Particle In-Flight and Coating Properties of Fe-Based Feedstock Materials Sprayed with Modern Thermal Spray Systems

New developments in the field of thermal spraying systems (increased particle velocities, enhanced process stability) are leading to improved coatings. Innovations in the field of feedstock materials are supporting this trend. The combination of both has led to a renaissance of Fe-based feedstocks. Using modern APS or HVOF systems, it is now possible to compete with classical materials for wear and corrosion applications like Ni-basis or metal-matrix composites. This study intends to give an analysis of the in-flight particle and spray jet properties achievable with two different modern thermal spraying systems using Fe-based powders. The velocity fields are measured with the Laser Doppler Anemometry. Resulting coatings are analyzed and a correlation with the particle in-flight properties is given. The experiments are accompanied by computational fluid dynamics simulations of spray jet and particle velocities, leading to a comprehensive analysis of the achievable particle properties with state-of-the-art HVOF and APS systems.     

Yttrium incorporation in Cr2AlC: On the metastable phase formation and decomposition of (Cr,Y)2AlC MAX phase thin films

Herein we report on the synthesis of a metastable (Cr,Y)₂AlC MAX phase solid solution by co-sputtering from a composite Cr–Al–C and elemental Y target, at room temperature, followed by annealing. However, direct high-temperature synthesis resulted in multiphase films, as evidenced by X-ray diffraction analyses, room-temperature depositions, followed by annealing to 760°C led to the formation of phase pure (Cr,Y)₂AlC by diffusion. Higher annealing temperatures caused a decomposition of the metastable phase into Cr₂AlC, Y₅Al₃, and Cr-carbides. In contrast to pure Cr₂AlC, the Y-containing phase crystallizes directly in the MAX phase structure instead of first forming a disordered solid solution. Furthermore, the crystallization temperature was shown to be Y-content dependent and was increased by ∼200°C for 5 at.% Y compared to Cr₂AlC. Calculations predicting the metastable phase formation of (Cr,Y)₂AlC and its decomposition are in excellent agreement with the experimental findings.     

Feature‐based recursive observer design for homography estimation and its application to image stabilization

This paper presents a new algorithm for online estimation of a sequence of homographies applicable to image sequences obtained from robotic vehicles equipped with vision sensors. The approach taken exploits the underlying Special Linear group structure of the set of homographies along with gyroscope measurements and direct point‐feature correspondences between images to develop temporal filter for the homography estimate. Theoretical analysis and experimental results are provided to demonstrate the robustness of the proposed algorithm. The experimental results show excellent performance and robustness even in the case of very fast camera motions (relative to frame rate) and severe occlusions.     

Supramolecular Capsules Derived from Resorcin[4]arenes by H-Bonding and Metal Coordination: Synthesis,Characterization, and Single-Molecule Force Spectroscopy

Self-assembly by H-bonding and by metal-coordination of functionalized calix[4]arenes and cavitands to large supramolecular capsules is described. In addition, a new method of analyzing supramolecular recognition processes at the single molecule level is discussed. By measuring interaction forces in a hydrogen-bonded assembly using single-molecule force spectroscopy (SMFS), the dynamics of the self-assembly process can be evaluated. In the future, consequent application of this new technique will influence supramolecular design principles and the use of non-covalent interactions as construction elements in the field of nanotechnology.     

Microwave analysis of PACVD diamond deposition reactor based on electromagnetic modelling

The production of high quality diamond films by microwave plasma assisted CVD, with rapid growth rates and good uniformity over large surfaces, requires perfectly optimized reactors from the microwave design point of view. Most MW plasma assisted CVD reactors used for diamond film deposition work on the resonant cavity principle. The design of such reactors relies on 3 choices: i) choice of a suitable resonant mode (i.e. with an electric field structure conducive to plasma ignition), ii) choice of a MW coupling system to excite the cavity, and iii) choice of a quartz window to delimit a reduced pressure zone inside the cavity, so as to obtain the plasma in front of the substrate [1].In this paper, we present an analysis method for MW plasma reactors relying on EM modelling, which allows for the identification of a resonant mode responsible for plasma ignition, applied to an existing reactor exhibiting plasma instabilities and requiring constant supervision.This analysis method, which can be generalised to any resonant cavity reactor, can describe the device behaviour (shape and location of the plasma, occurrence of instabilities) as a function of the various cavity geometrical configurations and to get a first estimate of the process performance.On the basis of such an analysis, it was possible to propose modifications to the reactor considered in order to improve process stability, and obtain higher growth rates. First growth tests done on diamond mono- and nano-crystalline films show excellent material quality and an increase in growth rate by more than an order of magnitude.     

Material property requirements for analysis and design of UHTC components in hypersonic applications

Analytical modeling of thermal and mechanical response is a fundamental step in the design process for ultra-high-temperature ceramic components, such as nose tips and wing leading edges for hypersonic applications. The purpose of the analyses is to understand the response of test articles to high-enthalpy flows in ground tests and to predict component performance in particular flight environments. Performing these analyses and evaluating the results require comprehensive and accurate physical, thermal, and mechanical properties. In this paper, we explain the nature of the analyses, highlight the essential material properties that are required and why they are important, and describe the impact of property accuracy and uncertainty on the design process.     

Deformation of Mesoporous Titania Nanostructures in Contact with D2O Vapor

For many applications, mesoporous titania nanostructures are exposed to water or need to be backfilled via infiltration with an aqueous solution, which can cause deformations of the nanostructure by capillary forces. In this work, the degree of deformation caused by water infiltration in two types of mesoporous, nanostructured titania films exposed to water vapor is compared. The different types of nanostructured titania films are prepared via a polymer template assisted sol–gel synthesis in conjunction with a polymer‐template removal at high‐temperatures under ambient conditions versus nitrogen atmosphere. Information about surface and inner morphology is extracted by scanning electron microscopy and grazing incidence small‐angle neutron scattering (GISANS) measurements, respectively. Furthermore, complementary information on thin film composition and porosity are probed via X‐ray reflectivity. The backfilling induced deformation of near surface structures and structures inside the mesoporous titania films is determined by GISANS before and after D₂O infiltration. The respective atmosphere used for template removal influences the details of the titania nanostructure and strongly impacts the degree of water induced deformation. Drying of the films shows reversibility of the deformation.