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51.
Dong Oh Ha JuDong Yeo Sung Tae Kang Mi‐Ja Kim JaeHwan Lee 《European Journal of Lipid Science and Technology》2012,114(7):780-786
Thermal oxidation of edible oils can generate 2,2‐diphenyl‐1‐picrylhydrazyl (DPPH) radical scavenging compounds from oxidized lipids (RSOLs). However, effects of photosensitization on the formation of RSOLs have not been reported yet. Methylene blue (MB) photosensitization and involvement of singlet oxygen and transition metals on the RSOL formations were determined in stripped lard oils. RSOLs were formed in lard containing MB and visible light irradiation only. Addition of sodium azide decreased RSOLs with concentration dependent manner, which implies singlet oxygen was involved on the RSOL formation. Ethylenediammetetraacetic acid (EDTA), a well known metal chelator, accelerated the formation of RSOLs through protecting the decomposition of MB photosensitizer. Results from p‐anisidine values showed that RSOLs from photosensitization may not be formed from the same pathways compared to thermal oxidation. Practical application: Understanding mechanisms of lipid oxidation can help extend the shelf‐life of foods. Photosensitization plays important roles in accelerating the rates of lipid oxidation. The results of this study showed that foods containing photosensitizers can generate radical scavenging compounds from oxidized lipids (RSOLs) under visible light irradiation and singlet oxygen is involved in the formations of these compounds. However, these compounds may not share the same pathways with thermally oxidized lipids. Metal chelating agents accelerated the rates of lipid oxidation and formation of RSOLs which implies that metal chelators can act as prooxidant. Careful considerations are necessary on the addition of metal chelators because non‐polar photosensitizers can act a prooxidant. 相似文献
52.
Mi Soon Yeo Duk Hui Kang Se Kyung Kim Hyun Shik Yun Yoon Mo Koo Youn-Woo Lee Kyung Ho Row 《Korean Journal of Chemical Engineering》2002,19(5):815-817
Ceramide was prepared by the cultivation ofSaccharomyces cerevisiae from cell extracts by solvent exfraction and analyzed by NP-HPLC using a UV detector. The mobile phase was composed of hexane,
methanol, and IPA. From the experimental conditions, the composition of mobile phase was 72/5/23 (hexane/IPA/methanol, vol%).
Quantitative analysis of ceramide was performed. Based on the analytical conditions, the effect of cultivation temperature
for the production of ceramide was investigated and the optimum cultivation temperature was found to be 35°C.
This paper is dedicated to Dr. Youn Yong Lee on the occasion of his retirement from Korea Institute of Science and Technology. 相似文献
53.
Natural manganese ores were selected as raw materials for the desulfurization sorbent because of economical efficiency and high reactivity on hydrogen sulfide. Initial reaction rates between H2S and desulfurization sorbent of natural manganese ores were determined in a temperature range of 400-800°C using a thermobalance reactor. All reactions were first order with respect to H2S and were expressed by the Arrhenius relation. When the sulfidation reaction was controlled by diffusion, the temperature dependence of the effective diffusivity was given by the Arrhenius equation. Activation energies and frequency factors were obtained from the product layer diffusion coefficient of various sorbents by plotting as an Arrhenius equation form. Several additives were mixed to improve the sulfidation capacity, and NiO was the best additive. 相似文献
54.
Yong?Rae?Chae Yeo?Joon?Yoon Keun?Garp?RyuEmail author 《Korean Journal of Chemical Engineering》2004,21(5):999-1002
Expanded bed behavior was modeled by using the Richardson-Zaki correlation between the superficial velocity of the feed stream and the void fraction of the bed. A polydisperse material, Chelating excellose® (70-210 Μm in diameter, 1.21 g/cm3 in density), which has Ni2+ ions for the selective binding of histidine-tagged proteins, was used as the resin. A method to modify the Stokes expression to express the terminal settling velocity of the resins by introducing two empirical parameters, the effective diameter of the resins and an exponent for(ρ p -ρ)/Μ term, was developed. Combined use of the Richardson-Zaki correlation and the modified Stokes expression was successful in modeling the bed expansion by incorporating physical properties of feed streams and the resins. 相似文献
55.
