) soluble (TI-THFS) fractions had good spinnability due to their narrow molecular weight distribution. Moreover, compared with HI-TS and THF insoluble (THFI), TI-THFS consisted of appropriate aromaticity and branched alkyl groups which promoted the stabilization and carbonization behaviors of its nanofibers, resulting in maintaining ideal fiber morphology of TI-THFS-derived nanofiber due to the mitigation of their exothermic reactions. Meanwhile, the TI-THFS-derived CNFs presented the highest surface area of 543 m² g⁻¹ and exhibited an excellent specific capacitance of 167 F g⁻¹ at 0.5 A g⁻¹ in 6 M KOH electrolyte.     

基于分布式技术的用电信息采集主站系统设计与应用

随着用户侧数据采集设备的发展及电网业务对用户侧采集数据的深化应用,当前电力用户用电信息采集主站系统在数据采集、计算、入库等方面出现瓶颈,无法满足业务快速发展的需求.针对营销数字化转型发展的需要,基于分布式架构、异步网络、并行计算与分布式存储等技术,文中提出一种具有高频实时采集特征的主站系统技术方案,在采集通信层、任务调度层、分布式存储层及并行计算层4个层面全面解决高频并发交互、复杂任务调度、海量数据存储及实时计算的效率问题.通过中国某省级工程应用表明,所提出的方案可显著提升用电信息采集主站的采集能力,改善集中式采集主站性能.     

半芳香族耐高温尼龙PA6T/6I基LDS功能材料制备及性能

采用半芳香族耐高温尼龙聚对苯二甲酸/间苯二甲酸己二胺(PA6T/6I)为树脂基体,铜铬氧化物为激光镭射助剂,制备了PA6T/6I基的激光直接成型(LDS)功能材料。采用扫描电子显微镜对激光镭射助剂分散状态及LDS功能材料模塑器件的表面形貌能进行了表征,使用热失重分析仪、差示扫描量热仪对LDS功能材料的热失重行为、熔融结晶性能进行了表征,研究了激光镭射助剂添加量对LDS功能材料的力学性能、热稳定性、化学镀性能的影响,同时研究了PA6T/6I熔融结晶性能和注塑模具温度对于模塑器件表面、外观的影响。结果表明,偶联剂的添加有利于改善激光镭射助剂在PA6T/6I树脂基体中的分散,其中环氧类的偶联剂KBM–403处理后的LDS镭射助剂分散效果最佳。激光镭射助剂添加量的增加,会造成LDS功能材料拉伸强度、弯曲强度、冲击强度及初始分解温度降低。激光镭射助剂添加量在8%时,预镀铜上镀时间和镀层覆盖时间最短,化学镀效果最佳。当注塑模具温度为175℃时,玻纤增强PA6T/6I基LDS功能材料模塑器件的外观最佳。     

LTNE条件下界面对流传热系数对部分填充多孔介质通道传热特性的影响

在多孔介质区考虑局部非热平衡,采用Brinkman-extended Darcy模型结合应力跳跃条件对部分填充多孔介质通道内流体传热特性进行分析。获得了各区域温度分布及Nusselt数解析解,并分析了各参数对温度及Nusselt数的影响。结果表明：界面对流传热系数H_s较小时,界面应力跳跃系数β和Darcy数Da的增加会减小流固两相间温差。而在高H_s下,Da减小也会减小两相温差。在Da、H_s和固流两相热导率之比K较大且空心率S（自由流体区高度与通道高度之比）和Biot数Bi较小时,流固两相间会在接近多孔介质区中部出现最大温差,而该最大温差会随着S增加和Da及H_s的减小向界面区移动。对于不同K与Bi,Nusselt数Nu与S的关系曲线存在不同的类型,与模型A（界面处多孔介质固相和流相根据各自温度梯度和热导率划分总热流）不同的是,采用模型C（界面处固相热流分配与自由流体区流相的热交换相关）所获得的Nu曲线类型与H_s有关。在K较小时,β对Nu的影响大于H_s对Nu的影响;而在K较大时,H_s对Nu的影响要远大于β对Nu的影响,且H_s增加会明显提高通道内的Nu。     

弱电网下基于锁相控制并网变换器小扰动同步稳定分析

该文对弱电网下基于锁相控制并网变换器的小扰动同步稳定问题进行研究。首先,以机理化揭示并网变换器同步特性为目标,通过将其和传统同步机的同步动态进行类比等效,建立适用于并网变换器同步稳定分析的类Heffron-Phillips动力学模型。进而借鉴传统电力系统低频振荡分析思路,采用复转矩系统法分析思想,将锁相环主导的同步振荡模式阻尼分为两部分:锁相环自身固有阻尼分量和弱电网下复杂控制耦合引入的附加阻尼分量,进而从阻尼特性的角度揭示弱电网下并网变换器同步稳定机理,并从影响固有或附加阻尼分量的角度,研究电网阻抗、控制器参数等因素对小扰动同步稳定性的影响。该文研究结果清晰揭示了弱电网下并网变换器同步失稳机理,并为后续同步稳定控制指明了思路。     

基于AprilTag图像识别的移动机器人定位研究

气流激振故障是燃汽轮机由于工作介质引发的常见故障,针对某型燃气轮机气流激振故障,建立峰值保持降采样算法和粒子群算法优化的深度置信网络故障诊断模型。使用峰值保持降采样法对振动数据进行缩减,并以之作为深度置信神经网络的输入,降低模型训练时间,同时采取粒子群算法对深度置信网络结构参数寻优,搜索诊断性能最好的深度置信模型所对应的网络结构参数。实例结果表明,优化后的模型不仅降低模型训练时间,实现网络结构参数智能寻优,还有效实现燃气轮机气流激振故障诊断,测试准确率约为99.8%。     

硅-碳纳米管柔性复合负极的制备与性能

采用浮动催化化学气相沉积(FCCVD)法,将纳米硅颗粒(NSi)与碳纳米管(CNT)连续体原位复合,制备纳米硅-CNT复合膜(NSi-CNTf)柔性电极.借助SEM、能量色散谱(EDS)和电化学性能测试,分析电极的形貌特征和电化学性能.相较于传统Si/Cu电极,NSi-CNTf电极省去了浆料研磨、涂覆工艺,且具有良好的柔韧性和抗弯折性,比容量和循环性能均有提升.FCCVD法制备的NSi-CNTf柔性电极材料,纳米硅均匀分布在CNT薄膜的三维导电结构中,结合紧实,以0.2 A/g在0.01～2.00 V循环200次,比容量保持在790 mAh/g;在4.0 A/g下充放电,比容量保持在509 mAh/g.     

基于DBN网络与BP神经网络PID控制的永磁同步电机调速策略比较研究

针对BP神经网络自身存在的学习速率固定、记忆不稳定等缺点,设计了一种基于DBN网络PID的永磁同步电机控制器,通过Matlab/Simulink对基于BP神经网络PID控制器的电机调速策略和基于DBN网络PID控制器的电机调速策略进行建模仿真分析,探讨两者对于PMSM调速策略中控制鲁棒性和稳定性的优劣。仿真结果表明,基于DBN网络PID的永磁同步电机调速控制策略训练效果更佳,具有更好的稳定性和鲁棒性。     

Failure Analysis of an Oxidative Chlorination Reactor Clad with AISI 304L Stainless Steel

Failure analysis of the hermetical AISI 304L stainless steel cladding in oxidative chlorination reactor shows that its pitting and stress corrosion arose due to the presence of chlorine ion in the working environment. In order to improve its corrosion resistance, AISI 316L stainless steel should be utilized.