Power management system for a 2.5 W remote sensor powered by a sediment microbial fuel cell

One of the challenges in using wireless sensors that require high power to monitor the environment is finding a renewable power source that can produce enough power. Sediment microbial fuel cells (SMFCs) are considered an alternative renewable power source for remote monitoring, but current research on SMFCs has demonstrated that they can only produce several to tens of mW of continuous power. This limits the use of SMFCs as an alternative renewable remote power source to mW-level power. Such low power is only enough to operate a low-power sensors. However, there are many remote sensors that require higher power, on the order of watts. Current technology using a SMFC to power a remote sensor requiring watts-level intermittent power is limited because of limitations of power management technology. Our goal was to develop a power management system (PMS) that enables a SMFC to operate a remote sensor consuming 2.5 W of power. We designed a custom PMS to store microbial energy in capacitors and use the stored energy in short bursts. Our results demonstrate that SMFCs can be a viable alternative renewable power source for remote sensors requiring high power.     

An exploratory study on the gaps and pathways to the Korean fusion DEMO

With the vision of being an early demonstrator of fusion energy, the strategic plans for the Fusion DEMO program of Korea (K-DEMO program) has been developed. A staged development of the K-DEMO plant was considered in the strategic plans as to verify technical feasibility in the first stage and economic feasibility in the second stage. The top-tier design requirements and assumptions of the first stage K-DEMO plant are defined and postulated. With these requirements and assumptions, the desired and current status of nuclear fusion technologies are compared to identify the gaps to be filled to design, fabricate, construct, and operate it. The pathways from KSTAR, ITER to K-DEMO plant have also been studied to identify R&D activities for K-DEMO program that are to go in parallel with KSTAR and ITER are extracted from the pathways. Cross-cutting with the fusion R&D activities of the other countries and utilizing the commonalities with the existing systems are discussed with the provision of open-innovation strategy that is one of the key strategies of K-DEMO program. The priority of the R&D activities of K-DEMO program is qualitatively determined in consideration of the gaps, cross-cutting, and risks associated with the R&D investments.     

Influence of helical tube dimensions on open channel natural convection heat transfer

Natural convection heat transfer of a helical tube was investigated experimentally for varying tube diameter, length, height, pitch, radius, and number of turns, in order to determine an appropriate characteristic length to describe the phenomenon. Mass-transfer rates of a CuSO₄–H₂SO₄ electroplating system were measured by replacing the heat transfer system according to the analogy concept. When the pitch-to-diameter ratio was larger than 5 and the pitch-to-radius ratio was smaller than 2.3, the heat transfer rates were very close to those of a horizontal cylinder, and decreased with the diameter of the tube while remaining unaffected by the total length and height. The natural convection heat transfer of the Nth turn of a helical tube was measured for varying pitch-to-diameter ratio and number of turns, and the results were formulated as an empirical correlation.     

Hybrid DSO-GA-based sensorless optimal control strategy for wind turbine generators

The operation of a wind turbine generator involves natural uncertainty due to aerodynamic characteristics, resulting in a system that performs inefficiently. In general, the conventional controller now in wide use is not suitable for every operating point, because its tuning parameters and set-points do not meet the varying system characteristics. A study into an optimal control technique is conducted to reduce the negative effects of inherent uncertainty in system operation. In order to resolve the uncertainty problem, an optimal control method for an effective wind turbine generator is designed on the basis of a sensorless frame by utilizing a hybrid of the direct search optimization method (DSO) and the genetic algorithm (GA). This method is easy to implement and computation of functional derivatives is not necessary. The conventional GA is well known for its high performance in global optimization and its effectiveness in making ideal choices for control variables. The proposed DSO-GA hybrid differs from the conventional GA in terms of the sampling survey and the crossover operation. Moreover, the proposed multivariable optimal control strategy is a sensorless optimization technique that determines the pitch angle of the blades and the yaw angle of the nacelles to produce stable maximum power from a wind turbine system under steady-state operation. The proposed DSO-GA controller is implemented for a lab-scale wind turbine generator exposed to artificial wind, and the experimental results constitute a 3-D performance surface model of output voltage, which is used as an objective function for simulation. The optimization procedure with the objective function is carried out by means of the conventional and proposed methods, whose results reveal that the proposed DSO-GA optimizer yields far better performance in terms of generation number, convergence rate, and robustness. Both techniques are applied to a wind power generator through simulation and experiments. The performances are compared, and conclusions are drawn for each case.     