Selective Enrichment of Conjugated Linoleic Acid Isomers in Their Mixtures Using Combined Chemical and Enzymatic Methods 下载免费PDF全文
Jiwon Kim Min-Yu Chung Hee-Don Choi In-Wook Choi In-Hwan Kim Hyang Sook Chun Byung Hee Kim 《Journal of the American Oil Chemists' Society》2017,94(4):577-585
The aim of this study was to selectively enrich t10,c12-conjugated linoleic acid (t10,c12-CLA) and c9,t11-CLA in commercial CLA mixtures using a combination of urea crystallization and lipase-catalyzed esterification. The objective of the urea fractionation is to remove saturated and monounsaturated fatty acids (FA) from the CLA mixtures. CLA-enriched free FA (FFA) mixtures containing 53.8 wt% t10,c12-CLA and 39.1 wt% c9,t11-CLA were produced from the CLA mixtures containing ~34 wt% each of the two CLA isomers by a urea crystallization using methanol and the urea-to-FA weight ratio of 2.5:1. The CLA-enriched FFA mixtures were partially esterified with dodecan-1-ol in a recirculating packed-bed reactor using an immobilized lipase from Candida rugosa to further enrich the t10,c12-CLA and c9,t11-CLA in an FFA fraction and an FA dodecyl ester fraction, respectively, under the optimal conditions, i.e., temperature, 20 °C; FA-to-dodecan-1-ol molar ratio, 1:1; water content, 2 wt% of total substrates; residence time, 5 min; and reaction time, 24 h (for t10,c12-CLA enrichment) and 12 h (for c9,t11-CLA enrichment). After the reaction, an FFA fraction with 72.6 wt% t10,c12-CLA was obtained. Another FFA fraction with 62.0 wt% c9,t11-CLA was recovered after the saponification of the FA dodecyl ester fraction. The yields of t10,c12-CLA and c9,t11-CLA in the FFA fractions were 43.6 and 21.5 wt%, respectively, based on their initial weights in the CLA mixtures. 相似文献
56.
Using a high-resolution, high-dynamic bandwidth capacitive force transducer and two piezoelectric actuators, adhesive pull-off forces between nominally flat rough silicon surfaces were measured under various dynamic conditions in normal and tangential directions and environmental humidity levels. The upper specimen approached and retracted with a constant velocity in the vertical (normal) direction, while the lower specimen started moving in the horizontal (tangential) direction during the middle of the contact. The experiments were performed under 35 and 60% relative humidity conditions. It was found that sliding of the contacting surfaces led to a significant reduction in pull-off forces under low-humidity contact conditions, whereas it caused higher pull-off forces under partially wet contact conditions. Comparing the effects of sliding velocity and sliding distance on the measured pull-off force values, it was found that the sliding distance played an important role in the increase in pull-off forces. 相似文献
57.
58.
An optimization system, based on modeling and simulation, was developed for a sulfolane extraction plant. The primary objective
of the operation of this plant is to increase benzene composition, which is mostly affected by the recycle streams in the
plant. In this work the optimal recycle streams were identified and resulting product compositions were evaluated. In the
optimization, suitable parametric models for each process unit were obtained first from the steady-state rigorous modeling
and simulation of the sulfolane extraction plant. The parametric models were then employed to develop the optimization system
based on the SQP scheme. Results of simulations show promise for further economic improvements over present operation states. 相似文献
59.
A model representing the wet-end section of a paper mill has been developed to characterize its dynamic behavior during the
grade change. The model is based on the mass balance relationships written for the simplified wetend white water network.
From the linearization of the dynamic model, higher-order Laplace transfer functions were obtained followed by the reduction
procedure to give simple lower-order models in the form of 1st-order or 2nd-order plus dead times. The dynamic response of the wet-end is influenced both by the white water volume and by the level
of wire retention. Effects of key manipulated variables such as the thick stock flow rate, the ash flow rate and the retention
aid flow rate on the major controlled variables were analyzed by numerical simulations. The simple dynamic model developed
in the present study can be effectively used in the operation and control.
This paper is dedicated to Professor Se Ki Moon on the occasion of his retirement from Hanyang University. 相似文献
60.
Yeong-Koo Yeo Jong Ho Park See-Han Park Changman Sohn 《Korean Journal of Chemical Engineering》2005,22(3):339-344
In this work, the Model Algorithmic Control (MAC) method is applied to control the grade change operations in paper mills.
The neural network model for the grade change operations is identified first and the impulse model is extracted from the neural
network model. Results of simulations for MAC control of grade change operations are compared with plant operation data. The
major contribution of the present work is the application of MAC in the industrial plants based on the identification of neural
network models. We can confirm that the proposed MAC method exhibits faster responses and less oscillatory behavior compared
to the plant operation data in the grade change operations. 相似文献