难溶有机药物阿莫西林纳米结构的制备

在表面活性剂SDS的辅助下,运用简单的化学沉淀法制备了三种阿莫西林纳米结构.运用扫描电镜和红外光谱对制备的阿莫西林进行了形貌、尺寸和化学结构的表征.实验发现通过调节阿莫西林钠溶液的pH值,可以得到阿莫西林纳米和微米颗粒纳米带和纳米纤维,在一定程度上实现了这一难溶有机药物的可控生长.     

基于网络科学的团队协作模型及网络模式的识别

网络科学的出现为研究和解决团队系统中的问题提供了新的方法和思路,在其框架下可以将团队的整体表现看作参与者之间的互动结果。文章将网络科学应用于足球运动中,为足球球员组成的团队构建了一个传控网络模型,并对模型的网络模式进行了进一步的分析。     

水雷引信控制系统的低功耗设计

引入水雷引信控制系统的低功耗设计思想,选用MSP430f1611作为系统的微控制芯片并经过精心的外部电路设计,实现了控制系统低功耗,可靠的运行。试验证明,在有限的电池容量条件下此控制系统能够极大的延长工作时间。     

TiB2 Powders Synthesis by Borothermal Reduction in TiO2 Under Vacuum

TiB₂ powders were synthesized by borothermal reduction in nanoscale TiO₂ with boron under vacuum. Reaction processes were investigated, and the effect of by‐product B₂O₃ was evaluated. Results showed that TiO₂ was firstly reduced by boron to form TiBO₃ and Ti₂O₃, and then to produce TiB₂ and B₂O₃ with increasing temperature. The reaction processes of TiB₂ powders synthesis included two‐step reduction in TiO₂ by boron and the removal of B₂O₃. The presence of B₂O₃, which was previously reported as the most important factor in promoting the coarsening of ZrB₂ and HfB₂ powders by borothermal reduction, did not lead to significant coarsening of TiB₂ powders. Due to the minor effect of B₂O₃, TiB₂ powders with small particle size and low oxygen content could be prepared by direct heat treatment of TiO₂ and boron at 1550°C under vacuum for 1 h. The particle size and oxygen content of synthesized TiB₂ powders were ~0.9 μm and ~1.7 wt%, respectively.     

Differentiated Electric Behaviors of La2/3Cu3Ti4O12 Ceramics Prepared by Different Methods

Microstructure and electric behaviors of La_2/3Cu₃Ti₄O₁₂ (LCTO) ceramics prepared by the sol‐gel method (SG) and solid‐state method (SS) have been systemically investigated. The results indicated that LCTO‐SG ceramics sintered at 1105°C for 15 h showed larger grain size, higher density, and especially higher dielectric constant up to about 0.9–1.6 × 10⁴ at 10²~10⁵ Hz compared to LCTO‐SS ceramics. The higher dielectric constant of the LCTO‐SG ceramics might be due to the stronger internal barrier layer capacitor (IBLC) effect. More notably, compared with LCTO‐SS ceramics, two kinds of dielectric anomalies, one conduction activation energy value and same activation energies for the conduction and relaxation process in LCTO‐SS ceramics, the LCTO‐SG ceramics showed three kinds of dielectric anomalies, two values of conduction activation energy, and decrease in conduction activation energy with increasing temperature. The activation energies for the conduction and relaxation process in LCTO‐SG ceramics showed great difference below about 210°C, suggesting that the mechanism of electrical conduction and dielectric relaxation seem to be different in LCTO‐SG ceramics. These remarkable differences in electric behaviors of LCTO ceramics prepared by sol‐gel and solid‐state methods were firstly found and analyzed.     

井眼在软沉积岩和盐岩蠕变的解析解推导

随着勘探开发的不断深入,钻遇复杂地层的可能性越来越大。尤其是软泥岩和盐岩,这些地层的倾向蠕变可引起卡钻、高扭矩崩塌、套管损坏和套管挤毁等复杂情况,这些问题都可以显着增加钻井、固井和生产成本。文章根据Perzyna粘塑性理论,推导出井眼应力和蠕变率的关系,对实现安全钻井和经济钻井具有重要的指导意义,但其适用领域有待进一步验证。     

伸缩式法兰液位检测技术的研究与应用

文章介绍了一种新型检测仪表,该变送器探测杆可根据现场情况变化长度,安装方便,易于检修维护。     

4A分子筛合成研究

本实验主要以化学原料、高岭土和凹凸棒石粘土为原料,通过酸化,碱化,成胶,晶化这一工艺过程,利用传统水热法成功合成了4A分子筛,并通过微波法进行对比。实验过程使用光学显徽镜进行观察;产品通过X射线粉末衍射、NEXUS670型傅里叶红外光谱仪进行了表征。结果表明,传统水热法与微波法均能合成出4A分子筛,并且微波法合成出的样品粒度小且均匀,合成时间大幅减少,降低了能耗。     

Ethanol Synthesis from Syngas on Transition Metal-Doped Rh(111) Surfaces: A Density Functional Kinetic Monte Carlo Study

Advances in methodology, software and power of supercomputers make computational approaches, specifically, density functional theory (DFT), capable of providing qualitative, and in many cases quantitative, insights into catalysis. In this article we adopted a multiscale modeling paradigm in combination of DFT calculations and kinetic Monte Carlo (KMC) methods to provide better understanding of the promoting effect of doping metals (Fe, Mo, Mn) in ethanol synthesis from syngas on Rh(111). Our calculations show that metal-doping and the position of doped metals can have significant effects on the yield and selectivity of ethanol synthesis on Rh(111). Depending on the reaction conditions, Mo and Mn may stay either on the surface or in the subsurface region, while Fe prefers to stay at the surface and participate in the reaction directly. In term of the overall yield and ethanol yield, Mo–Rh(111) with Mo at the surface layer exhibits the highest activity, followed by Mn–Rh(111) with Mn at the subsurface > Fe–Rh(111) > Mo–Rh(111) with Mo at the subsurface, Mn–Rh(111) with Mn at the surface and Rh(111) in a decreasing sequence. In term of the ethanol selectivity, Fe–Rh(111) displays the highest to ethanol, followed by Mo–Rh(111) with Mo at the surface layer, Mn–Rh(111) with Mn at the subsurface > Mo–Rh(111) with Mo at the subsurface, Mn–Rh(111) with Mn at the surface and Rh(111) in a decreasing sequence. As long as Mo stays at the surface layer, Mo is the only dopant we studied here, being able to enhance both yield and selectivity of ethanol synthesis from syngas on Rh(111). Our results suggest that the design of alloy catalyst should be very careful and controlling the position of dopants is essential to the overall catalytic performance.