Redox-induced performance degradation of anode-supported tubular solid oxide fuel cells

Redox behavior of a Ni-Y₂O₃-stabilized ZrO₂ (YSZ) composite anode support and the performance degradation of an anode-supported tubular solid oxide fuel cell (SOFC) were studied under complete oxidation and reduction conditions (degrees of oxidation and reduction = 100%). Materials characterization studies showed that the exposure time in oxidizing and reducing atmospheres played a critical role in the degradation of the porous structures and the physical properties of the anode support. In particular, the redox cycling with an 8 h exposure time resulted in the cracking of YSZ network, leading to significant decay of the mechanical strength. The polarization experiments on the redox-cycled anode-supported tubular cell showed serious performance degradation as a result of the decreases of open-circuit potential and power density. The ac-impedance measurements combined with microstructural observations indicated that the performance degradation resulted mainly from (i) the degradation of anode support, (ii) microcracks across the whole cell, and (iii) interface delamination.     

Preparation and characterization of polyimide/modified layered double hydroxide nanocomposites

Polyimide (PI)/modified layered double hydroxide (m‐LDH) nanocomposites were prepared in this study. For this work, m‐LDHs were prepared from layered double hydroxides (LDHs) through an anionic exchange reaction with pyromellitic dianhydride (PMDA), succinic acid or terephthalic acid. PMDA and 4,4′‐oxydianiline were used to make the poly(amic acid) precursor for PI. X‐ray diffraction and transmission electron microscopy measurements confirmed that the PMDA‐modified LDH (PMH) and terephthalic acid‐modified LDH (TMH) were well dispersed in the PI matrix. For the succinic acid‐modified LDH, some of the LDH was intercalated with the succinic acid molecules but most maintained its original structure. Thus, the PI/PMH and PI/TMH nanocomposites exhibited improved mechanical, thermal and electrical properties compared to pure PI. The PMH has aromatic groups and is expected to have better π–π interactions with the PI chains than the other m‐LDHs. Thus, the PI/PMH nanocomposites exhibited the best properties among the nanocomposites investigated. Copyright © 2010 Society of Chemical Industry     

The public's value of hydrogen fuel cell buses: A contingent valuation study

With the increasing interest in global warming, there has been intense international competition with regard to the introduction of the hydrogen (H₂) fuel cell (FC) bus, which represents a promising solution for the low-carbon age. With respect to the investment in H₂-based technology development and the expansion of H₂ FC vehicles, the consumer attitude is a crucial factor because the Korean government will consider it one of the most important factors in its decision to approve a large-scale introduction of H₂ FC buses. In this regard, this study measures the public's willingness to pay (WTP) for a large-scale introduction of H₂ FC buses in Korea by employing a survey approach termed the contingent valuation. Furthermore, to enhance statistical efficiency, this study employs the one-and-one-half-bound dichotomous choice method. The annual mean WTP estimate was KRW 4230 (USD 4.55) per household as of 2007. The estimate of the annual benefits to the affected residents was KRW 32.3 billion (USD 34.7 million). The results of this study are expected to be helpful in policy decisions related to the introduction of H₂ FC buses and investment in H₂ technology development.     

ZnO spintronics and nanowire devices

ZnO is a very promising material for spintronics applications, with many groups reporting room-temperature ferromagnetism in films doped with transition metals during growth or by ion implantation. In films doped with Mn during pulsed laser deposition (PLD), we find an inverse correlation between magnetization and electron density as controlled by Sn-doping. The saturation magnetization and coercivity of the implanted single-phase films were both strong functions of the initial anneal temperature, suggesting that carrier concentration alone cannot account for the magnetic properties of ZnO:Mn and factors such as crystalline quality and residual defects play a role. Plausible mechanisms for ferromagnetism include the bound magnetic polaron model or exchange that is mediated by carriers in a spin-split impurity band derived from extended donor orbitals. The progress in ZnO nanowires is also reviewed. The large surface area of nanorods makes them attractive for gas and chemical sensing, and the ability to control their nucleation sites makes them candidates for microlasers or memory arrays. Single ZnO nanowire depletion-mode metal-oxide semiconductor field effect transistors exhibit good saturation behavior, threshold voltage of ∼−3 V, and a maximum transconductance of 0.3 mS/mm. Under ultraviolet (UV) illumination, the drain-source current increased by approximately a factor of 5 and the maximum transconductance was ∼5 mS/mm. The channel mobility is estimated to be ∼3 cm²/Vss, comparable to that for thin film ZnO enhancement mode metal-oxide semiconductor field effect transistors (MOSFETs), and the on/off ratio was ∼25 in the dark and ∼125 under UV illumination. The Pt Schottky diodes exhibit excellent ideality factors of 1.1 at 25°C, very low reverse currents, and a strong photoresponse, with only a minor component with long decay times thought to originate from surface states. In the temperature range from 25°C to 150°C, the resistivity of nanorods treated in H₂ at 400°C prior to measurement showed an activation energy of 0.089 eV and was insensitive to ambient used. By contrast, the conductivity of nanorods not treated in H₂ was sensitive to trace concentrations of gases in the measurement ambient even at room temperature, demonstrating their potential as gas sensors. Sensitive pH sensors using single ZnO nanowires have also been fabricated.